专利号:US-7601774-B2 优先权日:2004-07-19 标题:Synthesis of aromatic polyhalogenated halomethyl compounds 发明人:KORNBERG NURIT; ADDA MICHAEL; PELED MICHAEL 权利人:BROMINE COMPOUNDS LTD 摘要:The present invention discloses a process for the preparation of highly pure pentabromobenzyl bromide, PBB-Br, wherein the benzylic bromination reaction is carried out in a suitable organic solvent in the presence of water and wherein the reaction temperature is such that it is sufficient to activate the initiator but not high enough to consume a substantial amount thereof.
专利号:US-10081591-B2 优先权日:2016-03-17 标 题 :Isomer selective synthesis of methanofullerenes 发明人:JACKSON EDWARD A; RICHTER HENNING 权利人:NANO C INC 摘要:[6,6]-Phenyl C 71 butyric acid derivatives (C 70 -PCBR 3 ) having a selectivity of greater than 95 wt % of the α-isomer are provided by reacting fullerene C 70 with a dialkyl sulfonium tetrafluoroborate having the formula:
专利号:US-9527797-B1 优先权日:2016-03-17 标 题:Isomer-selective synthesis of methanofullerenes 发明人:JACKSON EDWARD A; RICHTER HENNING 权利人:NANO-C INC 摘要:[6,6]-Phenyl C 71 butyric acid derivatives (C 70 -PCBR 3 ) having a selectivity of greater than 95 wt % of the α-isomer are provided by reacting fullerene C 70 with a dialkyl sulfonium tetrafluoroborate having the formula:
专利号:US-2007205403-A1 优先权日:2004-07-19 标 题:Synthesis of Aromatic Polyhalogenated Halomethyl Compounds
专利号:EP-3219701-B1 优先权日:2016-03-17 标 题:Isomer-selective synthesis of methanofullerenes
专利号:WO-2006008738-A1 优先权日:2004-07-19 标题:Synthesis of aromatic polyhalogenated halomethyl compounds
参考文献:10.1021/es201850n 摘要:Möller A, Xie Z, Cai M, Zhong G, Huang P, Cai M, Sturm R, He J, Ebinghaus R. Polybrominated diphenyl ethers vs alternate brominated flame retardants and Dechloranes from East Asia to the Arctic. Environ Sci Technol. 2011 Aug 15;45(16):6793–9. doi: 10.1021/es201850n.