合成目标产物 Mepiquat Chloride 主要起始原料 N-Methylpiperidine And Chloromethane
(文献来源)合成步骤主要原料 N-Methylpiperidine 和 Chloromethane
1,1-二甲基哌啶-1-鎓碘化物置于silver(I) Chloride体系中,化学反应生成甲哌 参考文献:Kinetics Of Reactions Of Cyclic Secondary Amines With 2,4-Dinitro-1-Naphthyl Ethyl Ether In Dimethyl Sulfoxide Solution. Spectacular Difference Between The Behavior Of Pyrrolidine And Piperidine 标题:Kinetics Of Reactions Of Cyclic Secondary Amines With 2,4-Dinitro-1-Naphthyl Ethyl Ether In Dimethyl Sulfoxide Solution. Spectacular Difference Between The Behavior Of Pyrrolidine And Piperidine 摘要: Doi:10.1021/ja00406A032
专利号:US-11919928-B2 优先权日:2016-03-16 标题 :Method for producing dihydrotentoxin 发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI 权利人:KUMIAI CHEMICAL INDUSTRY CO 摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.
专利号:US-11213031-B2 优先权日:2017-11-13 标 题:Tetrazolylpropyl derivatives and their use as fungicides 发明人:SUDAU ALEXANDER; HOFFMANN SEBASTIAN; DAHMEN PETER; WEBSTER ROBERT ALAN; MEISSNER RUTH; GOERTZ ANDREAS; MILLER RICARDA; COQUERON PIERRE-YVES; BERNIER DAVID; NICOLAS LIONEL; BRUNET STEPHANE; KENNEL PHILIPPE; TOQUIN VALERIE; GOURGUES MATHIEU; LOQUE DOMINIQUE; THOMAS VINCENT 权利人:BAYER AG; BAYER CROPSCIENCE AG 摘要:The present invention relates to tetrazolylpropyl derivatives of formula (I) n nwherein one of V 1 and V 2 represents CR 3 and the other one of V 1 and V 2 represents N, Q represents a 6-membered aromatic cycle as defined in the specification, and R 1 , R 2 , R 3 , R 4 , and R 5 are defined as disclosed in the specification, to compositions comprising such compounds, to the use of said compounds as fungicides, as well as to particular intermediates useful in the synthesis of said tetrazolylpropyl derivatives.
专利号:WO-2020226482-A1 优先权日:2019-05-09 标题:Synergistic compositions for controlling plant pathogens with chitinolytic microorganisms / organic acid combinations and method of use thereof 发明人:LAI HONG HENG 权利人:LAI HONG HENG 摘要:The present invention relates to pesticidal compositions and methods for controlling plant pathogens, particularly basal stem rot in the oil palm primarily caused by Ganoderma species. The pesticidal compositions comprising, as active components: (A) Bioactive compound derived from a whole broth culture of an chitinolyic microorganisms, wherein the bioactive compound comprises any or any combination of: chitinolyic microorganism, whole cell broths, liquid cultures, spores, pure cultures, cell fraction, substances, suspensions, supernatants, filtrates, extract or a cell-free extract thereof or metabolite thereof or isolated compounds, wherein the bioactive compound is derived from at least one chitinolyic microorganisms that degrade chitinous substrates. The said chitinolytic microorganism is bacteria belonging to genus Bacillus, Streptomyces and/or fungal genus Trichoderma; (B) at least one organic acid; and (C) at least one pesticide selected from chemical pesticides, microbial pesticides, plant defense activators, cuticle degrading enzymes, cell wall synthesis inhibitors, bacteriocins, antifungal peptides, antimicrobial preservatives, plant oil or plant extract. More specifically, this invention envisions the use of bioactive compounds and/or metabolites from chitinolyic microorganisms in combination essentially of organic acid and the compositions comprising them, in the use form as fungicides and/or insecticides, also be present as 'booster' to other pesticides results in many cases in an expension of pesticidal spectrum of activity or in a prevention of pesticide resistance development. Furthermore, in many cases, synergistic effects are obtained. In various embodiments, the organic acid consists essentially of acetic acid, preferably acetic acid from a fermentation. The formulation is typically applied to agricultural soil or plant material. In a particular, the present invention can be used in combination with a carrier selected from the plant growth nutrient, organic fertilizer or inorganic/organic mixture fertilizer. Although the following description relates almost exclusively to managing basal stem rot (BSR) disease in oil palm primarily caused by Gonoderma species. It will be appreciated by those skill in the art that the invention could be used to treat other diseases and pests of other plants, includes but is not limited to a fungus, bacteria, actinomycete, virus, insects, Acari and/or nematodes.
专利号:EP-3650430-A1 优先权日:2015-05-12 标题 :Intermediates and processes for the synthesis of herbicides
专利号:CN-102584681-A 优先权日:2011-01-12 标 题:One-step Synthesis of High Purity Plant Growth Regulator Dibenzylamine
专利号:WO-2021069704-A1 优先权日:2019-10-11 标 题:Active compound combinations 发明人:GÖRTZ ANDREAS; KLÜKEN MICHAEL; MONTAGNE CYRIL; ES-SAYED MAZEN 权利人:BAYER AG 摘要:The present invention relates to active compound combinations comprising N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylimidoformamide, at least one fungicide selected from specified inhibitors of the ergosterol synthesis or from specified compounds capable of having a multisite action, and at least one additional fungicide selected from inhibitors of the ergosterol synthesis or from compounds capable of having a multisite action, to compositions comprising such compound combination, and to the use thereof as biologically active agents, especially for control of harmful microorganisms in crop protection and in the protection of industrial materials.
[参考文献]: A A Gevorgian, Et Al. [参考文献]: Gig Sanit. 1986 Apr:(4):72. [参考文献]: Enrico Defranchi, Et Al. Feasibility Assessment Of Micro-Electrode Chip Assay As A Method Of Detecting Neurotoxicity In Vitro. Front Neuroeng. 2011 Apr 28:4:6. [参考文献]: Fengzu Zhang, Et Al. Dissipation And Residue Behavior Of Mepiquat On Wheat And Potato Field Application. Environ Monit Assess. 2013 Nov;185(11):9101-9. [参考文献]: Guo-Qiang Hu, Et Al. [参考文献]: Zhongguo Zhong Yao Za Zhi. 2012 Nov;37(21):3215-8. [参考文献]: H Karasali, Et Al. Hplc Determination Of Mepiquat Chloride In Commercial Pesticide Formulations. Bull Environ Contam Toxicol. 2009 Nov;83(5):636-9.
合成参考文献
摘要:Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan., 17(S269), 1992 摘要:USDA; Agric Res Service. ARS Pesticide Properties Database on Mepiquat chloride (24307-26-4). Available from, as of Oct 1, 2002: 摘要:O'Neil, M.J. (ed.). The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. 13th Edition, Whitehouse Station, NJ: Merck and Co., Inc., 2001., p. 1047 参考文献:10.2116/analsci.31.1011 摘要:Li H, Liu J, Yang X. Facile Synthesis of Glutathione-capped CdS Quantum Dots as a Fluorescence Sensor for Rapid Detection and Quantification of Paraquat. Analytical Sciences. 2015 Oct 10;31(10):1011–7. doi: 10.2116/analsci.31.1011.