CAS: 1983-27-3; Dichloro-(Chloromethyl)-Sulfanylidene-λ5-Phosphane
该化合物是有机磷化合物,其特点是磷硫-硫联结和氯甲基功能组,这种化合物一般是淡黄色液体无色的,由于氯原子的存在,可参与核生殖替代反应,因此以其反应为名.它主要用于各种化学中间体的合成,并应用于农药和其他农用化学品的生产.磷酰胺的存在,带来具体的生物活动,使其在化学生物学和毒理学领域引起兴趣.然而,由于其潜在的毒性和再活性,必须经过适当的安全规程加以谨慎处理.其物理和化学特性,如沸点,密度和溶性,可因环境条件和其他物质的存在而变化.
- 英文名称Dichloro-(Chloromethyl)-Sulfanylidene-λ5-Phosphane
- 中文名称氯甲基硫膦
- IUPAC名称dichloro-(chloromethyl)-sulfanylidene-λ5-phosphane
- 其它别名Phosphonothioicdichloride, (chloromethyl)- (6CI,7CI,8CI,9CI); (Chloromethyl)phosphonothioicdichloride; (Chloromethyl)phosphonothioyl dichloride; (Chloromethyl)thiophosphonic dichloride
- CAS编号1983-27-3
- MFCD编号:MFCD00015876
- 分子式:CH2Cl3PS分子量:183.42
- 产品CID: 1009206
- 产品分类有机原料 → 有机膦化合物
- 相似结构搜索
- 产品信息参考
;;; - InChIKey: HRHKZXIMFUYRDS-UHFFFAOYSA-N
- 1S/CH2Cl3PS/c2-1-5(3,4)6/h1H2
- 计算化学: 氢键受体数1.0氢键供体数*可旋转键数1.0
物理性质
MSDS等安全信息
上下游产品
[1,3,5]trithiane chloromethylphosphonic dichloride 12H18ClN2O3PSC12H18ClN2O3PS 12H18Cl2NOPSC12H18Cl2NOPS O-2-Chlor-4-methylphenyl-N-s-butylchlormethylphosphon-amidothioat合成工艺路线路线简述
- 合成目标产物 Chloromethylphosphonothioic Dichloride 主要起始原料 Chloromethylphosphonic Dichloride
- (文献来源)合成步骤主要原料 Chloromethylphosphonic Dichloride
📜1,3,5-三噻烷置于三氯化磷体系中,用 Neat (No Solvent) 用作溶剂,化学反应 3.0H,以13.9%的收率获得氯甲基硫膦
参考文献:Golovanov,A. V.; Maselnnikov,I. G.; Kornilova,T. V.,Journal Of General Chemistry Of The Ussr,1986,Vol. 56,P. 847
标题:Golovanov,A. V.; Maselnnikov,I. G.; Kornilova,T. V.,Journal Of General Chemistry Of The Ussr,1986,Vol. 56,P. 847
海关参考信息
- 2903110000-一氯甲烷及氯乙烷
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Mild Synthesis Of Organophosphorus Compounds: Reaction Of Phosphorus-Containing Carbenoids With Organoboranes作者:Monika I. Antczak,Jean-Luc Montchamp |发布日期:2008.3.1
摘要:Organoboranes React With Phosphorus-Containing Carbenoids To Produce A Variety Of Functionalized Organophosphorus Compounds Under Mild Conditions. In Some Cases, Selective Migration Of One Group Attached To Boron Can Be Observed. Phosphonite-Borane Complexes Are Introduced As Novel Synthons For The Synthesis Of Phosphinic Esters.
合成参考文献
参考文献:10.1007/bf00907633
摘要:Genkina GK, Gilyarov VA. Synthesis of bis (chloromethyl)chlorophosphine. Russian Chemical Bulletin. 1969 Jan;18(1):181–2. doi: 10.1007/bf00907633.
参考文献:10.1007/10653318_206
摘要:Graner G, Hirota E, Iijima T, Kuchitsu K, Ramsay DA, Vogt J, Vogt N. CH2Cl3PS (Chloromethyl)phosphonothioic dichloride. 1999. In: Molecules containing One or Two Carbon Atoms. : Springer-Verlag; 1999.
参考文献:10.1134/s1070363207080300
摘要:Bagautdinova RK, Pudovik MA. Reaction of chloromethylphosphonylated isothiocyanates with (1-phenylethyl)amine. Russian Journal of General Chemistry. 2007 Aug;77(8):1466–7. doi: 10.1134/s1070363207080300.
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