CAS: 18339-94-1; 1,1-Dimethylsila-11-Crown-4

该化合物是一个循环硅烷化合物,其独特结构在循环框架内结合硅原子和氧原子.该化合物具有硅烷环,共由11个原子组成,包括4个氧原子和1个硅原子,与碳原子交接.二甲基组的存在有助于其消毒特性,并可能影响其再活性和溶解性.一般而言,这种性质的化合物表现出令人感兴趣的化学行为,包括在材料科学中的潜在应用,特别是由于其稳定性和独特的机械特性,在聚合物和涂层方面的潜在应用.此外,结构中的氧原子可以增强化合物在各种溶剂中的极性和溶解性.

结构式图片

上下游产品

dimethylsilicon dichloride 2,2'-[1,2-ethanediylbis(oxy)]bisethanol

合成工艺路线路线简述

    📜二氯二甲基硅烷,三乙二醇 反应生成1,1-二甲基硅-11-冠-4
    参考文献:Krieble; Burkhard,Journal Of The American Chemical Society,1947,Vol. 69,P. 2691 Anm.13
    标题:Krieble; Burkhard,Journal Of The American Chemical Society,1947,Vol. 69,P. 2691 Anm.13

    海关参考信息

    专利信息


    专利号:US-5393511-A
    优先权日:1988-10-10
    标题 :Synthesis of zeolites of faujasite structure
    发明人:DELPRATO FRANCOIS; GUTH JEAN-LOUIS; ANGLEROT DIDIER; ZIVKOV CATHERINE
    权利人:ELF AQUITAINE
    摘要:A process is provided for the preparation of zeolites belonging to the faujasite structural class and exhibiting a Si:Al ratio higher than 1 in which a reaction mixture is first produced, which has a pH higher than 10 and contains water, a source of tetravalent silicon, a source of trivalent aluminum, a source of hydroxide ions in the form of a strong inorganic or organic base and a structuring agent ST so as to produce an aluminosilicate gel having the desired composition to permit its crystallization into a compound of the faujasite structural class. The gel obtained is kept at a temperature, pressure and for a sufficient period to effect the crystallization of the gel into a precursor of the zeolite consisting of the zeolite trapping the structuring agent ST in its cavities and the precursor is then subjected to a calcination to destroy the structuring agent and to produce the zeolite. The structuring agent ST consists of at least one compound belonging to the group formed by the carbon-containing macrorings and macropolyrings which contain in the rings heteroatoms chosen from oxygen, nitrogen, silicon and sulphur, and which contain 10 to 24 atoms per ring. Precursors of the zeolites are also provided.

    专利号:US-5098686-A
    优先权日:1988-10-10
    标题 :Synthesis of zeolites of faujasite structure
    发明人:DELPRATO FRANCOIS; GUTH JEAN-LOUIS; ANGLEROT DIDIER; ZIVKOV CATHERINE
    权利人:ELF AQUITAINE
    摘要:PCT No. PCT/FR89/00522 Sec. 371 Date Jun. 8, 1990 Sec. 102(e) Date Jun. 8, 1990 PCT Filed Oct. 10, 1989 PCT Pub. No. WO90/03944 PCT Pub. Date Apr. 19, 1990.A process is provided for the preparation of zeolites belonging to the faujasite structural class and exhibiting a Si:Al ratio higher than 1 in which a reaction mixture is first produced which has a pH higher than 10 and contains water, a source of tetravalent silicon, a source of trivalent aluminum, a source of hydroxide ions in the form of a strong inorganic or orgnaic base and a structuring agent ST so as to produce an aluminosilicate gel having the desired composition to permit its crystallization into a compound of the faujasite structural class. The gel obtained is kept at a temperature, pressure and for a sufficient period to effect the crystallization of the gel into a precursor of the zeolite consisting of the zeolite trapping the structuring agent ST in its cavities and the precursor is then subjected to a calcination to destroy the structuring agent and to produce the zeolite. The structuring agent ST consists of at least one compound belonging to the group formed by the carbon-containing macrorings and macropolyrings which contain in the rings, heteroatoms chosen from oxygen, nitrogen, silicon and sulphur, and which contain 10 to 24 atoms per ring. Precursors of the zeolites are also provided.

    专利号:WO-9003944-A1
    优先权日:1988-10-10
    标 题 :Synthesis of zeolites having a faujasite structure

    专利号:EP-0364352-A1
    优先权日:1988-10-10
    标 题:Method for the synthesis of zeolites belonging to the structural family of faujasite, products obtained and their use in adsorption and catalysis

    专利号:EP-0364352-B1
    优先权日:1988-10-10
    标 题:Method for the synthesis of zeolites belonging to the structural family of faujasite, products obtained and their use in adsorption and catalysis

    专利号:US-5304601-A
    优先权日:1990-04-09
    标题 :Catalysts based on a faujasite and its application
    发明人:DES COURIERES THIERRY; GUTH JEAN-LOUIS; PATARIN JOEL; ZIVKOV CATHERINE
    权利人:ELF AQUITAINE
    摘要:PCT No. PCT/FR91/00287 Sec. 371 Date Jan. 17, 1992 Sec. 102(e) Date Jan. 17, 1992 PCT Filed Apr. 8, 1991 PCT Pub. No. WO91/15293 PCT Pub. Date Oct. 17, 1991.A catalyst is provided which contains 1 to 99 wt. % of an inorganic binder and 99 to 1% of a zeolite consisting of a faujasite having an Si:Al synthesis ratio at least equal to 3 and 30 and the compensation cations of this zeolite consist partly or wholly of cations of one or more elements chosen from H, B, Al, Ga, In, rare earth metals and transition metals. The catalyst can also contain up to 15%, referred to the total weight of the binder and zeolite, of a catalytically active metal of the noble, non-noble transition or other type which is not already present in the compensation cations of the zeolite. The catalyst can be used in acid catalysis reactions carried out on hydrocarbon feedstock, in particular in fluidized bed catalytic cracking.

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