CAS: 3446-90-0; 4-(Methylthio)Benzyl Alcohol

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CAS号3446-89-7 甲硫基苯甲醛 | CAS号13205-48-6 4-甲硫基苯甲酸 | CAS号38185-19-2 4-(甲硫基)溴苄 | CAS号3795-79-7 4-(甲基硫代)苯甲酸甲酯 | CAS号38185-19-2 4-(甲硫基)溴苄 | CAS号40517-43-9 1-(氯甲基)-4-(甲基磺酰基)苯 | CAS号4052-30-6 4-甲砜基苯甲酸 | CAS号13205-48-6 4-甲硫基苯甲酸 | CAS号33963-58-5 4-甲亚砜基苯甲酸 | CAS号38746-92-8 2-(4-(甲硫基)苯基)乙腈 | CAS号3446-89-7 甲硫基苯甲醛 | CAS号37794-15-3 p-(methylsulphi... | CAS号3795-79-7 4-(甲基硫代)苯甲酸甲酯

4-(甲基硫代)苯甲酸甲酯置于hn(Ch2Ch2C3H3N2Mes)2Cl2,Potassium Tert-Butylate,氢气,Cobalt(II) Chloride体系中,用 四氢呋喃 用作溶剂,100.0 °C,6.0 Mpa 条件下,反应 16.0H,以85%的收率获得对甲硫基苯甲醇
参考文献:酯的一般和无磷钴催化的加氢生成醇†
标题:酯的一般和无磷钴催化的加氢生成醇†
摘要:酯的催化加氢对于有机合成和化学工业中酒精的可持续生产至关重要.本文中,我们描述了第一个非贵金属催化系统,该系统能够在不存在膦配体的情况下将未活化的酯有效地氢化为醇(最大转换数为2391).39种酯类底物(包括芳族/脂肪族酯,内酯,聚酯和各种药物分子)的高产氢化证明了该方案的普遍适用性.
Doi:10.1002/cjoc.201900292

专利信息

专利号:US-6093799-A
优先权日:1998-03-16
标题:Universal linker for combinatorial synthesis
发明人：LI GE; GRIFFITHS SIAN LOUISE; MCDONALD EDWARD; XU LIBO
权利人:PHARMACOPEIA INC
摘要:A substrate for solid phase synthesis of the formula: ##STR1## is disclosed. Also disclosed are processes for preparing the substrate and intermediates useful therein. Among the novel intermediates are compounds of the formula: ##STR2## wherein t is 0 or 1; n is 3-20; R is OH, an activated ester or the residue of a solid support having a plurality of amino functionalities; A is --O-- or --NH-- and Q is hydrogen or a protecting group for an amine or alcohol.

专利号:CN-102827042-A
优先权日:2012-09-17
标 题:Chiral synthesis of Florfenicol

专利号:BR-112016017141-A2
优先权日:2014-04-16
标 题:METHOD FOR THE SYNTHESIS OF FLORFENICOL

专利号:CN-109809967-A
优先权日:2019-03-04
标题:A kind of method of synthesis of chiral alcohol

专利号:US-2008176865-A1
优先权日:2005-06-15
标 题:Substituted arylpyrazoles
发明人：BILLEN DENIS; BOYLE JESSICA; CRITCHER DOUGLAS JAMES; GETHIN DAVID MORRIS; HALL KIM THOMAS; KYNE GRAHAM MICHAEL
权利人:PFIZER LTD
摘要:This invention relates to a range of 1-aryl-4-cyclopropylpyrazoles in which the cyclopropyl ring is substituted at the angular position, and pharmaceutically acceptable salts and solvates thereof, to compositions comprising such compounds, processes to their synthesis and their use as parasiticides.

专利号:CN-102827042-B
优先权日:2012-09-17
标 题 :Chiral synthesis method of florfenicol