CAS: 2359-09-3; 5-(Tert-Butyl)Isophthalic Acid

上下游产品

CAS号186581-53-3 重氮甲烷 | CAS号124-38-9 二氧化碳 | CAS号98-19-1 5-叔丁基间二甲苯 | CAS号108-38-3 间二甲苯 | CAS号630-19-3 三甲基乙醛 | CAS号127-17-3 丙酮酸 | CAS号20330-45-4 N-[4-(1,1-二甲基乙基... | CAS号42265-67-8 4-叔丁基-2-氯苯胺 | CAS号100141-30-8 N-(4-(TERT-BUTY... | CAS号13239-25-3 5-tert-butylben... | CAS号16308-65-9 甲基 5-叔-丁基-异邻苯二甲酸酯二酯 | CAS号377731-29-8 5-TERT-BUTYL-IS...

📜间二甲苯置于aluminum (III) Chloride,Potassium Permanganate,Sodium Carbonate体系中,用 二氯甲烷,水,叔丁醇 用作溶剂,化学反应 2.5H,反应生成5-叔丁基-1,3-苯二羧酸
参考文献:[2 + 3]-亚胺笼的动态共价化学检查.
标题:[2 + 3]-亚胺笼的动态共价化学检查.
摘要:通过形成亚胺键来合成形状持久的有机笼状化合物,开辟了实现具有不同尺寸,几何形状,拓扑和功能的笼状结构的可能性.通常认为亚胺键在化学上相当不稳定,允许自校正机制直至达到热力学平衡,这通常在形成笼子的情况下发生.但是,此假设有一些矛盾的实验数据.为了更深入地了解共价有机笼的亚胺键动力学,我们借助氘代二醛分子构件研究了两个不同[2 + 3]亚胺笼的二醛和三胺的形成和交换.
Doi:10.1021/acs.Joc.0C01887

专利信息

专利号:US-12263464-B2
优先权日:2018-03-14
标题 :Method for in-situ synthesis of metal organic frameworks (MOFs), covalent organic frameworks (COFs) and zeolite imidazolate frameworks (ZIFs), and applications thereof
发明人：PAHWA DEEPAK; PAHWA VARUN; CHOUDHARY ANIL KUMAR; SONIA; JHA VIVEK KUMAR; CHAUHAN ANJALI; YADAV ANNU
权利人:DESICCANT ROTORS INTERNATIONAL PRIVATE LTD
摘要:The present invention relates to a method for the in situ synthesis of of MOFs (metal organic frameworks), COFs (covalent organic frameworks), and ZIFs (Zeolitic imidazolate framework), onto and within different types of porous substrates, and their applications. The present invention provides a unique and easy to utilize method by which a number of MOFs, COFs and ZIFs can be synthesized directly onto and within a porous substrate with high performance efficiency ensuring higher grammage in formation of adsorbent product onto and within the substrate.

专利号:US-2022089618-A1
优先权日:2019-01-29
标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks
发明人：MAJANO GERARDO J; FALKOWSKI JOSEPH M
权利人:EXXONMOBIL RES & ENG CO
摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.

专利号:US-10737239-B2
优先权日:2015-11-27
标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks
发明人：BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich
权利人:BASF SE
摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.

专利号:US-9951095-B2
优先权日:2014-05-16
标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks
发明人：ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI
权利人:TEXAS A & M UNIV SYS
摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

专利号:US-9604902-B2
优先权日:2013-03-15
标 题 :Selective synthesis of 2-octyl acrylate by acid catalyzed esterification of 2-octanol and acrylic acid
发明人：COLBY JOSHUA L; CLEM TABITHA A; SPAWN TERENCE D; HUTT AARON E; TEPLY WADE T
权利人:3M INNOVATIVE PROPERTIES CO
摘要:A method of making 2-octyl acrylate comprising reacting 2-octanol with acrylic acid in the presence of an acid catalyst and added water is described. The 2-octanol may be derived from renewable resources, such as castor oil. The method is efficient and provides selectivity for 2-octyl acrylate.

专利号:US-11891406-B2
优先权日:2019-03-14
标题:Conductivity enhancement of MOFs via development of MOFpolymer composite material
发明人：PEEDIKAKKAL ABDUL MALIK P; AL-BETAR ABDUL-RAHMAN; AL-MOUSA AMMAR HUSSAIN
权利人:UNIV KING FAHD PET & MINERALS
摘要:A method for enhancing the conductivity of MOF-5 by the development of an MOF-5 polymer composite material. The composite material incorporates a conductive polymer, preferably polyaniline, in the solvo-thermal synthesis pathway of MOF-5. The electrically conductive MOF-5 composite exhibits electric conductivity three orders of magnitude higher than that of MOF-5 while maintaining the crystallinity, robustness, and thermal stability of MOF-5.