CAS: 2208-05-1; 2-(Dimethylamino)Ethyl Benzoate

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CAS号108-01-0 2-(二甲基氨基)乙醇 | CAS号98-88-4 苯甲酰氯 | CAS号4584-46-7 二甲氨基氯乙烷盐酸 | CAS号65-85-0 苯甲酸 | CAS号1711-02-0 4-碘苯甲酰氯 | CAS号26926-35-2 Benzoesaeure-me... | CAS号93-89-0 苯甲酸乙酯 | CAS号93-97-0 苯甲酸酐 | CAS号582-25-2 苯甲酸钾 | CAS号2964-09-2 苯甲酰氯化胆碱 | CAS号17518-43-3 苯甲酰碘化胆碱

📜4-碘苯甲酰氯置于n-甲基吡咯烷酮,Platinum(Iv) Oxide,Sodium Acetate,三乙胺体系中,用 二氯甲烷 用作溶剂,化学反应 5.5H,反应生成苯甲酸二甲基氨基乙酯
参考文献:Platinum Oxide Catalyzed Silylation Of Aryl Halides With Triethylsilane: An Efficient Synthetic Route To Functionalized Aryltriethylsilanes
标题:Platinum Oxide Catalyzed Silylation Of Aryl Halides With Triethylsilane: An Efficient Synthetic Route To Functionalized Aryltriethylsilanes
摘要:The First Platinum-Catalyzed Selective Silylation Of Aryl Halides Including Aryl Iodides And Bromides Having An Electron-Withdrawing Group Is Described. The Reaction Takes Place Rapidly In Nmp With Triethylsilane As A Silicon Source And Sodium Acetate To Provide Functionalized Aryltriethylsilanes In Moderate To Good Yields. Heteroaromatic Halides Also Were Found To Be Readily Silylated With Triethylsilane. The Procedure Is Chemoselective And Tolerates A Wide Variety Of Functional Groups.
Doi:10.1021/ol052996U

专利信息

专利号:US-9867899-B2
优先权日:2010-05-24
标题 :Reinforced adhesive complex coacervates and methods of making and using thereof
发明人：STEWART RUSSELL J
权利人:UNIV UTAH RES FOUND
摘要:Described herein is the synthesis of reinforced adhesive complex coacervates and their use thereof. The reinforced adhesive complex coacervates are composed of (a) at least one polycation, (b) at least one polyanion, and (c) a reinforcing component. The adhesive complex coacervates described herein can be subsequently cured to produce strong, cohesive adhesives. The reinforced adhesive complex coacervates have several desirable features when compared to conventional adhesives. The reinforced adhesive complex coacervates are effective in wet or underwater applications. The reinforced adhesive complex coacervates described herein, being phase separated from water, can be applied underwater without dissolving or dispersing into the water. The reinforced adhesive complex coacervates have numerous biological applications as bioadhesives and bioactive delivery devices. In particular, the reinforced adhesive complex coacervates described herein are particularly useful in underwater applications and situations where water is present such as, for example, wet tissues in physiological conditions.

专利号:US-2014220082-A1
优先权日:2011-06-28
标 题:Adhesive complex coacervates and methods of making and using thereof
发明人：STEWART RUSSELL J
权利人:STEWART RUSSELL J; UNIV UTAH RES FOUND
摘要:Described herein is the synthesis of adhesive complex coacervates and their use thereof. The adhesive complex coacervates are produced by reacting (a) at least one poly anion comprising a plurality of activated ester groups, and (b) at least one polycation comprising a plurality of nucleophilic groups, wherein the nucleophilic groups react with the activated ester groups to produce a new oovalent bond between the polycation and the polyanion. The adhesive complex coacervates described herein have low interfacial tension with water and wettable substrates. When applied to a wet substrate they spread over the interface rather than beading up. The adhesive complex coacervates have numerous biological applications as bioadhesives and drug delivery devices. In particular, the adhesive complex coacervates described herein are particularly useful in wet or underwater applications and situations where water is present such as, for example, physiological conditions.

专利号:US-9999700-B1
优先权日:2010-11-12
标 题 :Simple coacervates and methods of use thereof
发明人：STEWART RUSSELL J
权利人:UNIV UTAH RES FOUND
摘要:Described herein is the synthesis of adhesive from simple adhesive coacervates and their uses thereof. The adhesives are composed of (a) a polyanion in the absence of a polycation, wherein the polyanion comprises at least one crosslinking group capable of covalently crosslinking with itself, and (b) a sufficient amount of a complimentary multivalent cation or multivalent anion to produce the simple coacervate. The adhesives have numerous medical and non-medical applications.

专利号:US-8137582-B2
优先权日:2007-08-15
标题 :Alkaloid monomers, liquid crystal compositions and polymer networks derived therefrom
发明人：GOLDFINGER MARC B; QI KAI
权利人:GOLDFINGER MARC B; QI KAI; DU PONT
摘要:Disclosed is the chemical synthesis of chiral alkaloid monomers, liquid crystal compositions comprising the chiral alkaloid monomers, and polymerization of the liquid crystal compositions to provide polymer networks with useful cholesteric optical properties and stability.