专利号:US-2009043069-A1 优先权日:2007-08-06 标 题 :Activated esters for synthesis of sulfonated telechelic polycarbonates 发明人:BRUNELLE DANIEL J; COLONNA MARTINO; FIORINI MAURIZIO; BERTI CORRADO; BINASSI ENRICO 权利人:GEN ELECTRIC 摘要:A process of making a sulfonated telechelic polycarbonate is described. A dihydroxy compound, a carbonate ester, and an activated ester of a sulfobenzoic acid salt are reacted together. The method results in a sulfonated telechelic polycarbonate which has a high percentage of sulfonated end groups, is soluble, and is transparent.
专利号:US-6545187-B1 优先权日:2001-09-19 标 题 :Production of low-particulate bisphenol and use thereof in the manufacturing of polycarbonate 发明人:KISSINGER GAYLORD MICHAEL; CHEN FANG CHRISTINE; BLUBAUGH JAMES CRISTOPHER; NANCE DARLENE HOPE; STOKES EDWARD BRITTAIN; ORDONEZ JUAN RODRIGUEZ; QUINTANA JOSE M 权利人:GEN ELECTRIC 摘要:Low-particulate dihydric aromatic compounds such as bisphenol-A that can be used in the synthesis of low-particulate polycarbonates are prepared by introducing into a desorber column containing a non-aggregate packing material an adduct of bisphenol and phenol and optionally a stripping gas. The column is maintained at an operating temperature that is sufficiently high and an operating pressure that is sufficiently low such that the adduct is distilled. The stream of phenol and the stripping gas is recovered from the top of the column. A second stream containing bisphenol that is substantially free of added particulate matter is recovered from the bottom of the column. This purified stream of bisphenol-A can further be used in a method of producing optical-grade polycarbonate.
专利号:US-4404363-A 优先权日:1981-05-02 标题 :Separation of diphasic mixtures containing aromatic polyesters 发明人:FREITAG DIETER; SERINI VOLKER; GOOSSENS JOHN; BOTTENBRUCH LUDWIG; HUCKS UWE 权利人:BAYER AG 摘要:Diphasic mixtures obtained from the synthesis of aromatic polyesters by the diphasic interface process may be separated into an aqueous phase and an organic phase by the addition of selected compounds.
专利号:US-8394912-B2 优先权日:2009-12-22 标 题 :Process and apparatus for the preparation of polycarbonate 发明人:DOEBERT FRANK; STREMMEL ANDREAS; BIEDRON CHRISTOPH; LAUE STEPHAN; RECHNER JOHANN; HAGEN TORSTEN; BRUYNSEELS FRANK; QUAEYHAEGENS FRANK; DECLOEDT JOHAN; VAN DORST PAUL; ARNDT UWE; EYNDE JOHAN VANDEN; TRACHT URSULA; KOENIG THOMAS; LIESENFELDER ULRICH 权利人:DOEBERT FRANK; STREMMEL ANDREAS; BIEDRON CHRISTOPH; LAUE STEPHAN; RECHNER JOHANN; HAGEN TORSTEN; BRUYNSEELS FRANK; QUAEYHAEGENS FRANK; DECLOEDT JOHAN; VAN DORST PAUL; ARNDT UWE; EYNDE JOHAN VANDEN; TRACHT URSULA; KOENIG THOMAS; LIESENFELDER ULRICH; BAYER MATERIALSCIENCE AG 摘要:The invention relates to a process for the pretreatment of material surfaces in order to minimize the interaction between polycarbonate and metal and, in the processing and synthesis of polycarbonate, to obtain a high-quality polymer which in particular does not become discolored and is free of insoluble constituents.
专利号:WO-2023038267-A1 优先权日:2021-09-13 标 题 :Monomer composition for synthesis of recycled plastic, method for preparing same, and recycled plastic and molded product using same
专利号:US-8309655-B2 优先权日:2009-12-22 标题 :Methods for the preparation of a poly(arylene ether) polysiloxane multiblock copolymer, multiblock copolymers produced thereby, and associated compositions and articles 发明人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT 权利人:KAMALAKARAN RADHA; SRINIVASAN VEERARAGHAVAN; CHOWDHURY RAJESH; KARAMBELKAR VIVEK VASANT; SABIC INNOVATIVE PLASTICS IP 摘要:A poly(arylene ether)-polysiloxane multiblock copolymer is prepared by the reaction of a hydroxy-diterminated poly(arylene ether), a hydroxyaryl-diterminated polysiloxane, and an aromatic diacid chloride. This synthesis overcomes disadvantages of known syntheses of poly(arylene ether)-polysiloxane block copolymers. The poly(arylene ether)-polysiloxane multiblock copolymer is useful for improving the melt processability of poly(arylene ether) compositions.
参考标题:Redox‐neutral Coupling Between Two C(Sp 3 )−h Bonds Enabled By 1,4‐palladium Shift For The Synthesis Of Fused Heterocycles 作者:Ronan Rocaboy,Ioannis Anastasiou,Olivier Baudoin |发布日期:2019.10.7 摘要:Secondary C-H Bonds, Which Are Adjacent To An Oxygen Or Nitrogen Atom On One Side, And Benzylic Or Adjacent To A Carbonyl Group On The Other Side. A Variety Of Valuable Fused Heterocycles Were Obtained From Easily Accessible Ortho-Bromophenol And Aniline Precursors. The Second C-H Bond Cleavage Was Successfully Replaced With Carbonyl Insertion To Generate Other Types Of C(Sp3 )-C(Sp3 ) Bonds.
合成参考文献
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