CAS: 7351-61-3; 3-(Trichlorosilyl)Propyl Methacrylate

该化合物是一种有机硅化合物,其特点是存在一种甲基丙烯酸化合物功能组和一个三氯硅酸化合物组,该化合物一般是淡黄色液体的无色,由于存在甲基丙烯酸双联和三氯硅酸基混合物而以其反应性而闻名.甲基丙烯酸酯组允许聚合,使其在合成各种聚合材料时有用,而三氯硅酸盐组则能够促进与表面的结合,增强粘合性.该化合物通常用于涂层,粘合剂和密封剂等需要改进耐久性和化学抗药性的应用中.此外,氯原子的存在会影响化合物的活性和稳定性,因此,由于潜在的毒性和环境考虑,必须谨慎处理.适当的储存和处理程序对于在与该物质打交道时确保安全至关重要.

结构式图片

相似化合物

38595-89-0 24636-31-5 1888-94-4

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

allyl methacrylate trichlorosilane 3-(triacetoxysilyl)propyl methacrylate acetyl chloride hexaethyl disiloxane Methacrylsaeure-γ-triethylsilylpropylester

合成工艺路线路线简述

    📜甲基丙烯酸烯丙酯置于dihydrogen Hexachloroplatinate,吩噻嗪,三氯硅烷体系中,用 四氢呋喃 作为反应溶剂,化学反应 0.5H,以88%的收率获得产物甲基丙烯酸丙基三氯硅烷
    参考文献:Efimov,Yu. T.; Tandura,T. A.; Kopylov,V. M.,Journal Of General Chemistry Of The Ussr,1991,Vol. 61,# 10,P. 2083-2091
    标题:Efimov,Yu. T.; Tandura,T. A.; Kopylov,V. M.,Journal Of General Chemistry Of The Ussr,1991,Vol. 61,# 10,P. 2083-2091

    海关参考信息

    专利信息


    专利号:US-6136926-A
    优先权日:1996-07-22
    标 题 :Cross-linkable, olefinic polymers and methods for their synthesis
    发明人:RAETZSCH MANFRED; HESSE ACHIM; BUCKA HARMUT; LEISTNER DIRK; IVANCHEV SERGEJ; HEIKIN SAUL; MESH ALLA; PUKSCHANSKI MOISEJ
    权利人:BOREALIS GMBH
    摘要:Cross-linkable, olefinic polymers synthesized from mixtures of olefinic polymers and ethylenically unsaturated organosilane compounds, which can be grafted, by a 2-step method using thermally decomposing free radical-forming agents by heating the mixtures to a temperature of 30 DEG to 110 DEG C. below the softening temperature or the crystallite melting point of the olefinic polymers used and subsequently heating the mixtures to a reaction temperature of 10 DEG to 60 DEG C. below the softening temperature or the crystallite melting point of the olefinic polymers used. In the alternative, they can be grafted by a method involving the action of ionizing radiation with simultaneous absorption of organosilane compounds and the action of radiation. The method is suitable for producing films, sheets, fibers, panels, coatings, pipes, hollow objects, foamed materials and molded articles.

    专利号:US-9416147-B2
    优先权日:2014-04-03
    标题 :Preparation of silazane compound
    发明人:TONOMURA YOICHI; KUBOTA TOHRU
    权利人:SHINETSU CHEMICAL CO
    摘要:A silazane compound useful as synthesis intermediates for paint additives, polymer modifiers, pharmaceuticals and agricultural chemicals is efficiently prepared by reaction of a halosilane compound with an amino-containing compound in a solvent which is the same silazane compound as the target product.

    专利号:US-10954139-B2
    优先权日:2015-12-11
    标 题:Oleophilic foams for oil spill mitigation
    发明人:DARLING SETH B; ELAM JEFFREY W; MANE ANIL U
    权利人:UCHICAGO ARGONNE LLC
    摘要:A method of fabricating an oleophilic foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD) or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with an oleophilic material.

    专利号:US-11351478-B2
    优先权日:2018-09-06
    标题 :Oil skimmer with oleophilic coating
    发明人:DARLING SETH B; ELAM JEFFREY W
    权利人:UCHICAGO ARGONNE LLC
    摘要:A method of fabricating an coating includes providing a coating comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the coating to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The coating is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.

    专利号:US-10870917-B2
    优先权日:2016-07-08
    标 题:Functionalized foams
    发明人:DARLING SETH B; ELAM JEFFREY W; MANE ANIL U; SNYDER SETH W
    权利人:UCHICAGO ARGONNE LLC
    摘要:A method of fabricating an foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Practical Conversion Of Chlorosilanes Into Alkoxysilanes Without Generating Hcl
    作者:Ryutaro Wakabayashi,Yasushi Sugiura,Toshimichi Shibue,Kazuyuki Kuroda |发布日期:2011.11.4
    摘要:Alcohol‐free: A Versatile, Efficient, And Practical Synthesis Of Alkoxysilanes Without Generation Of Hcl Involves The Reaction Of Chlorosilanes With Unsymmetrical Ethers In The Presence Of A Lewis Acid (See Scheme). The Reaction Proceeds Through Selective Cleavage Of Co Bonds And Is Superior To Conventional Processes. Industrially Feasible Reagents Are Used And Only One By‐product Results.

    合成参考文献


    参考文献:10.1002/jssc.201100225
    摘要:Fei T, Li H, Ding M, Ito M, Lin J. Determination of parabens in cosmetic products by solid‐phase microextraction of poly(ethylene glycol) diacrylate thin film on fibers and ultra high‐speed liquid chromatography with diode array detector. J of Separation Science. 2011 May 24;34(13):1599–606. doi: 10.1002/jssc.201100225.
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