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CAS号430-51-3 氟代丙酮 | CAS号503-09-3 环氧氟丙烷 | CAS号127-00-4 1-氯-2-丙醇 | CAS号5689-83-8 4-甲基-1,3,2-二氧硫杂... | CAS号75-56-9 环氧丙烷 | CAS号430-51-3 氟代丙酮 | CAS号70628-05-6 1-fluoropropan-...合成工艺路线路线简述
- 合成目标产物 1-Fluoro-2-Propanol 主要起始原料 Fluoroacetone
- (文献来源)合成步骤主要原料 Fluoroacetone
📜环氧氟丙烷置于lithium Aluminium Tetrahydride体系中,用 乙醚 作为反应溶剂,化学反应生成 1-氟丙烷-2-醇
参考文献:Use Of Substituent Effects On Isotope Effects To Distinguish Between Proton And Hydride Transfers. Part I. Mechanism Of Oxidation Of Alcohols By Bromine In Water1-3
标题:Use Of Substituent Effects On Isotope Effects To Distinguish Between Proton And Hydride Transfers. Part I. Mechanism Of Oxidation Of Alcohols By Bromine In Water1-3
摘要:
DOI:10.1021/ja01469A039
专利信息
专利号:WO-8911470-A1
优先权日:1988-05-27
标题 :Dihalogeno-3,3 fluoro-2 propenols-1, preparation method and utilization for the synthesis of fluoro-2 acrylic and dihalogeno-3,3 fluoro-2 acrylic acids and their derivatives
发明人:WAKSELMAN CLAUDE; NGUYEN THOAI; MOLINES HUGUETTE
权利人:CENTRE NAT RECH SCIENT
摘要:The invention relates to dihalogeno-3,3 fluoro-2 propenol-1 having the formula X?1X?2C=CF-CH2?OH (I), wherein X?1 and X?2, which may be identical or different, represent a fluorine, a chlorine or a bromine atom providing that X?1 and X?2 do not represent both a chlorine atom. These compounds may be prepared by reaction of an alcohol having the formula HCH?1X?2-CFX?3-CH2?OH (II), X?1 and X?2 have the meaning given hereabove and X?3 is a fluorine, chlorine or bromine atom, similar to or different from X?1 and/or X?2, with an organolithian compound. They may be used to prepare halides of the fluoro-2 acrylic acid and of the dihalogeno-3,3 fluoro-2 acrylic acids or their esters.
专利号:EP-0042408-A1
优先权日:1979-12-26
标 题 :METHODS OF SYNTHESIS OF HEXAFLUOROISOPROPANOL FROM IMPURE MIXTURES AND SYNTHESIS OF A FLUOROMETHYL ETHER.
专利号:WO-8101843-A1
优先权日:1979-12-26
标 题 :Methods of synthesizing hexafluoroisopropanol from impure mixtures and synthesis of a fluoromethyl ether therefrom
专利号:US-8252778-B2
优先权日:2006-03-24
标题:Highly fluorinated oils and surfactants and methods of making and using same
发明人:YU YIHUA; JIANG ZHONG-XING
权利人:YU YIHUA; JIANG ZHONG-XING; UNIV UTAH RES FOUND
摘要:Disclosed are compounds comprising the structure: n nIn one aspect, the compounds exhibit maximum symmetric branching. Also disclosed are bilayers, micelles, coatings, and nanoparticles comprising the disclosed compounds. Also disclosed are processes for the preparation of the disclosed compounds and methods of using the disclosed compounds. Also disclosed are highly fluorinated dendrons and methods for making same. Also disclosed are methods for Fluorous Mixture Synthesis and tagging. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.
专利号:JP-2004520449-A
优先权日:2001-06-05
标题 :Process for removing dimethyl ether in the synthesis of sevoflurane
专利号:JP-4162590-B2
优先权日:2001-06-05
标 题 :Process for removing dimethyl ether in the synthesis of sevoflurane