CAS: 26046-85-5; (1R,3R)-3-Phenoxybenzyl 2,2-Dimethyl-3-(2-Methylprop-1-En-1-yl)Cyclopropanecarboxylate

上下游产品

CAS号4489-14-9 (1R-trans)-2,2-... | CAS号13826-35-2 3-苯氧基苄醇

Ethyl 5-Methylhexa-2,4-Dienoate置于吡啶,草酰氯,C29H35Br2Con3,Sodium Hydroxide,Zinc Dibromide,锌体系中,用 四氢呋喃,甲醇,二氯甲烷,水,甲苯 用作溶剂,化学反应 40.25H,反应生成右旋苯醚菊酯
参考文献:钴催化的1,3-二烯的还原性二甲基环丙烷化
标题:钴催化的1,3-二烯的还原性二甲基环丙烷化
摘要:二甲基环丙烷是有价值的合成靶标,使用锌类胡萝卜素试剂难以获得高收率.在本文中,我们描述了席梦思-史密斯反应的钴催化变体,该变体使用me 2 Ccl 2 / Zn试剂混合物能够有效地进行1,3-二烯的二甲基环丙烷化.根据1,3-二烯的取代模式,反应具有很高的区域选择性.产品是乙烯基环丙烷,可作为过渡金属催化的开环反应的底物,包括1,3重排和[5 + 2]环加成反应.初步研究表明,在钴催化条件下,中等活化度的单烯烃也适用于二甲基环丙烷化.
Doi:10.1002/anie.201807542

专利信息

专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人：NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.

专利号:BR-112019014061-A2
优先权日:2017-01-23
标 题 :compounds of formula i, intermediates b, intermediates c, intermediates ii and intermediates d, composition, use, method to combat phytopathogenic fungi, seed and process for the synthesis of the compounds of formula i

专利号:US-2015272130-A1
优先权日:2012-12-03
标 题:Composition comprising a biological control agent and a fungicide
发明人：WACHENDORFF-NEUMANN ULRIKE; DAHMEN PETER; SAWADA HARUKO
权利人:BAYER CROPSCIENCE AG
摘要:The present invention relates to a composition comprising at least one biological control agent selected from the group consisting of Paecilomyces lilacinus strain 251 (AGAL No. 89/030550) and Coniothyrium minitans CON/M/91-08 (DSM 9660) and/or a mutant of these strains having all the identifying characteristics of the respective strain, and/or at least one metabolite produced by the respective strain that exhibits activity against nematodes, insects and/or phytopathogens, and at least one fungicide (I) selected from the group consisting of compounds capable to introduce a host defence, inhibitors of the amino acid and/or protein biosynthesis, inhibitors of the ATP production, inhibitors of the cell wall synthesis, inhibitors of the lipid and membrane synthesis, inhibitors of the melanine biosynthesis, inhibitors of the nucleic acid synthesis, inhibitors of the signal transduction, compounds capable to act as an uncoupler, and other fungicides in a synergistically effective amount. Furthermore, the present invention relates to a kit of parts comprising said composition and the use of said composition.

专利号:US-2015105251-A1
优先权日:2012-05-30
标 题 :Composition comprising a biological control agent and a fungicide selected from inhibitors of the lipid membrane synthesis, the melanine biosynthesis, the nucleic acid synthesis or the signal transduction

专利号:WO-2013178655-A1
优先权日:2012-05-30
标 题 :Composition comprising a biological control agent and a fungicide selected from inhibitors of the lipid membrane synthesis, the melanine biosynthesis, the nucleic acid synthesis or the signal transduction

专利号:US-2015250175-A1
优先权日:2012-10-01
标 题:Pesticidally active mixtures comprising anthranilamide compounds
发明人：KOERBER KARSTEN; WACH JEAN-YVES; KAISER FLORIAN; POHLMAN MATTHIAS; DESHMUKH PRASHANT; CULBERTSON DEBORAH L; ROGERS W DAVID; GUNJIMA KOSHI; DAVID MICHAEL; BRAUN FRANZ JOSEF; LANGEWALD JUERGEN
权利人:BASF SE
摘要:The present invention relates to pesticidal mixtures comprising as active compoundsn 1) at least one pesticidally active anthranilamide compound of formula (I) nn n n n n n n n n n wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and k are as defined in the description;n nandn 2) at least one pesticidally active compound II selected from a group M comprising acteylcholine esterase inhibitors, GABA-gated chloride channel antagonists, sodium channel modulators, nicotinic acteylcholine receptor agonists/antagonists, allosteric nicotinic acetylcholine receptor activitaors, chloride channel activators, juvenile hormone mimics, homopteran feeding blockers, mit grow inhibitors, inhibitors of mitochondrial bATP synthase, uncouplers of the oxidative phosphorylation, inhibitors of the chitin biosynthesis, moulting disruptors, ecdyson receptor agonists, octamin receptor agonists, inhibitors of the MET, voltage-dependent sodium channel blockers, inhibitors of the lipid synthesis, ryanodine receptor modulators and other compounds as defined in the description, in synergistically effective amounts. nn The invention relates further to methods and use of these mixtures for combating and controlling insects, acarids or nematodes in and on plants, and for protecting such plants being infested with pests, especially also for protecting plant propagation material, such as seeds.