四甲基氢氧化铵,溶剂黄146 以 甲醇 用作溶剂,化学反应 4.0H,以87.6%的收率获得四甲基醋酸铵 参考文献:Therapeutic Delivery Of Carbon Monoxide 标题:Therapeutic Delivery Of Carbon Monoxide 摘要:将含有co配体的锰配合物,额外卤素,一齿或双齿配体的化合物,药物组合物和方法,用于将一氧化碳治疗性地输送给人类和其他哺乳动物,其中额外的配体不在相对位置上占据反位.
专利信息
专利号:US-4451679-A 优先权日:1982-10-21 标题 :Alcohols and aldehydes prepared from olefins and synthesis gas 发明人:KNIFTON JOHN F; LIN JIANG-JEN; GRIGSBY JR ROBERT A; BRADER JR WALTER H 权利人:TEXACO INC 摘要:This invention concerns a process of preparing alcohols and aldehydes which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols and aldehydes.
专利号:US-10253165-B2 优先权日:2015-02-26 标 题 :Control of organic impurities in polycarbonate synthesis 发明人:BOJARSKI AARON DAVID; GARCIA AGUDO JORGE A 权利人:SABIC GLOBAL TECHNOLOGIES BV 摘要:Polymerization processes comprising melt polymerizing a carbonate and a dihydroxy compound in the presence of an amount of a beta organic catalyst so as to give rise to a polycarbonate product, wherein the amount of beta organic catalyst comprises at least one onium salt and also comprises triphenyl phosphonium oxide (TPPO), and wherein the TPPO represents less than about 0.3 weight % of the sum of the weights of the at least one onium salt and the TPPO in the amount of beta organic catalyst.
专利号:US-2008214386-A1 优先权日:2004-03-01 标题:Catalyst for Cyclic Carbonate Synthesis 发明人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU 权利人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU 摘要:Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.
专利号:US-2023093326-A1 优先权日:2020-06-19 标 题 :Polyester Carbonates on the Basis of Cycloaliphatic Diacids, 1,4:3,6-Dianhydrohexitol and Specific Amounts of an Additional Aliphatic Dihydroxy Compound 发明人:MEYER ALEXANDER; SCHULZ LUKAS FABIAN; PFINGST THOMAS 权利人:COVESTRO DEUTSCHLAND AG 摘要:The present invention relates to a process for preparing a polyester carbonate on the basis of cycloaliphatic diacids and at least one 1,4:3,6-dianhydrohexitol and at least one additional aliphatic dihydroxy compound, to the polyester carbonate prepared according to the process and to a molding compound and a molding body containing the polyester carbonate. The process according to the invention is a direct synthesis, in which all structural elements forming the subsequent polyester carbonate are present as monomers already in the first process step. It is characterized in that a specific ratio of 1,4:3,6-dianhydrohexitol and the at least one additional aliphatic dihydroxy compound is advantageous.
专利号:US-4268689-A 优先权日:1978-12-11 标 题 :Manufacture of vicinal glycol esters from synthesis gas 发明人:KNIFTON JOHN F 权利人:TEXACO DEVELOPMENT CORP 摘要:This invention concerns the improved preparation of glycol esters, such as ethylene glycol diesters, by reaction of carbon monoxide and hydrogen in the presence of a ruthenium or osmium-containing catalyst and a liquid phase medium containing a carboxylic acid co-reactant. The improvement which comprises the invention here also involves use of a co-catalyst species selected from the group consisting of one or more alkali metal salts, alkaline earth metal salts, quaternary ammonium salts, iminium salts and quaternary aliphatic phosphonium salts.
专利号:WO-9706170-A1 优先权日:1995-08-03 标题 :Processes for producing n,n'-difluorodiazoniabicyclo-alkane salts, intermediates in the synthesis of the same, target products, and application of the target products
摘要:Bystron, T.; Jirasko, M., Science of Synthesis: Hypervalent Halogens in Organic Synthesis, (2025) . 参考文献:10.1007/s00775-008-0361-z 摘要:Gabbiani C, Casini A, Mastrobuoni G, Kirshenbaum N, Moshel O, Pieraccini G, Moneti G, Messori L, Gibson D. Peculiar mechanistic and structural features of the carboplatin–cytochrome c system revealed by ESI-MS analysis. JBIC Journal of Biological Inorganic Chemistry. 2008 Mar 19;13(5):755–64. doi: 10.1007/s00775-008-0361-z.