CAS: 104-24-5; 4-Phenylazobenzoyl Chloride

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CAS号1562-93-2 偶氮苯-4-苯甲酸 | CAS号150-13-0 对氨基苯甲酸 | CAS号586-96-9 亚硝基苯 | CAS号29530-53-8 4-phenyldiazeny... | CAS号2918-88-9 Benzoic acid,4-... | CAS号24909-60-2 [(3S,8S,9S,10R,... | CAS号62625-24-5 4-苯基偶氮苯乙酰溴 | CAS号7508-68-1 Benzoic acid, 4...

📜亚硝基苯置于氯化亚砜,溶剂黄146体系中,用 甲苯 用作溶剂,化学反应 2.0H,反应生成4-苯基偶氮苯甲酰氯
参考文献:可见光通过偶氮苯-苯基吡唑对gaba受体的光学调控
标题:可见光通过偶氮苯-苯基吡唑对gaba受体的光学调控
摘要:光药理学为研究γ-氨基丁酸受体(gabars)的生物学功能提供了优越的时空分辨率,基于gabars的光药理学显着推进了神经元和细胞的研究.在此,我们报道了通过光控制 Gabars 功能的偶氮苯-苯基吡唑 ( Abps ).Abps对白纹伊蚊幼虫的杀虫活性在光照前后不同.Abp3 (1 μm) 可以诱导背侧未配对的正中神经元去极化,并实现对蚊子幼虫行为的实时光调节.电生理实验表明abp3光照前后对 Gabars 的抑制作用不同.Abps利用可见光实现了 Gabars 的光学控制,为现有的 Gabar 光控工具提供了有价值的补充.
Doi:10.1021/acs.Jafc.2C01463

专利信息

专利号:US-2024217941-A1
优先权日:2021-04-28
标题 :Ring closure of benzoquinones containing an unsaturated side chain using a basic catalyst
发明人：BONRATH WERNER; KUENZI ROLF; TIRPANCI MELTEM; NETSCHER THOMAS
权利人:DSM IP ASSETS BV
摘要:The present invention relates to the formation of compound of the formula (I) by a ring closure reaction of the compound of the formula (II) in the presence of a catalytic amounts of a base. It has been found that this reaction is very efficient and offers for example an efficient pathway for the synthesis of 3,4-dehydro-α-tocotrienol respectively α-tocotrienol and α-tocopherol.

专利号:US-2024228454-A1
优先权日:2021-04-28
标 题 :Ring closure of benzoquinones containing an unsaturated side chain using a base in two-phase system
发明人：BONRATH WERNER; KUENZI ROLF
权利人:DSM IP ASSETS BV
摘要:The present invention relates to the formation of compound of the formula (I) by a ring closure reaction of the compound of the formula (II) in the presence of a base in a two-phase system. It has been found that this reaction is very efficient and offers for example an efficient pathway for the synthesis of 3,4-dehydro-α-tocotrienol respectively a-tocotrienol and a-tocopherol.