CAS: 871-58-9; N-Butylxanthicacidpotassiumsalt

该化合物是一种硫酸盐衍生物,可应用于有机合成和农用化学配方,其主要优点包括它作为多用途中间体,在准备硫酸甲酯和二硫酸甲酯化合物方面发挥着作用,这些化合物对农药和除草剂开发很有价值;丁氧碳代硫酸盐的混合物会增加有机溶剂的溶解性,便于在温和条件下作出反应;此外,钾对硫酸盐的抗生素会比类似钠或锂盐的稳定性和处理能力得到改善;这种化合物在核循环替代和交叉反应方面特别有用,提供高效的硫化转移能力;其平衡的再活性和储存稳定性使它成为工业和研究规模合成工艺的一个实际选择.

结构式图片

相似化合物

2720-73-2 141-96-8 140-92-1

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号71-36-3 正丁醇 | CAS号75-15-0 二硫化碳 | CAS号3999-70-0 potassium butanolate | CAS号75-15-0 二硫化碳 | CAS号71-36-3 正丁醇 | CAS号105-77-1 二硫化二正丁基黄原酸酯 | CAS号74-93-1 甲硫醇 | CAS号2905-52-4 BIS(ETHOXYTHI°C... | CAS号4092-75-5 Bis(thi°Carboni... | CAS号65573-07-1 O-Butyl O-ethyl... | CAS号82524-67-2 S-ethoxythi°Car...

合成工艺路线路线简述

  • 71-36-3 = 871-58-9
    反应条件:1.1 -2.1 Solvents: Carbon Disulfide
    标题:Method Of Producing Potassium Butyl Xanthate
    参考文献:Ussr]

    71-36-3 = 871-58-9
    反应条件:1.1 Reagents: Potassium Hydroxide; Rt; 30 Min,Rt
    标题:Synthesis Of Iron Sulfide Thin Films And Powders From New Xanthate Precursors
    作者:Almanqur,Laila; Et Al
    参考文献:Journal Of Crystal Growth 日期:2019 卷标:522 页码:175-182]

    3999-70-0 = 871-58-9
    反应条件:1.1 Solvents: Carbon Disulfide
    标题:Method Of Producing Potassium Butyl Xanthate
    参考文献:Ussr
正丁醇置于二硫化碳,氢氧化钾体系中,化学反应生成 丁基黄原酸钾
参考文献:Novel Thiadiazoles
标题:Novel Thiadiazoles
摘要:公式为##str1##的新型噻二唑,其中r是1至3个碳原子的烷基,W选择自氧和硫,X选择自--O--,--S--和##str2##,R"选择自氢和1至3个碳原子的烷基,N为1,2,3或4,R'选择自氢,--Cn,1至3个碳原子的烷氧基,2至4个碳原子的烷氧羰基,2至4个碳原子的烯基,苯基,其可选地用卤素,1至3个碳原子的烷基和1至3个碳原子的烷氧基中的一个成员或用卤素,1至3个碳原子的烷基和1至3个碳原子的烷氧基中的两个成员取代,具有杀虫和杀线虫作用.

海关参考信息

专利信息


专利号:US-4357465-A
优先权日:1975-12-09
标 题 :3',4'-Diedeoxykanamycin B derivatives
发明人:UMEZAWA HAMAO; UMEZAWA SUMIO; SEKI SHIGEO; FUKATSU SHUNZO; YASUDA SHUNTARO
权利人:MICROBIAL CHEM RES FOUND
摘要:New routes are provided for the synthesis of 3',4'-dideoxykanamycin B which is effective in inhibiting kanamycin-resistant organisms from kanamycin B through new intermediate, of which a fundamental process comprises a new reaction of a 3',4'-epoxy derivative of amino- and hydroxyl-protected kanamycin B with a xanthate to form a corresponding 3',4'-dideoxy-3'-eno derivative followed by removal of the amino- and hydroxyl-protecting groups thereof and by hydrogenation of the resulting 3',4'-dideoxy-3'-eno-kanamycin B. A 3',4'-episulfide derivative corresponding to the 3',4'-epoxy derivative which is formed as second product in the reaction of 3',4'-epoxy derivative with xanthate is also used as intermediate for the preparation of 3',4'-dideoxykanamycin B.

专利号:US-4195170-A
优先权日:1975-12-09
标 题:3',4'-Episulfido kanamycin B compounds
发明人:FUKATSU SHUNZO; SEKI SHIGEO; UMEZAWA HAMAO; UMEZAWA SUMIO; YASUDA SHUNTARO
权利人:MICROBIAL CHEM RES FOUND
摘要:New routes are provided for the synthesis of 3',4'-dideoxykanamycin B which is effective in inhibiting kanamycin-resistant organisms from kanamycin B through new intermediate, of which a fundamental process comprises a new reaction of a 3',4'-epoxy derivative of amino- and hydroxyl-protected kanamycin B with a xanthate to form a corresponding 3',4'-dideoxy-3'-eno derivative followed by removal of the amino- and hydroxyl-protecting groups thereof and by hydrogenation of the resulting 3',4'-dideoxy-3'-eno-kanamycin B. A 3',4'-episulfide derivative corresponding to the 3',4'-epoxy derivative which is formed as second product in the reaction of 3',4'-epoxy derivative with xanthate is also used as intermediate for the preparation of 3',4'-dideoxykanamycin B.

专利号:CN-107698475-A
优先权日:2017-08-18
标 题:A kind of synthesis technique of liquid xanthate under solvent-free condition

专利号:CN-112403684-A
优先权日:2020-11-25
标题:A kind of synthesis method of xanthogen-quaternary ammonium salt ionic liquid and its application

专利号:CN-110229284-B
优先权日:2019-07-15
标 题 :Synthesis method of polyaryletherketone grafted polyvinylpyrrolidone

专利号:CN-117247350-A
优先权日:2023-09-04
标题:Synthesis method of quinoline-2-xanthate
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主要参考文献

参考标题:Copper-Catalyzed Synthesis Of Thiazol-2-Yl Ethers From Oxime Acetates And Xanthates Under Redox-Neutral Conditions
作者:Zhongzhi Zhu,Xiaodong Tang,Jinghe Cen,Jianxiao Li,Wanqing Wu,Huanfeng Jiang
摘要:Acetates And Xanthates For The Synthesis Of Thiazol-2-Yl Ethers With Remarkable Regioselectivity Has Been Developed. Various Oxime Acetates, Whether Derived From Aryl Ketones Or Alkyl Ketones, Or Natural Product Cores Are Suitable For This Conversion. Unique Dihydrothiazoles Were Also Obtained When Both Reaction Sites Were Methine. Mechanistic Studies Indicated That Imino Copper(III) Intermediates Were Involved

合成参考文献


摘要:Aitken, R. A., Science of Synthesis Knowledge Updates, (2018) 3, 314.
摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(102), 1982
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