CAS: 24513-57-3; 4-(Hydroxymethyl)-4,6A,10,10,13A,15B-Hexamethyl-2,3,4,4A,5,6,6A,7,9,9A,10,11,12,13,13A,13B,14,15,15A,15B-Icosahydro-1H-Cyclohepta[1,2-A:5,4-A']Dinaphthalene-3,11-Diol

该化合物是一个复杂的有机化合物,其特征是其多环结构,由凝固的环环和环球芳烃组成.该化合物具有多个立体中心的特点,有助于其个性性性,并展示了具体的立体化学,以其3S,4S,4aR,6aS,9aR,11R,13aR,13bS,15a,15bR)为标志.该化合物在特定位置的存在,增强了其在各种溶剂中的回能性和溶性.作为更大种类的多环芳烃的成员,它可能表现出有趣的电子特性和在材料科学或药用化学中的潜在应用.其结构复杂性表明生物系统中存在多种相互作用的潜力,尽管具体的生物活动需要进一步调查.

英文名称4-(Hydroxymethyl)-4,6A,10,10,13A,15B-Hexamethyl-2,3,4,4A,5,6,6A,7,9,9A,10,11,12,13,13A,13B,14,15,15A,15B-Icosahydro-1H-Cyclohepta[1,2-A:5,4-A']Dinaphthalene-3,11-Diol
中文名称21-表山芝烯三醇
IUPAC名称4-(hydroxymethyl)-4,6a,10,10,13a,15b-hexamethyl-2,3,4,4a,5,6,6a,7,9,9a,10,11,12,13,13a,13b,14,15,15a,15b-icosahydro-1H-cyclohepta[1,2-a:5,4-a']dinaphthalene-3,11-diol
其它别名21-Episerratriol; C(14A)-Homo-27-Norgammacer-14(15)-Ene-3β,21β,24-Triol; 3-Epilycoclavanol; Serrat-14-En-3Beta,21Beta,24-Triol; 1H-Cyclohepta[1,2-A:5,4-A']Dinaphthalene-3,11-Diol, 2,3,4,4A,5,6,6A,7,9,9A,10,11,12,13,13A,13B,14,15,15A,15B-Eicosahydro-4-(Hydroxymethyl)-4,6A,10,10,13A,15B-Hexamethyl-, (3S,4S,4Ar,6As,9Ar,11R,13Ar,13Bs,15As,15Br)-; 3-Exo-Methyl-2-Norbornanon
CAS编号24513-57-3
MFCD编号:MFCD20260790
分子式:C30H50O3分子量:458.73
产品CID: 1193412
产品分类天然产物 → 萜类

相似结构搜索
产品信息参考;;;
InChIKey: VYUNCIDAMBNEFU-UHFFFAOYSA-N
InChI=1S/C30H50O3/c1-26(2)21-9-7-19-17-27(3)14-11-23-29(5,16-13-25(33)30(23,6)18-31)22(27)10-8-20(19)28(21,4)15-12-24(26)32/h7,20-25,31-33H,8-18H2,1-6H3
计算化学: 氢键受体数3.0氢键供体数3.0可旋转键数1.0

MSDS等安全信息

危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
安全声明H303+H313+H333

上下游产品

Acetic acid (4S,4aR,6aS,9aR,11R,13aR,13bS,15aS,15bR)-11-acetoxy-4,6a,10,10,13a,15b-hexamethyl-3-oxo-2,3,4,4a,5,6,6a,7,9,9a,10,11,12,13,13a,13b,14,15,15a,15b-icosahydro-1H-cyclohepta[1,2-a;5,4-a']dinaphthalen-4-ylmethyl ester Lyc°Clavanoldiacetat-A lyc°Clavanol triacetate

合成工艺路线路线简述

📜Lycolavanoldiacetat-A 在 Chromium(Vi) Oxide,Lithium Aluminium Tetrahydride,硫酸体系中,用四氢呋喃,丙酮作为反应溶剂,获得 21-Episerratriol
参考文献:Triterpenoid Chemistry. Vi. Iycopodium Triterpenoid. (5). The Structures And Stereochemistry Of Serratriol,21-Episerratriol,And Lycolavanol.
标题:Triterpenoid Chemistry. Vi. Iycopodium Triterpenoid. (5). The Structures And Stereochemistry Of Serratriol,21-Episerratriol,And Lycolavanol.
摘要:从狼尾草中分离出的三萜类三醇,蛇床子三醇,21-表蛇床子三醇和番荔枝黄烷醇的结构被确定为蛇床子-14-烯-3β,21α,24-三醇(3),蛇床子-14-烯-3β,21β,24-三醇(36)和蛇床子-14-烯-3α,21β,24-三醇(22).第四种可能的立体异构体三醇,Serrat-14-En-3α,21α,24-Triol(43),是由番荔枝黄烷醇制备的.报告了 1,3-乙二醇形成丙酮的新方法.
Doi:10.1248/Cpb.22.2383