📜4-Chloronaphthalen-1-Yl Trifluoromethanesulfonate置于potassium Phosphate,Palladium Diacetate,3-(Tert-Butyl(Phenyl)Phosphaneyl)-2-Cyclohexyl-1-Methyl-1H-Indole,异丙醇体系中,用 四氢呋喃 作为反应溶剂,以78 %的收率获得产物1-萘基三氟甲磺酸酯 参考文献:Palladium-Catalyzed Deuterodehalogenation Of Halogenated Aryl Triflates Using Isopropanol-D8 As The Deuterium Source 标题:Palladium-Catalyzed Deuterodehalogenation Of Halogenated Aryl Triflates Using Isopropanol-D8 As The Deuterium Source 摘要: DOI:10.1021/acs.Orglett.3C03281
专利号:US-8410301-B2 优先权日:2007-11-28 标题:Methods for the synthesis of organic sulfides by using sulfides and organic sulfur-indium complexes 发明人:LEE PHIL-HO 权利人:LEE PHIL-HO; KNU INDUSTRY COOPERATION FOUND 摘要:The present invention relates to a novel synthesis method for the formation of carbon-sulfur bonds by the reaction of an organic sulfur-indium complex with nucleophile in the presence of a palladium catalyst. The present invention provides a synthesis method to prepare several kinds of organic sulfides which are difficult to be prepared by the conventional synthesis methods. A short reaction time and quantitative yield are the advantages of this method. In addition, several kinds of organic sulfide can be prepared by the selection of nucleophile and organic sulfur-indium complex to be used.
专利号:US-2010234633-A1 优先权日:2007-11-28 标 题:Methods for the synthesis of organic sulfides by using sulfides and organic sulfur-indium complexes
专利号:WO-2009069888-A2 优先权日:2007-11-28 标 题 :Methods for the synthesis of organic sulfides by using sulfides and organic sulfur-indium complexes
专利号:US-6323366-B1 优先权日:1997-07-29 标 题:Arylamine synthesis 发明人:WOLFE JOHN P; AHMAN JENS; SADIGHI JOSEPH P; SINGER ROBERT A; BUCHWALD STEPHEN L 权利人:MASSACHUSETTS INST TECHNOLOGY 摘要:The present invention provides a method for the preparation of a wide range of primary arylamines. The arylamines are prepared in two efficient, straightforward transformations: 1) an activated aryl group and an imine group are combined, in the presence of a transition metal catalyst, under conditions wherein the transition metal catalyst catalyzes the formation of a carbon-nitrogen bond between the activated carbon of the arene and the imine nitrogen; and 2) the resulting N-aryl imine is transformed, via any of a number of standard protocols, to the primary arylamine. The method of the invention may also be exploited in the preparation of vinylamines.
专利号:US-10150111-B2 优先权日:2016-09-06 标题 :Method for catalytic synthesis of cinnamic acid with catalyst recycle
专利号:KR-20090036001-A 优先权日:2007-10-08 标题:Allene substituted unsaturated compounds and synthesis of them using indium