CAS: 4107-98-6; N,N-Diisopropylaniline

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CAS号108-86-1 溴苯 | CAS号108-18-9 二异丙胺 | CAS号591-51-5 苯基锂 | CAS号15288-53-6 2-(三甲基硅烷基)苯酚 | CAS号1078-58-6 二苯锌 | CAS号3262-89-3 苯硼酸酐 | CAS号17763-67-6 三氟甲烷磺酰苯 | CAS号41742-64-7 lithium(CN-phen... | CAS号366-29-0 N,N,N',N'-四甲基联苯胺 | CAS号1124-52-3 N-phenylpropan-... | CAS号768-52-5 N-异丙基苯胺 | CAS号75-33-2 2-丙基硫醇

📜二异丙胺置于dipotassium Hydrogenphosphate,Copper Dichloride体系中,用 四氢呋喃,乙醚,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 25.0H,反应生成 N,N-二异丙苯胺
参考文献:铜催化亲核有机锌的亲电胺化:O-苯甲酰羟胺作为广泛有用的r 2 N(+)和rhn(+)合成子的文献
标题:铜催化亲核有机锌的亲电胺化:O-苯甲酰羟胺作为广泛有用的r 2 N(+)和rhn(+)合成子的文献
摘要:本文详细介绍了新的铜催化的二有机锌试剂的亲电胺化反应,该反应使用o-苯甲酰羟胺作为亲电氮源,可以一步一步获得.在催化量的铜盐存在下,将简单且功能化的芳基,杂芳基,苄基,正烷基,仲烷基和叔烷基亲核试剂与r 2 Noc(o)ph和rhnoc(o)ph试剂偶联叔胺和仲胺通常分别具有非常好的收率.在许多情况下,可通过简单的萃取后处理将产物分离为分析纯.胺化过程显示出可以承受很大程度的空间需求.名义上不活泼的c芳基的胺化详细说明了通过顺序的定向原位金属化/过渡金属化/催化胺化反应序列进行的-H键.描述了使用zncl 2共催化直接cu催化的格氏试剂的胺化.
DOI:10.1021/jo051999H

专利信息

专利号:US-7271231-B2
优先权日:1995-01-24
标 题 :Polymerization of olefins
发明人：BROOKHART MAURICE S; JOHNSON LYNDA KAYE; KILLIAN CHRISTOPHER MOORE
权利人:DU PONT
摘要:Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected α-diimine nickel complexes with ethylene.

专利号:US-8138272-B2
优先权日:2006-05-22
标 题:Preparation of polymer conjugates of therapeutic, agricultural, and food additive compounds
发明人：KONRADI ANDREI W; SMITH JENIFER L
权利人:KONRADI ANDREI W; SMITH JENIFER L; ELAN PHARM INC
摘要:This invention provides an improved synthesis of polymer conjugates of formula (I), n nof agricultural, therapeutic, and food additive compounds. In particular, a process is described for the preparation of conjugates by treating primary or secondary alcohol substituents of active compounds with polymeric nucleophiles using “Mitsunobuâ€? or related reaction conditions.

专利号:US-2024383828-A1
优先权日:2021-07-03
标 题:Process for converting synthesis gas to higher alcohols
发明人：LEITNER WALTER; PRIETO GONZALO; JESKE KAI; VORHOLT ANDREAS JOHANNES; ROESLER THORSTEN; BELLEFLAMME MAURICE
权利人:STUDIENGESELLSCHAFT KOHLE GGMBH; MAX PLANCK GESELLSCHAFT
摘要:The present invention refers to a process for converting a feed gas stream comprising carbon monoxide and hydrogen as major components (synthesis gas) into higher (C 3+ ) alcohols making use of a catalyst combination of a Fischer-Tropsch catalyst and an olefin hydroformylation catalyst. In a second aspect, the invention relates to a Fischer-Tropsch catalyst suitable to be applied in said process.

专利号:US-5218088-A
优先权日:1989-11-02
标 题 :Process for preparing dithiophosphate oligonucleotide analogs via nucleoside thiophosphoramidite intermediates
发明人：GORENSTEIN DAVID; FARSCHTSCHI NASSAR
权利人:PURDUE RESEARCH FOUNDATION
摘要:A method for synthesis of oligonucleotide analogs having dithiophosphate internucleosidic linkages is described. Monohalohydrocarbylthiophosphoramidites are utilized to prepare nucleoside thiophosphoramidite intermediates which are activated for nucleoside coupling with tetrazole catalysts. Sulfur oxidation and dehydrocarbylation of the coupled thiophosphite intermediates provide oligonucleotide analogs having achiral dithiophosphate internucleosidic linkages.

专利号:US-4973679-A
优先权日:1981-03-27
标题:Process for oligonucleo tide synthesis using phosphormidite intermediates
发明人：CARUTHERS MARVIN H; BEAUCAGE SERGE L
权利人:UNIVERSITY PATENTS INC
摘要:A new class of nucleoside phosphoramidites which are relatively stable to permit isolation thereof and storage at room temperature. The phosphoramidites are derivatives of saturated secondary amines.

专利号:US-5530107-A
优先权日:1992-10-15
标 题:Method for making steroidal peracyl glycosides
发明人：ALLAN DOUGLAS J M; BUSCH FRANK R; LAMBERT JOHN F; SHINE RUSSELL J; WALINSKY STANLEY W
权利人:PFIZER
摘要:Processes for the synthesis of tigogenin beta-O-cellobioside heptaalkanoate which is an intermediate for the known hypocholesterolemic agent tigogenin beta-cellobioside. The process comprises reacting α-cellobiosyl bromide heptaalkanoate and β-tigogenin in the presence of zinc fluoride or zinc cyanide under conditions capable of forming said tigogenyl β-O-cellobioside heptaalkanoate. The analogous preparations of hecogenin β-O-cellobioside heptaalkanoate, 11-ketotigogenin β-O-cellobioside heptaalkanoate, and diosgenin β-O-cellobioside heptaalkanoate are also disclosed. The process provides both high β-anomeric selectivity and high yields.