专利号:WO-2021129102-A1 优先权日:2019-12-27 标 题 :Heterocyclic compound, synthesis method therefor, organic electroluminescent device and electronic apparatus 发明人:WANG JINPING; XUE ZHEN; CHEN ZHIWEI 权利人:SHAANXI LIGHTE OPTOELECTRONICS MAT CO LTD 摘要:Disclosed are a heterocyclic compound, a synthesis method therefor, an organic electroluminescent device and an electronic apparatus. The heterocyclic compound has a chemical structural formula as shown in formula 1, wherein M is selected from the groups shown in formula 1-A. The compound can improve the properties of the organic electroluminescent device.
专利号:US-2007069198-A1 优先权日:2003-09-29 标题:Synthesis of phenyl-substituted fluoranthenes by a diesel-alder reaction and the use thereof
专利号:US-7906225-B2 优先权日:2003-09-29 标 题:Synthesis of phenyl-substituted fluoranthenes by a diesel-alder and the use thereof 发明人:DOETZ FLORIAN; SCHWALM REINHOLD; ROESCH JOACHIM 权利人:BASF AG 摘要:A substituted fluoranthene, a light emitting layer including the substituted fluoranthene, a diode including the substituted fluoranthene, and a visual display unit including the substituted fluoranthene.
专利号:US-7732652-B2 优先权日:2001-07-04 标题 :Perylene derivative synthesis process, perylene derivative and organic EL device 发明人:FUJITA TETSUJI; ARA KENSUKE; INOUE TETSUSHI 权利人:TDK CORP 摘要:The invention aims to provide a perylene derivative preparation process featuring satisfactory yields and improved preparation efficiency, a perylene derivative obtained by the process, and an organic EL device using the same. The object is achieved by a perylene derivative preparation process comprising subjecting to coupling reaction a 1,8-dihalogenated naphthalene derivative of the formula (1): n nwherein X is Cl, Br or I, R 1 to R 4 , R 11 and R 12 each are hydrogen, alkyl, alkoxy, alkylthio, alkenyl, alkenyloxy, alkenylthio, aralkyl, aralkyloxy, aralkylthio, aryl, aryloxy, and arylthio radicals which may be substituted, amino radical, cyano radical, hydroxyl radical, —COOM 1 radical (wherein M 1 is hydrogen, alkyl, alkenyl, aralkyl or aryl), —COM 2 radical (wherein M 2 is hydrogen, alkyl, alkenyl, aralkyl, aryl or amino), or —OCOM 3 radical (wherein M 3 is alkyl, alkenyl, aralkyl or aryl), and at least two adjoining radicals selected from among R 1 to R 4 , R 11 and R 12 may bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms on which they substitute, with the proviso that when the carbocyclic aliphatic ring, aromatic ring or fused aromatic ring has substituent radicals, the substituent radicals are the same as R 1 to R 4 , R 11 and R 12 , to thereby synthesize a perylene derivative of the formula (2):n n nwherein R 1 ′ to R 4 ′, R 11 ′ and R 12 ′ are as defined for R 1 to R 4 , R 11 and R 12 in formula (1), and R 1 to R 4 , R 11 and R 12 and R 1 ′ to R 4 ′, R 11 ′ and R 12 ′ may be the same or different.
专利号:CN-117813301-A 优先权日:2021-08-11 标题:Synthesis of bilirubin
参考标题:Synthesis Of Cyclopenta-Fused Polycyclic Aromatic Hydrocarbons Utilizing Aryl-Substituted Anilines 作者:Yeojin Choi,Tanmay Chatterjee,Jun Kim,Jun Soo Kim,Eun Jin Cho 摘要:Cyclopenta-Fused Polycyclic Aromatic Hydrocarbons (Cp-Pahs), Potentially Electronically And Biologically Highly Active Materials, Were Synthesized From Readily Available 2-Aryl-Substituted Anilines. Reactions Occur Under Extremely Mild, Room Temperature Conditions Using Tbuono As The Sole Reagent. The Use Of A Nitrite Source Generates A Reactive Diazonium Intermediate In Situ That Then Reacts With
合成参考文献
摘要:Suna, E.; Shubin, K., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 715. 摘要:A10: Santodonato J, Howard P, Basu D: Health and ecological assessment of polynuclear aromatic hydrocarbons. J Environ Pathol Toxicol. 1981 Sep;5(1):1-364. 参考文献:10.1007/s12032-018-1150-3 摘要:Stults WP, Wei Y. Ambient air emissions of polycyclic aromatic hydrocarbons and female breast cancer incidence in US. Med Oncol. 2018 May 05;35(6):88. doi: 10.1007/s12032-018-1150-3.