CAS: 1836-75-5; Nitrofen

该化合物是一种有机化合物,其特点是芳香结构,包括一个由两个氯原子和一氧化亚氮组组成的苯环替代,该化合物一般是一种固体,以有机溶剂中的中溶性为名,同时在水中较不易溶解;氯和硝基组的存在有助于其化学反应,使其有可能成为各种化学反应,包括替代电子药剂的候选体;经常用于研究和工业应用,特别是农用化学品和药物合成;此外,由于其卤化性质,它可能表现出环境持久性和潜在毒性,需要谨慎处理和处置;在特定处理预防措施时,应参考安全数据单,因为接触时可能会对健康造成危害.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签"欧盟管控危险化学品"ECHA物质食品接触材料-禁用CMR物质ECHA物质化妆品禁用物质清单C&L通报Other工作场所安全标识要求REACH预注册废弃物危险特性清单

上下游产品

4-chlorobenzonitrile 2,4-dichlorophenol copper bifenox2,4-dichloro-4'-aminodiphenyl ether 4-(2,4-dichlorophenoxy)-N-hydroxyaniline (2S,3R,4S,5S,6R)-2-{N-[4-(2,4-Dichloro-phenoxy)-phenyl]aminooxy}-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol -D-glucofuranurono-6,3-lactone1-deoxy-1-4-(2,4-dichlorophenoxy)-N-hydroxyanilino-D-glucofuranurono-6,3-lactone

合成工艺路线路线简述

  • 合成目标产物 Nitrofen 主要起始原料 4-Fluoronitrobenzene And 2,4-Dichlorophenol
  • (文献来源)合成步骤主要原料 4-Fluoronitrobenzene 和 2,4-Dichlorophenol
📜N,N-二甲基对硝基苯胺置于双(三甲基硅烷基)氨基钾体系中,用 四氢呋喃,二氯甲烷,N,N-二甲基甲酰胺 用作溶剂,化学反应 5.17H,反应生成除草醚
参考文献:从苯胺到芳醚:一种温和条件下的简便,高效且多功能的合成方法
标题:从苯胺到芳醚:一种温和条件下的简便,高效且多功能的合成方法
摘要:我们通过醇/酚(roh)与芳基铵盐(arnme反应开发了用于芳基醚的合成的简单且直接的方法3 +),它很容易从苯胺制备(arnr' 2,R'= H或me) .该反应在室温下顺利地且快速地进行(在几个小时内)在市售的碱,例如ko的存在吨卜或khmds,并具有相对于二者roh和arnr'宽的底物范围2.它具有可扩展性,并且与各种功能组兼容.
Doi:10.1002/anie.201712618

海关参考信息

专利信息


专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

专利号:ES-2717283-T3
优先权日:2012-07-24
标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids

专利号:US-2010159539-A1
优先权日:2008-03-13
标 题 :Methods and systems for producing biofuels and bioenergy products from xenobiotic compounds
发明人:ASCON MIGUEL; ASCON DOLORES
权利人:ASCON MIGUEL; ASCON DOLORES
摘要:The present invention provides methods and systems for producing biofuel and bioenergy products using, as starting raw material, xenobiotic materials or compounds. The xenobiotic materials or compounds may originate from industrial or chemical plants, municipal waste, pharmaceutical products, cosmetic and personal care products, or other sources, and may include aliphatic and aromatic hydrocarbons, chlorinated organic solvents and other halogenated hydrocarbons, as well as heteroaromatic compounds. In accordance with the invention, these materials act as a carbon source to support the metabolism of xenobiotic-degrading microorganisms, thereby producing biomass and/or biogas that may be converted to bioenergy products by microbial synthesis. For example, the biomass may be converted to products such as ethanol, methanol, butanol, and methane, among others. The biogas may be converted to hydrogen gas and biodiesel, among others. Thus, the present invention couples the microbial breakdown (decomposition) of xenobiotic materials with the microbial synthesis of biofuel, thereby supplying needed (inexpensive) energy products, while reducing environmental pollution and contamination, and reducing the costs associated with disposal of hazardous waste.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Toxicology., 29(1), 1983 []
摘要:California EPA; Pesticide Regulation, 10th Annual Report. Dec 1995. EH96-06 (1995)
摘要:Kling DE et al; Toxicol In Vitro. 19 (1): 1-10 (2005)
摘要:Weed Science Society of America. Herbicide Handbook. 5th ed. Champaign, Illinois: Weed Science Society of America, 1983., p. 345
摘要:Pohanish, R.P. (ed). Sittig's Handbook of Toxic and Hazardous Chemical Carcinogens 5th Edition Volume 1: A-H,Volume 2: I-Z. William Andrew, Norwich, NY 2008, p. 1866
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