CAS: 14282-91-8; Hexaammineruthenium(Iii) Chloride

该化合物是一个协调化合物,在+3氧化状态下,由6个氨皮环绕的三氧化状态下,以为特征.这种橙色晶状固体在水中高度溶解,在标准条件下具有稳定性,在无机合成和催化研究中成为有价值的前体.其明确界定的八角几何测量和红氧化活性中心有利于研究电子转移过程和设计分子催化剂.该化合物还由于具有可预测的再活动性和形成稳定复合体的能力,在电化学和材料科学中被使用.妥善处理需要防范,因为它对光和湿度具有潜在的敏感性.

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欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

hydrogenchloride hexaammineruthenium(II) chloride sulfur dioxide sodium tetrachloroaurate(III)

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    专利信息


    专利号:US-12281398-B2
    优先权日:2022-02-07
    标题:Microfluidic process for the general electrochemical synthesis of geminal dipseudohalide or halide-pseudohalide compounds
    发明人:SCHROER THORSTEN G; LECROY GREGORY E; AGUILA MIGUEL; RODRIGUEZ MAYRA P; DOWNARD TYLER J; MACLEOD BRIANNA L
    权利人:US GOV AIR FORCE; US AIR FORCE
    摘要:A process for the microfluidic electrochemical synthesis of geminal dipseudohalide or halide-pseudohalide compounds comprising the steps ofpumping a solution comprising a compound of Formula Iinto a microfluidic electrochemical reactor in the presence of a base, one of a halide or pseudohalide salt (MY), and a mediator;applying an electrical current through the microfluidic electrochemical reactor; andperforming oxidative addition to create a geminal dipseudohalide or halide-pseudohalide compound of the general Formula II

    专利号:US-5756419-A
    优先权日:1995-09-25
    标题 :Process for the conversion of synthesis gas in the presence of a catalyst comprising cobalt and additional elements
    发明人:CHAUMETTE PATRICK; DIDILLON BLAISE
    权利人:INST FRANCAIS DU PETROLE
    摘要:The invention concerns the preparation of a catalyst comprising a support containing at least one oxide of the element Si, Al, Ti, Zr, Sn, Zn, Mg or Ln (where Ln is a rare earth), cobalt, at least one element A selected from the group formed by ruthenium, platinum, palladium and uranium, and at least one element B selected from the group formed by molybdenum and tungsten, characterized in that it comprises at least the following successive steps: n (1) formation of a precursor comprising at least cobalt and at least a portion of the support; n (2) at least partial reduction of the precursor in the presence of at least one reducing compound; and n (3) deposition of any part of compound present in the catalyst and not present in the precursor on the reduced precursor. n The invention also concerns the use of the catalyst in a process for the synthesis of C 5 + hydrocarbons from synthesis gas.

    专利号:US-5786393-A
    优先权日:1995-07-13
    标题 :Liquid phase process for converting synthesis gas
    发明人:CHAUMETTE PATRICK; BOUCOT PIERRE; GALTIER PIERRE
    权利人:INST FRANCAIS DU PETROLE
    摘要:In the synthesis of essentially linear saturated C5+ hydrocarbons from synthesis gas, the reactive gas phase circulating either as a downflow or as an upflow through a fixed bed catalytic reaction zone, an upflow of an inert liquid phase through said zone at a superficial flow rate of more than 0.01 cm/s, as compared to a downflow of liquid phase, increases the selectivity of the process to the formation of the desired C5+ cut.

    专利号:US-5869541-A
    优先权日:1996-03-08
    标 题:Conversion of synthesis gas to hydrocarbons in the presence of a liquid phase
    发明人:EUZEN JEAN-PAUL; HARTER ISABELLE; CHAUMETTE PATRICK
    权利人:INST FRANCAIS DU PETROLE; AGIP PETROLI
    摘要:A process for the synthesis of essentially linear saturated C5+ hydrocarbons from a gas phase comprising synthesis gas is described. The process comprises circulation of an inert liquid phase and said gas phase in a reaction zone, in which the reaction zone is provided with at least one means for introducing gas and liquid phases, and at least one means for extracting the hydrocarbon phase formed by the Fischer-Tropsch reaction, and characterized in that the reaction zone comprises at least one mixing means. Preferably, at least one mixing means is a static mixer. An apparatus for carrying out the described process is also described.

    专利号:US-2013289145-A1
    优先权日:2011-01-24
    标题 :Catalyst for fischer-tropsch synthesis, production method therefor, and production method using fischer-tropsch synthesis catalyst
    发明人:MIURA YASUTOMO; NAKASHIZU SHIGENORI
    权利人:MIURA YASUTOMO; NAKASHIZU SHIGENORI
    摘要:The catalyst for FT synthesis comprises manganese carbonate containing from 10 to 25% by mass of silica in terms of an oxide on the basis of the mass of the catalyst, not more than 6% by mass of an organic binder on the basis of the mass of the catalyst, and from 0.5 to 5% by mass of ruthenium in terms of a metal on the basis of the mass of the catalyst, wherein the catalyst has a surface area of 100 to 210 m 2 /g and a pore volume of 0.1 to 0.6 ml/g.

    专利号:WO-2024059703-A1
    优先权日:2022-09-16
    标题:Covalently modified template-independent dna polymerase and methods of use thereof
    发明人:SPRACHMAN MELISSA M; BRYAN CASSIE M; GRISWOLD JR; DOE ROBERT E; MORAN ISAAC; RECORDS WILLIAM C; MAGYAR ANDREW P; RODRIGUEZ JUAN CARLOS; COLEMAN RACHEL; DOYLE ROBERT
    权利人:CHARLES STARK DRAPER LABORATORY INC
    摘要:Provided herein are engineered terminal deoxynucleotidyl transferase (TdT) proteins with certain modifications, including mutations to confer thermal stability and to install an exposed amino acid residue to which a small molecule can be covalently tethered via bioconjugate chemistries such as click chemistry. Also provided herein are methods of nucleic acid molecule synthesis using engineered TdTs and nucleotide molecules attached to redox-cleavable linkers, wherein the engineered TdT incorporates the nucleotide molecule into a nucleic acid strand and is separated from the nucleotide molecule when the redoxcleavable linker is cleaved upon exposure to suitable electrochemical conditions. Also provided herein are engineered TdTs covalently attached to a nucleotide molecule via a tether and also nucleotide molecules comprising a redox-cleavable linker. Further provided herein are systems for enzymatic DNA synthesis comprising an engineered TdT, a redox-cleavable linker a redox shuttle solution, and two or more electrodes.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/978-1-0716-2823-2_2
    摘要:Rahimian N, Nahand JS, Hamblin MR, Mirzaei H. Exosomal MicroRNA Profiling. Methods Mol Biol. 2023;2595():13–47. doi: 10.1007/978-1-0716-2823-2_2.
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