CAS: 93-98-1; Benzanilide

• 英文名称Benzanilide
• 中文名称苯甲酰苯胺
• IUPAC名称N-phenylbenzamide
• 其它别名N-Phenylbenzamide; N-Phenyl-Benzamide; Benzanilide; N-Benzoyl Aniline; Benzanilid
• CAS编号93-98-1
• MFCD编号:MFCD00003069
• EINECS号:202-292-7
• FDA UNII编号:AK1B12366O
• 分子式:C13H11NO
• 分子量:197.23
• 产品CID: 1984604
• 产品分类化学试剂 → 有机试剂 → 酰卤

• 相似结构搜索
• 产品信息参考;;;
• InChIKey: ZVSKZLHKADLHSD-UHFFFAOYSA-N
• InChI=1S/C13H11NO/c15-13(11-7-3-1-4-8-11)14-12-9-5-2-6-10-12/h1-10H,(H,14,15)…
• 计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数2.0

物理性质

• 熔点161-163 °C(文献)
• 沸点117 °C10 mm Hg(文献)
• 闪点117°C/10mm
• 密度1,315 g/cm 3
• pKa:13.52±0.70(预测)
• PSA:29.1
• LogP:3.0119
• 折射率1.6050 (估算)
• 蒸汽压0.0261 mmHg at 25 °C
• 溶解性水: Insoluble
• 外观形态灰色至黄绿色粉末
• 储存条件存储低于 +30°C.
• 产品应用有机合成中间体,用于药物,染料,香料的生产.
• 性质描述无色或白色片状结晶.熔点162-164°C,沸点117°C(1.33kPa),相对密度1.135.几乎不溶于水,溶于乙醇,微溶于乙醚.能升华.

MSDS等安全信息

• GHS符号GHS07
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2A
• 警示词Warning
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P271-P261-P280
• UN编号NONH for all modes of transport
• 危险品标志Xn
• 安全声明22-24/25-36-26
• 危险类别码20/21/22-36/37/38
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 4686-14-0 = 93-98-1
  反应条件:1.1 Catalysts: Water Solvents: Dimethylformamide; 24 H,120 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; 10 Min,Rt
  标题:Formation Of Amides From Imines Via Cyanide-Mediated Metal-Free Aerobic Oxidation
  作者:Seo,Hong-Ahn; Cho,Yeon-Ho; Lee,Ye-Sol; Cheon,Cheol-Hong
  参考文献:Journal Of Organic Chemistry 日期:2015 卷标:80(24) 页码:11993-11998]
  
  65-85-0 = 93-98-1
  反应条件:1.1 Reagents: Diisopropylethylamine,N-[1-(Cyano-2-Ethoxy-2-Oxoethylideneaminooxy)Dimethylamino(Morpholino)Uronium He... Solvents: Tetrahydrofuran,Water; 24 H,Ph 10.8,25 °C
  标题:Evaluation Of Safe Mixed Solvents In N-Phenylbenzamide Synthesis For Alteration Of Hazardous Dipolar Aprotic Solvents In Amide Drug Syntheses
  作者:Islam,Tariqul; Sarker,Zaidul Islam Md; Uddin,Abm Helal; Rashid,Shah Samiur; Bin,Liew Kai
  参考文献:Tetrahedron 日期:2023 卷标:131]
  
  98-88-4 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran; 0 °C; 0 °C -> Rt; 12 H,Rt
  标题:α-Imino Iridium Carbenes From Imidoyl Sulfoxonium Ylides: Application In The One-Step Synthesis Of Indoles
  作者:Caiuby,Clarice A. D.; De Jesus,Matheus P.; Burtoloso,Antonio C. B.
  参考文献:Journal Of Organic Chemistry 日期:2020 卷标:85(11) 页码:7433-7445]
  
  591-50-4 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine Catalysts: (Sp-4-1)-(Acetonitrile)Dichloro[1-(4,6-Dimethoxy-1,3,5-Triazin-2-Yl)-1,3-Dihydro... Solvents: 1,4-Dioxane; 6 H,3 Atm,100 °C
  标题:N-Heterocyclic Carbine Palladium Complex Crystal And Its Synthesis Method And Application In Preparing Amide Compound
  参考文献:China]
  
  591-50-4 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine Catalysts: (Sp-4-3)-[3′,4′-Bis(4,5-Dihydro-4,4-Dimethyl-2-Oxazolyl-Kn3)[1,1′-Biphenyl]-4-Ol... (Solid-Supported) Solvents: Acetonitrile; Rt -> 120 °C; 6 H,100 Psi,120 °C
  标题:Catalytic Process For Synthesizing Ester Compounds And Amide Compounds
  参考文献:United States]
  
  98-88-4 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; 0.5 H,0 °C; 0 °C -> Rt; 2 H,Rt
  标题:Substituted 2,4-Diaminopyrimidine Compounds As Protein Kinase Inhibitors And Their Preparation,Pharmaceutical Compositions And Use In The Treatment Of Diseases
  参考文献:China]
  
  7510-33-0 = 93-98-1
  反应条件:1.1 Reagents: Tetrabutylammonium Perchlorate,4-Methyl-N,N-Bis[2-[[(4-Methylphenyl)Sulfonyl]Oxy]Ethyl]Benzenesulfonamide Solvents: Dimethylformamide; 25 °C1.2 Reagents: Sodium Bicarbonate Solvents: Water; Basified,25 °C
  标题:Electrochemical Reduction Of α-Diketones And α-Diimines In The Presence Of A Bielectrophilic Substrate: Synthesis Of New Aza-Crown Compounds
  作者:Medini,Hayet Khemis; Mekni,Nejib Hussein; Aoun,Sami Ben; Boujlel,Khaled
  参考文献:Journal Of The Electrochemical Society 日期:2017 卷标:164(2)]
  
  591-50-4 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine Catalysts: Palladium (Merrifield Resin-Supported Bisoxazoline Complexes),3′,4′-Bis(4,5-Dihydro-4,4-Dimethyl-2-Oxazolyl)[1,1′-Biphenyl]-4-Ol (Palladium Complexes,Merrifield Resin-Supported) Solvents: Acetonitrile; 100 Psi,Rt -> 120 °C; 6 H,120 °C
  标题:A Palladium-Bisoxazoline Supported Catalyst For Selective Synthesis Of Aryl Esters And Aryl Amides Via Carbonylative Coupling Reactions
  作者:Ibrahim,Mansur B.; Suleiman,Rami; Fettouhi,Mohammed; El Ali,Bassam
  参考文献:Rsc Advances 日期:2016 卷标:6(82) 页码:78826-78837]
  
  591-50-4 = 93-98-1
  反应条件:1.1 Reagents: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene Catalysts: Palladium Solvents: Dimethylacetamide; 115 °C
  标题:1,8-Diazabicyclo[5.4.0]Undec-7-Ene
  作者:Savoca,Ann C.; Urgaonkar,Sameer
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2006 卷标:1 页码:1-11]
  
  574-66-3 = 93-98-1
  反应条件:1.1 Catalysts: Benzenesulfonic Acid,4-Ethenyl-,Sodium Salt (1:1),Polymer With Diethenylbenze... (Neutralized) Solvents: Benzonitrile; 1 H,130 °C
  标题:In Situ Functionalized Sulfonic Copolymer Toward Recyclable Heterogeneous Catalyst For Efficient Beckmann Rearrangement Of Cyclohexanone Oxime
  作者:Li,Difan; Mao,Dan; Li,Jing; Zhou,Yu; Wang,Jun
  参考文献:Applied Catalysis 日期:2016 卷标:510 页码:125-133]
  
  93-97-0 = 93-98-1
  反应条件:1.1 Catalysts: Titania Solvents: Ethanol; 2.5 H,25 - 35 °C
  标题:Photocatalytic Synthesis Of Anilides From Nitrobenzenes Under Visible Light Irradiation: 2 In 1 Reaction
  作者:Zand,Zahra; Kazemi,Foad; Partovi,Adel
  参考文献:Journal Of Photochemistry And Photobiology 日期:2015 卷标:152 页码:58-62]
  
  93-58-3 = 93-98-1
  反应条件:1.1 Catalysts: Phosphoric Acid,Aluminum Iron Salt; 4 H,92 °C
  标题:Mesoporous Iron Aluminophosphate: An Efficient Catalyst For One Pot Synthesis Of Amides By Ester-Amide Exchange Reaction
  作者:Vijayasankar,A. V.; Kathyayini,H.; Tumma,Harikrishna; Nagaraju,N.
  参考文献:Ceramic Transactions 日期:2012 卷标:233 页码:127-140]
  
  591-50-4 + 55-21-0 = 93-98-1
  反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: N,N′-Dimethylethylenediamine,Cuprous Iodide Solvents: Dimethyl Sulfoxide; 24 H,50 °C1.2 Reagents: Ethyl Acetate
  标题:Orthogonal Discrimination Among Functional Groups In Ullmann-Type C-O And C-N Couplings
  作者:Rovira,Mireia; Soler,Marta; Guell,Imma; Wang,Ming-Zheng; Gomez,Laura; Et Al
  参考文献:Journal Of Organic Chemistry 日期:2016 卷标:81(17) 页码:7315-7325]
  
  65-85-0 = 93-98-1
  反应条件:1.1 Reagents: Lithium Hydroxide,Oxygen Catalysts: Gold (Mesoporous Alumina-Supported) Solvents: Water; 14 H,Rt
  标题:Efficient Synthesis Of Amides And Esters From Alcohols Under Aerobic Ambient Conditions Catalyzed By A Au/mesoporous Al2O3 Nanocatalyst
  作者:Chng,Leng Leng; Yang,Jinhua; Ying,Jackie Y.
  参考文献:Chemsuschem 日期:2015 卷标:8(11) 页码:1916-1925]
  
  98-88-4 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran; 0 °C; 2 - 6 H,Rt
  标题:Innovative Strategy Toward Mutant Cftr Rescue In Cystic Fibrosis: Design And Synthesis Of Thiadiazole Inhibitors Of The E3 Ligase Rnf5
  作者:Brusa,Irene; Sondo,Elvira; Pesce,Emanuela; Tomati,Valeria; Gioia,Dario; Et Al
  参考文献:Journal Of Medicinal Chemistry 日期:2023 卷标:66(14) 页码:9797-9822]
  
  7702-38-7 = 93-98-1
  反应条件:1.1 Reagents: Sodium Formate Solvents: Dimethyl Sulfoxide; 1 H,120 °C
  标题:Reductive Hydrodehalogenation Of Halogenated Carboxylic Acid Derivatives Using A Dmso/hcoona.2H2O System
  作者:Liu,Guyue; Hao,Feiyue; Liang,Lingling; Jin,Zhengneng; Wu,Jiashou
  参考文献:Organic Letters 日期:2023 卷标:25(15) 页码:2691-2695]
  
  591-50-4 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine,1,8-Diazabicyclo[5.4.0]Undec-7-Ene Catalysts: 2211997-02-1 (Silica Supported; Reaction Product With Pd2(Dba)3.CHCL3) Solvents: Dimethylformamide,Toluene; 3 H,30 Bar,100 °C
  标题:Double Carbonylation Of Iodoarenes In The Presence Of Reusable Palladium Catalysts Immobilised On Supported Phosphonium Ionic Liquid Phases
  作者:Urban,Bela; Szabo,Peter; Sranko,David; Safran,Gyorgy; Kollar,Laszlo; Et Al
  参考文献:Molecular Catalysis 日期:2018 卷标:445 页码:195-205]
  
  1548-84-1 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine Solvents: Dimethylformamide; 16 H,100 °C
  标题:A Cross-Coupling Approach To Amide Bond Formation From Esters
  作者:Ben Halima,Taoufik; Vandavasi,Jaya Kishore; Shkoor,Mohanad; Newman,Stephen G.
  参考文献:Acs Catalysis 日期:2017 卷标:7(3) 页码:2176-2180]
  
  = 93-98-1
  反应条件:1.1 Catalysts: Acetic Anhydride
  标题:Acetic Anhydride
  作者:Zibuck,Regina
  参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-8]
  
  98-88-4 = 93-98-1
  反应条件:1.1 Reagents: Triethylamine Solvents: Dichloromethane; 0 °C; 0 °C -> Rt; 16 H,Rt1.2 Reagents: Water; Rt
  标题:Oxidative Fluorination Of N-Arylsulfonamides
  作者:Buckingham,Faye; Calderwood,Samuel; Checa,Begona; Keller,Thomas; Tredwell,Matthew; Et Al
  参考文献:Journal Of Fluorine Chemistry 日期:2015 卷标:180 页码:33-39

海关参考信息

• 2912110000-甲醛
  2912210000-苯甲醛
  2924199090-其他无环酰胺
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管