CAS: 85685-99-0; 1,3-Bis(Diphenylphosphino)Propane Monooxide
- 英文名称1,3-Bis(Diphenylphosphino)Propane Monooxide
- 中文名称[3-(二苯基膦)丙基]二苯基氧化膦
- IUPAC名称1,3-bis(diphenylphosphaneyl)propan-1-one
- 其它别名1,3-Bis(Diphenylphosphino)Propane Monooxide; 3-Diphenylphosphorylpropyl(Diphenyl)Phosphane; 1,3-Bis(Diphenylphosphino)Propane Monooxide, ; Ph2Pch2Ch2Ch2P(O)Ph2; [3-(Diphenylphosphanyl)Propyl](Oxo)Dipheny
- CAS编号85685-99-0
- MFCD编号:MFCD03412077
- 分子式:C27H24OP2分子量:426.44
- 产品CID: 1854788
- 产品分类有机原料 → 有机膦化合物
上下游产品
1,3-bis-(diphenylphosphino)propane 1,3-bis(diphenylphosphoryl)propane合成工艺路线路线简述
- 6737-42-4 = 85685-99-0 + 16524-41-7
反应条件:1.1 Reagents: Oxygen Solvents: Chloroform-D
标题:31P Nmr Spectroscopic Analysis On Photooxidation Of 1,N-Bis(Diphenylphosphino)Alkanes With The Aid Of Dft Calculations
作者:Yasui,Shinro; Et Al
参考文献:Journal Of Physical Organic Chemistry 日期:2020 卷标:33(4)]
79230-20-9 + 845821-92-3 = 85685-99-0 + 79230-20-9
反应条件:1.1 -2.1 Solvents: Toluene; 24 H,100 °C
标题:Direct Oxide Transfer From An η2-Keto Ligand To Generate A Cobalt Pccarbenep(O) Pincer Complex
作者:Sung,Simon; Et Al
参考文献:Dalton Transactions 日期:2019 卷标:48(27) 页码:9920-9924]
= 85685-99-0
反应条件:1.1 Solvents: Acetone-D6
标题:Rate And Mechanism Of The Reaction Of Alkenes With Aryl Palladium Complexes Ligated By A Bidentate P,P Ligand In Heck Reactions
作者:Amatore,Christian; Et Al
参考文献:Chemistry - A European Journal 日期:2007 卷标:13(7) 页码:2002-2011]
6737-42-4 = 85685-99-0
反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Palladium Diacetate Solvents: 1,2-Dichloroethane,Water
标题:Synthesis Of Hemilabile Phosphine-Phosphine Oxide Ligands Via The Highly Selective Pd-Catalyzed Mono-Oxidation Of Bidentate Phosphines: Scope,Limitations,And Mechanism
作者:Grushin,Vladimir V.
参考文献:Organometallics 日期:2001 卷标:20(18) 页码:3950-3961]
6737-42-4 = 85685-99-0
反应条件:1.1 Reagents: 1,2-Dibromoethane,Sodium Hydroxide Catalysts: Palladium Diacetate Solvents: 1,2-Dichloroethane,Water; 6 H,Reflux
标题:Diastereoselective Rhodium Catalyzed [4 + 2] Cycloisomerization Of Allenes
作者:Li,Jun; Et Al
参考文献:Organic Letters 日期:2021 卷标:23(8) 页码:2911-2914]
6737-42-4 = 85685-99-0
反应条件:1.1 Reagents: Hydrogen Peroxide Solvents: Dichloromethane,Water; 5 Min,Rt2.1 Reagents: Trifluoromethanesulfonic Anhydride Solvents: Dichloromethane; 0 °C; 30 Min,0 °C2.2 Reagents: 1-Pentanethiol,Diisopropylethylamine; 0 °C -> Rt; 16 H,Rt
标题:Selective Mono Reduction Of Bis-Phosphine Oxides Under Mild Conditions
作者:Petersson,Maria J.; Et Al
参考文献:Chemical Communications (Cambridge 日期:2008 卷标:(37) 页码:4493-4494]
16524-41-7 = 85685-99-0
反应条件:1.1 Reagents: Trifluoromethanesulfonic Anhydride Solvents: Dichloromethane; 0 °C; 30 Min,0 °C1.2 Reagents: 1-Pentanethiol,Diisopropylethylamine; 0 °C -> Rt; 16 H,Rt
标题:Selective Mono Reduction Of Bis-Phosphine Oxides Under Mild Conditions
作者:Petersson,Maria J.; Et Al
参考文献:Chemical Communications (Cambridge 日期:2008 卷标:(37) 页码:4493-4494]
= 85685-99-0
反应条件:1.1 Solvents: Acetonitrile; Rt
标题:Photoreduction Of Carbonate In A Copper(I) Complex
作者:Kunkely,Horst; Et Al
参考文献:Inorganic Chemistry Communications 日期:2010 卷标:13(1) 页码:137-138]
6737-42-4 = 85685-99-0
反应条件:1.1 Reagents: Tetrakis(Acetonitrile)Copper(1+) Hexafluorophosphate Solvents: Methanol,Acetonitrile; 6 D,Rt2.1 Solvents: Acetonitrile; Rt
标题:Photoreduction Of Carbonate In A Copper(I) Complex
作者:Kunkely,Horst; Et Al
参考文献:Inorganic Chemistry Communications 日期:2010 卷标:13(1) 页码:137-138]
79230-20-9 + 6737-42-4 = 85685-99-0 + 79230-20-9
反应条件:1.1 Solvents: Toluene; 24 H,100 °C
标题:Direct Oxide Transfer From An η2-Keto Ligand To Generate A Cobalt Pccarbenep(O) Pincer Complex
作者:Sung,Simon; Et Al
参考文献:Dalton Transactions 日期:2019 卷标:48(27) 页码:9920-9924
📜1,3-Bis(Diphenylphosphoryl)Propane置于三氟甲磺酸酐,1-戊硫醇,N,N-二异丙基乙胺体系中,用 二氯甲烷 作为反应溶剂,化学反应 16.5H,以71%的收率获得产物[3-(二苯基膦)丙基]二苯基氧化膦
参考文献:Selective Mono Reduction Of Bis-Phosphine Oxides Under Mild Conditions
标题:Selective Mono Reduction Of Bis-Phosphine Oxides Under Mild Conditions
摘要:在非常温和的条件下,使用三氟磺酸酐和硫醇,可以将双膦氧化物选择性地还原为双膦单氧化物.
DOI:10.1039/b807695B
海关参考信息
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📌 第三方产品分析报告
合成参考文献
摘要:Carbery, D., Science of Synthesis Knowledge Updates, (2010) 3, 164.
摘要:Nilsson, P., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 289.
摘要:Liu, S.; Xiao, J., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 239.
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