CAS: 73069-13-3; Atractylenolide I

上下游产品

furan-2(4H)-on(4aα,8aβ,8α,9aβ)-4a,5,6,7,8,8a,9,9a-°Ctahydro-9-hydroxy-3,8a-dimethyl-5-methylennaphtho2,3-bfuran-2(4H)-on 9a-hydroxy-3,8a-dimethyl-5-methylene-4a,5,6,7,8,8a,9,9a-°Ctahydro-4H-naphtho[2,3-b]furan-2-one 1,2,3,4,5,8-hexahydro-1-oxo-6-methoxynaphthalene 1,2,3,4,5,8-hexahydro-1-hydroxy-6-methoxynaphthalene(+/-)-3,8a,3',8'a-tetramethyl-5,5'-dimethylene-4,4a,5,6,7,8,8a,9,4',4'a,5',6',7',8',8'a,9'-hexadecahydro-[9a,9'a]bi[naphtho[2,3-b]furanyl]-2,2'-dione (+/-)-3,8a,3',8'a-tetramethyl-5,5'-dimethylene-4,4a,5,6,7,8,8a,9,4',4'a,5',6',7',8',8'a,9'-hexadecahydro-[9a,9'a]bi[naphtho[2,3-b]furanyl]-2,2'-dione 3,8a,3',8'a-tetramethyl-5,5'-dimethylene-4,4a,5,6,7,8,8a,9,4',4'a,5',6',7',8',8'a,9'-hexadecahydro[9a,9'a]bi[naphtho[2,3-b]furanyl]-2,2'-dione 9a-hydroxy-3,8a-dimethyl-5-methylene-4a,5,6,7,8,8a,9,9a-°Ctahydro-4H-naphtho[2,3-b]furan-2-one

📜苍术酮置于吡啶,氯化亚砜,Air,三乙胺,间氯过氧苯甲酸体系中,用 四氢呋喃,甲醇,二氯甲烷 作为反应溶剂,化学反应 859.0H,反应生成 白术内酯 I
参考文献:Dimerization Of Butenolide Structures. A Biomimetic Approach To The Dimeric Sesquiterpene Lactones (+/-)-Biatractylolide And (+/-)-Biepiasterolide
标题:Dimerization Of Butenolide Structures. A Biomimetic Approach To The Dimeric Sesquiterpene Lactones (+/-)-Biatractylolide And (+/-)-Biepiasterolide
摘要:The Biomimetic Synthesis Of The Bisesquiterpene Lactones (+/-)-Biatractylolide 1 And (+/-)-Biepiasterolide 2 Via Dimerization Of The Captodative Stabilized Radical 8 Is Reported. Atractylon 7 Has Also Been Shown To Be A Possible Intermediate During The Biosynthesis Of Biatractylolide 1,Biepiasterolide 2,Atractylolide 3,And Hydroxyatractylolide 4.
DOI:10.1021/jo0488053

专利信息

专利号:CN-106386810-B
优先权日:2015-06-20
标题:New application of wild chrysanthemum polysaccharide in promoting the synthesis of atractylodes lactones in Atractylodes Rhizoma

专利号:CN-106386810-A
优先权日:2015-06-20
标 题:The new application of polysaccharides from chrysanthemi to promote the synthesis of atractylodes lactones in Atractylodes macrocephala