CAS: 60081-73-4; Sodium 4-Vinylbenzenesulfinate

主要参考文献

参考标题:Sulfur Oxoacid-Substituted And Phosphorus Oxoacid-Substituted Polyaromatic Resins And Salts Thereof As Promoters In Acrylate Production From Coupling Reactions Of Olefins And Carbon Dioxide
摘要:This Disclosure Provides For Routes Of Synthesis Of α,β-Unsaturated Carboxylic Acids And Their Salts, Including Acrylic Acid. For Example, Disclosed Is A Process For Producing An α,β-Unsaturated Carboxylic Acid Or Its Salt, Comprising: (1) Contacting A Group 8-11 Transition Metal Precursor, An Olefin, Carbon Dioxide, A Diluent, And A Sulfur Oxoacid Anion-Substituted Polyaromatic Resin Or A Phosphorus Oxoacid Anion-Substituted Polyaromatic Resin With Associated Metal Cations To Provide A Mixture; And (2) Applying Reaction Conditions To The Mixture Suitable To Produce The α,β-Unsaturated Carboxylic Acid Or A Salt Thereof. Methods Of Regenerating The Polyaromatic Resin With Associated Metal Cations Are Described.

合成参考文献

摘要:Vrána, J.; Růžička, A., Science of Synthesis Knowledge Updates, (2021) 2, 35.