CAS: 917-23-7; 5,10,15,20-Tetraphenylporphyrin

该化合物是一种高度稳定且有计划性的大型循环化合物,其组成有四个联苯组,附于一个丙烯核心,分子由于其僵硬的结构,呈现出特殊的热和化学稳定性,使它成为合成具有独特光学和电子特性的更复杂的金属卤素的理想构件.

结构式图片

相似化合物

160240-15-3 14609-51-9 14527-51-6

物理性质

MSDS等安全信息

欧盟法规

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上下游产品

CAS号100-52-7 苯甲醛 | CAS号107798-98-1 5-苯基二吡咯甲烷 | CAS号109-97-7 吡咯 | CAS号1057140-05-2 5,15-Dibromo-10... | CAS号98-80-6 苯硼酸 | CAS号27226-54-6 tetraphenylporp... | CAS号1137951-10-0 N,N'-(5,5'-(phe... | CAS号75400-63-4 2-(α-hydroxy-α-... | CAS号1137951-09-7 4-methyl-N-(phe... | CAS号58356-65-3 锰(III)内四苯基卟啉乙酸酯 | CAS号35218-75-8 四苯基卟啉四磺酸水合物 | CAS号26334-85-0 5,10,15,20-tetr... | CAS号2669-65-0 内消旋-四苯基卟吩 | CAS号32073-84-0 5,10,15,20-四苯基-... | CAS号14172-90-8 5,10,15,20-四苯基-... | CAS号14640-21-2 间四苯基卟吩镁单水合物 | CAS号14705-63-6 四苯基卟吩氧化钒 | CAS号31004-82-7 manganese tetra... | CAS号14172-92-0 四苯基卟啉镍

合成工艺路线路线简述

  • 14074-80-7 = 917-23-7
    反应条件:1.1 Reagents: Trifluoroacetic Acid Solvents: Water; 1 H,Ph 1,Rt
    标题:Zinc Porphyrin Metal-Center Exchange At The Solid-Liquid Interface
    作者:Franke,Matthias; Et Al
    参考文献:Chemistry - A European Journal 日期:2016 卷标:22(25) 页码:8520-8524]

    = 917-23-7
    反应条件:1.1 Reagents: Trifluoroacetic Acid Solvents: Chloroform
    标题:Unusual Phlorins From The Oxidative Coupling Of Pentapyrromethanes: Their Facile Conversion To Meso-Substituted Porphyrins
    作者:Ka,J.-W.; Et Al
    参考文献:Tetrahedron Letters 日期:2001 卷标:42(27) 页码:4527-4529]

    98-80-6 + 151256-86-9 = 917-23-7
    反应条件:1.1 Reagents: Sodium Carbonate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Dimethylformamide,Water
    标题:Suzuki Cross-Coupling Of Meso-Dibromoporphyrins For The Synthesis Of Functionalized A2B2 Porphyrins
    作者:Vaz,B.; Et Al
    参考文献:Tetrahedron Letters 日期:2001 卷标:42(42) 页码:7409-7412]

    98-80-6 + 151256-86-9 = 917-23-7
    反应条件:1.1 Reagents: Tripotassium Phosphate Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran
    标题:Synthesis Of Unsymmetrically Substituted Meso-Phenylporphyrins By Suzuki Cross Coupling Reactions
    作者:Shi,Baolu; Et Al
    参考文献:Journal Of The Chemical Society 日期:2002 卷标:(11) 页码:1397-1400]

    60166-10-1 = 917-23-7
    反应条件:1.1 Reagents: Acetic Anhydride; Rt -> 5 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 5 °C; 5 °C -> Rt1.3 Rt1.4 Reagents: Ferrous Sulfate; 80 Min,Rt1.5 Reagents: Sodium Hydroxide Solvents: Water; Ph 5.0 - 6.0,Rt
    标题:Investigations On The Demetalation Of Metalloporphyrins Under Ultrasound Irradiation
    作者:Sun,Chengguo; Et Al
    参考文献:Ultrasonics Sonochemistry 日期:2010 卷标:18(2) 页码:501-505]

    7697-46-3 = 917-23-7
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran1.2 Reagents: Oxygen Solvents: Propionic Acid1.3 Reagents: 2,3-Dichloro-5,6-Dicyano-1,4-Benzoquinone
    标题:A New Route For Meso-Substituted Porphyrin
    作者:Kuroda,Yasuhisa; Et Al
    参考文献:Tetrahedron Letters 日期:1989 卷标:30(18) 页码:2411-12]

    100-52-7 = 917-23-7
    反应条件:1.1 Catalysts: P-Toluenesulfonic Acid; 10 Min
    标题:Microwave Assisted Synthesis Of Meso-Tetraphenylporphyrin And Its Application For Trace Metal Spectrophotometric Determination
    作者:Givianrad,M. H.; Et Al
    参考文献:Asian Journal Of Chemistry 日期:2013 卷标:25(11) 页码:6102-6104]

    100-52-7 = 917-23-7
    反应条件:1.1 Reagents: Propionic Acid; Reflux
    标题:Metalated Porphyrins As Versatile Visible Light And Nir Photoinitiators Of Polymerization
    作者:Noirbent,Guillaume; Et Al
    参考文献:European Polymer Journal 日期:2020 卷标:139]

    14074-80-7 = 917-23-7
    反应条件:1.1 Solvents: Tributyloctylphosphonium Chloride; 0 - 100 °C
    标题:Spectroscopic And Photophysical Study Of The Demetalation Of A Zinc Porphyrin And The Aggregation Of Its Free Base In A Tetraalkylphosphonium Ionic Liquid
    作者:Giri,Neeraj K.; Et Al
    参考文献:Physical Chemistry Chemical Physics 日期:2014 卷标:16(47) 页码:26252-26260]

    14074-80-7 = 917-23-7
    反应条件:1.1 Reagents: Chloroacetic Acid,Silica; 20 Min,Rt
    标题:Observations On The Mechanochemical Insertion Of Zinc(Ii),Copper(Ii),Magnesium(Ii),And Select Other Metal(Ii) Ions Into Porphyrins
    作者:Atoyebi,Adewole O.; Et Al
    参考文献:Inorganic Chemistry 日期:2019 卷标:58(15) 页码:9631-9642]

    16456-81-8 = 917-23-7
    反应条件:1.1 Reagents: Acetic Anhydride; Rt -> 5 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 5 °C; 5 °C -> Rt1.3 Rt1.4 Reagents: Ferrous Sulfate; 60 Min,Rt1.5 Reagents: Sodium Hydroxide Solvents: Water; Ph 5.0 - 6.0,Rt
    标题:Investigations On The Demetalation Of Metalloporphyrins Under Ultrasound Irradiation
    作者:Sun,Chengguo; Et Al
    参考文献:Ultrasonics Sonochemistry 日期:2010 卷标:18(2) 页码:501-505]

    67819-97-0 = 917-23-7
    反应条件:1.1 Reagents: Acetic Anhydride; Rt -> 5 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 5 °C; 5 °C -> Rt1.3 Rt1.4 Reagents: Ferrous Sulfate; 65 Min,Rt1.5 Reagents: Sodium Hydroxide Solvents: Water; Ph 5.0 - 6.0,Rt
    标题:Investigations On The Demetalation Of Metalloporphyrins Under Ultrasound Irradiation
    作者:Sun,Chengguo; Et Al
    参考文献:Ultrasonics Sonochemistry 日期:2010 卷标:18(2) 页码:501-505]

    14172-91-9 = 917-23-7
    反应条件:1.1 Reagents: Lithium Aluminum Hydride Solvents: Tetrahydrofuran; 10 Min1.2 Reagents: Isopropanol
    标题:Unusual Properties Of Tetraphenylporphyrin Copper Complex
    作者:Nefedov,V. A.; Et Al
    参考文献:Russian Journal Of Organic Chemistry 日期:2009 卷标:45(3) 页码:449-451]

    13707-41-0 = 917-23-7
    反应条件:1.1 Catalysts: Copper(Ii) Triflate Solvents: Dichloromethane; 30 Min,Rt1.2 Solvents: Dichloromethane; 2 °C; Rt; Rt1.3 Solvents: Water; Rt
    标题:Recoverable And Reusable Catalyst For The Reaction Of N-Tosyl Imines With Pyrrole: Synthesis Of Meso-Tetraarylporphyrins
    作者:Temelli,Baris; Et Al
    参考文献:Heterocycles 日期:2012 卷标:85(4) 页码:851-860]

    107798-98-1 + 707-07-3 = 917-23-7
    反应条件:1.1 Reagents: Trifluoroacetic Acid Solvents: Dichloromethane; 30 Min,Rt; 4 H,Rt1.2 Reagents: Pyridine; Rt; 17 H,Rt1.3 Reagents: Oxygen; 15 Min,Rt; 4 H,Rt
    标题:Synthesis Of 5,15-Diarylporphyrins Via Orthoesters Condensation With Aryldipyrromethanes
    作者:Abada,Zahra; Et Al
    参考文献:Tetrahedron Letters 日期:2011 卷标:52(25) 页码:3175-3178
Tetraphenylporphyrinogen置于2,3-二氯-5,6-二氰基-1,4-苯醌,三乙胺体系中,化学反应 0.5H,反应生成 四苯基卟啉
参考文献:一种利用微反应装置制备四苯基卟啉的方法
标题:一种利用微反应装置制备四苯基卟啉的方法
摘要:本发明公开了一种利用微反应装置制备四苯基卟啉的方法,它包括如下步骤:(1)将苯甲醛,吡咯,无水乙醇与无水二氯甲烷混匀,得到均相溶液a;将三氟化硼乙醚与无水二氯甲烷混合,得到均相溶液b;(2)将上述均相溶液分别同时泵入微反应装置中;(3)收集流出液体,即为卟啉原粗品;(4)将步骤(3)得到的流出液中加入氧化剂,氮氛下搅拌反应,即得四苯基卟啉.本发明方法工艺简单,可连续生产,反应时间短,反应选择性比常规反应好,具有较高的操作安全性;同时,利用微通道反应器的高效热传质能力以及易于直接放大的特征,转化率较常规条件下有明显提高,为50%,能体现出不同于常规反应的选择性.

专利信息


专利号:US-10995049-B2
优先权日:2019-07-19
标 题 :Total synthesis of prostaglandin J natural products and their intermediates
发明人：LI JIAMING; XU CHEN; AHMED TONIA S; GRUBBS ROBERT H; STOLTZ BRIAN M
权利人:CALIFORNIA INST OF TECHN
摘要:The present disclosure is directed to methods of preparing prostaglandin J natural products by stereoretentive metatheses reactions and intermediates used in the synthesis of these natural products, including the use of intermediates of Formula (I-A), where R 1 is defined in the specification

专利号:US-5200516-A
优先权日:1990-02-16
标 题:Synthesis of sugars from substituted and unsubstituted arene diols
发明人：HUDLICKY TOMAS
权利人:VIRGINIA TECH INTELL PROP
摘要:There are disclosed processes for the synthesis of substituted and unsubstituted arene diols useful in the further synthesis of sugars, sugar derivatives, chiral synthons or amino acids.

专利号:US-5756770-A
优先权日:1987-12-31
标题:Synthesis of stable, water-soluble chemiluminescent 1,2-dioxetanes and intermediates therefor
发明人：BRONSTEIN IRENA Y; EDWARDS BROOKS
权利人:TROPIX INC
摘要:A novel synthesis of 1,2-dioxetane phosphate alkali metal salts and novel intermediates employed in this synthesis are disclosed. A hydroxyaryl enol ether alkali metal salt having the formula: ##STR1## wherein T can be an unsubstituted or substituted adamant-2'-ylidene group, R 3 can be a methyl group, Y can be a phenyl group and M + can be a sodium cation, is reacted with a phosphorohalidate to give the corresponding enol ether ethylene phosphate, which is then reacted with an alkali metal cyanide to give the corresponding enol ether cyanoethyl phosphate diester alkali metal salt intermediate. Singlet oxygen addition to this enol ether cyanoethyl phosphate diester alkali metal salt intermediate to give the corresponding 1,2-dioxetane cyanoethyl phosphate diester alkali metal salt, followed by β-elimination of the cyanoethyl group using an alkali metal hydroxide or the like, gives the corresponding 1,2-dioxetane phosphate alkali metal salt.

专利号:EP-0629195-B1
优先权日:1992-03-05
标 题 :Synthesis of stable, water-soluble chemiluminescent 1,2-dioxetanes and intermediates therefor
发明人：BRONSTEIN IRENA Y; EDWARDS BROOKS
权利人:TROPIX INC
摘要:A novel synthesis of 1,2-dioxetane phosphate alkali metal salts and novel intermediates employed in this synthesis are disclosed. A hydroxyaryl enol ether alkali metal salt having formula (1), wherein T can be an unsubstituted or substituted adamant-2'-ylidene group, R<3> can be a methyl group, Y can be a phenyl group and M<+> can be a sodium cation, is reacted with a phosphorohalidate to give the corresponding enol ether ethylene phosphate, which is then reacted with an alkali metal cyanide to give the corresponding enol ether cyanoethyl phosphate diester alkali metal salt intermediate. Singlet oxygen addition to this enol ether cyanoethyl phosphate diester alkali metal salt intermediate to give the corresponding 1,2-dioxetane cyanoethyl phosphate diester alkali metal salt, followed by beta -elimination of the cyanoethyl group using an alkali metal hydroxide or the like, gives the corresponding 1,2-dioxetane phosphate alkali metal salt.

专利号:US-9884830-B2
优先权日:2004-05-21
标题 :Synthesis of tetracyclines and analogues thereof
发明人：MYERS ANDREW G; CHAREST MARK G; LERNER CHRISTIAN D; BRUBAKER JASON D; SIEGEL DIONICIO R
权利人:HARVARD COLLEGE
摘要:The tetracycline class of antibiotics has played a major role in the treatment of infectious diseases for the past 50 years. However, the increased use of the tetracyclines in human and veterinary medicine has led to resistance among many organisms previously susceptible to tetracycline antibiotics. The modular synthesis of tetracyclines and tetracycline analogs described provides an efficient and enantioselective route to a variety of tetracycline analogs and polycyclines previously inaccessible via earlier tetracycline syntheses and semi-synthetic methods. These analogs may be used as anti-microbial agents or anti-proliferative agents in the treatment of diseases of humans or other animals.

专利号:US-6524446-B2
优先权日:2001-03-27
标 题 :Process for synthesis of a porphyrin compound using a molecular sieve catalyst under microwave irradiation
发明人：KULKARNI SHIVANAND JANARDAN; RAGHAVAN KONDAPURAM VIJAYA; MOTKURI RADHA KISHAN; NAGABANDI SRINIVAS
权利人:COUNCIL SCIENT IND RES
摘要:The present invention provides an improved process for synthesis of porphyrin compounds of the general formula 1 n from pyrrole and aromatic aldehyde over zeolite molecular sieve catalysts using microwave heating, (solvent free) to provide an eco-friendly, economical, faster and selective heterogeneous method.

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主要参考文献

1.) Glass, Sarah, Ruediger, Tom, Griebel, Jan, Abel, Bernd, Schulze, Agnes, Uptake and release of photosensitizers in a hydrogel for applications in photodynamic therapy: the impact of structural parameters on intrapolymer transport dynamics, RSC Advances (2018), 8(72), 41624-41632. DOI:10.1039/c8ra08093c 2.) Liu, Yanqiu, Wang, Liang, Feng, Hexiang, Ren, Xitong, Ji, Juanjuan, Bai, Feng, Fan, Hongyou, Microemulsion-assisted self-assembly and synthesis of size-controlled porphyrin nanocrystals with enhanced photocatalytic hydrogen evolution, Nano Letters (2019), 19(4), 2614-2619, :10.1021/acs.nanolett.9b00423 3.) Kombo, Miza, Ma, Liu-Bo, Liu, Ya-Nan, Fang, Xiao-Xiang, Ullah, Naseeb, Odda, Atheer Hameid, Xu, An-Wu, Graphitic carbon nitride/CoTPP type-II heterostructures with significantly enhanced photocatalytic hydrogen evolution, Catalysis Science & Technology (2019), 9(9), 2196-2202. DOI:10.1039/c9cy00140a. 4.) Nicolaou, et al. Total Synthesis of Epicoccin G. J. Am. Chem. Soc. 2011, 133, 21, 8150–8153 5.) Zoldan, et al. n and p type character of single molecule diodes. Sci Rep. 2015;
5: 8350.

合成参考文献


摘要:Schramm, M. P., Science of Synthesis, (2009) 46, 491.
摘要:Jux, N.; Montforts, F.-P.; Haake, E., Science of Synthesis Knowledge Updates, (2022) 1, 99.
摘要:Jux, N.; Montforts, F.-P.; Haake, E., Science of Synthesis Knowledge Updates, (2022) 1, 50.
摘要:Jux, N.; Montforts, F.-P.; Haake, E., Science of Synthesis Knowledge Updates, (2022) 1, 95.
摘要:Jux, N.; Montforts, F.-P.; Haake, E., Science of Synthesis Knowledge Updates, (2022) 1, 64.
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