CAS: 90717-03-6; 7-Chloro-3-Methylquinoline-8-Carboxylic Acid

该化合物是含有苯环的双环结构,并带有苯环,并带有环.Quimerac 对一系列的宽叶草特别有效,并经常用于谷物作物.其行动方式通常包括抑制植物中特定的生化途径,导致其生长抑制.该化合物一般是使用后出现,针对已经发酵的杂草.就物理特性而言,Quimerac 通常是在室内温度下固态,在有机溶剂中表现出中等溶性.在使用Quimmerac 时,安全和环境因素十分重要,因为任何除草剂都需要遵守所建议的应用准则,以尽量减少对非目标生物和生态系统的潜在危险.在处理或应用该物质时,必须参考相关的安全数据表和管制准则.

结构式图片

相似化合物

87293-44-5 179024-66-9 948290-52-6

欧盟法规

REACH注册ECHA物质欧盟农药活性物质ECHA物质C&L通报REACH预注册

上下游产品

8-bromomethyl-7-chloro-3-methylquinoline 2-methylpropenal 2-chloro-6-aminobenzoic acid sodium 3-nitrobenzenesulfonate7-chloro-3-methyl-N-(2-(m-tolyloxy)ethyl)quinoline-8-carboxamide

合成工艺路线路线简述

  • 合成目标产物 Quinmerac 主要起始原料 Quinoline, 8-(Bromomethyl)-7-Chloro-3-Methyl-
  • 90717-09-2 = 90717-03-6 [标题:Reaction Conditions
    标题:Preparation Of 7-Chloro-8-Quinolinecarboxylic Acids
    参考文献:European Patent Organization]

    90717-09-2 = 90717-03-6 [标题:Reaction Conditions
    标题:Preparation Of 8-Bromomethylquinolines And Their Conversion To Plant-Protective Quinolinecarboxylic Acids
    参考文献:Federal Republic Of Germany]

    90717-02-5 = 90717-03-6
    反应条件:1.1 Reagents: Sulfuric Acid,Nitric Acid
    标题:Quinoline Derivatives And Their Use For Controlling Unwanted Plant Growth
    参考文献:Federal Republic Of Germany
7-氯-3,8-二甲基喹啉置于manganese(II) Acetate,臭氧,溶剂黄146,Sodium Bromide体系中,化学反应 12.0H,以92.5%的收率获得产物精喹禾灵
参考文献:氯甲喹啉酸及其制备方法
标题:氯甲喹啉酸及其制备方法
摘要:本发明涉及除草剂合成领域,具体涉及一种氯甲喹啉酸及其制备方法,该方法包括在催化剂的存在下,以3,8‑二甲基‑7‑氯喹啉为原料,以羧酸作为反应溶剂,以含氧气体为氧化剂,进行氧化反应,其中,所述催化剂为钴类金属化合物,锰类金属化合物和钒类金属化合物中的一种或多种.通过本发明的方法,能够避免废酸和废水的大量产生,绿色环保,大大降低了三废处理成本;并且,反应条件温和,后处理简单且产品纯度及收率高,非常适合工业化生产.

海关参考信息

专利信息


专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:US-11919928-B2
优先权日:2016-03-16
标题 :Method for producing dihydrotentoxin
发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
权利人:KUMIAI CHEMICAL INDUSTRY CO
摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

专利号:ES-2717283-T3
优先权日:2012-07-24
标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids
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✅ COA系统入驻 | 共享模式

合成参考文献


参考文献:10.1093/jexbot/52.362.1811
摘要:Grossmann K, Kwiatkowski J, Tresch S. Auxin herbicides induce H(2)O(2) overproduction and tissue damage in cleavers (Galium aparine L.). J Exp Bot. 2001 Sep;52(362):1811–6. doi: 10.1093/jexbot/52.362.1811.
参考文献:10.1007/s10142-004-0119-9
摘要:Raghavan C, Ong EK, Dalling MJ, Stevenson TW. Effect of herbicidal application of 2,4-dichlorophenoxyacetic acid in Arabidopsis. Funct Integr Genomics. 2005 Jan;5(1):4–17. doi: 10.1007/s10142-004-0119-9.
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