CAS: 71501-08-1; Dipentyl(Phenyl)Phosphane
该化合物是一种第三代磷化合物,其特征是苯和磷中心的两个正-myl替代物.这种有机磷离心体因其电子施食特性和消毒散积而受到重视,因此有助于化学和催化应用的协调,特别是在过渡-金属催化反应中.它的平衡的亲性会增加有机溶剂的溶解性,有利于同质催化.该化合物在标准条件下的稳定性和金枪鱼可再活动有助于其交叉相联和水功能反应的效用.二-n-myl苯基磷光也被用于专门磷离心和有机金属研究的合成和前体.建议由于对空气敏感,在惰性条件下进行妥善处理.
MSDS等安全信息
上下游产品
n-pentylmagnesium bromide Dichlorophenylphosphine合成工艺路线路线简述
📜正戊基溴化镁,苯基二氯化磷置于乙醚体系中,化学反应生成 二戊基苯基膦
参考文献:Davies; Pearse; Jones,Journal Of The Chemical Society,1929,P. 1264
标题:Davies; Pearse; Jones,Journal Of The Chemical Society,1929,P. 1264
海关参考信息
- 2902200000-苯
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专利信息
专利号:US-9834536-B2
优先权日:2013-04-23
标题:Method for producing catalyst for cyclic carbonate synthesis
发明人：TAKAHASHI TOSHIKAZU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU; YAMAMOTO SHOUJI; NANIKI TAKASHI; FURUKAWA TAKURO
权利人:AIST; MARUZEN PETROCHEM CO LTD
摘要:A method for producing a heterogeneous catalyst for use of synthesizing cyclic carbonates by reacting an epoxide and carbon dioxide in the presence of the catalyst. A method for making a catalyst that includes forming a catalyst precursor then reacting the catalyst precursor with a tertiary phosphine.
专利号:US-3644446-A
优先权日:1969-07-01
标 题 :Preparation of rhodium and iridium hydride carbonyl complexes
发明人：BOOTH FRANK B; FENTON DONALD M; OLIVIER KENNETH L
权利人:UNION OIL CO
摘要:HYDRIDE CARBONYL COMPLEXES OF RHODIUM AND IRIDIUM WITH BIPHYLIC LIGANDS ARE PREPARED BY TREATMENT OF RHODIUM OR IRIDIUM, COMPLEXES OR SALTS THEREOF WITH AN ALKALI METAL HYDROXIDE, ALKOXIDE OR ARYLOXIDE AND A BIPHYLLIC LIGAND AND A MIDL REDUCING AGENT. IN A TYPICAL SYNTHESIS A RHODIUM CARBONYL SALT IS CONTACTED WITH AN ALKALI METAL ALKOXIDE IN THE PRESENCE OF THE LIGAND AND THE HYDRIDE IS FORMED BY SUBSEQUENT OR SIMULTANEOUS CONTACTING WITH A REDUCING AGENT SUCH AS HYDROGEN, CARBON MONOXIDE OR AN OXIDIZABLE ALCOHOL. THE COMPOUNDS HAVE UTILITY AS HYDROFORMYLATION CATALYSTS.
专利号:US-10029241-B2
优先权日:2013-04-23
标题:Method for producing catalyst for cyclic carbonate synthesis
发明人：NANIKI TAKASHI; TAKAHASHI TOSHIKAZU; YASUDA HIROYUKI; YAMAMOTO SHOUJI
权利人:MARUZEN PETROCHEM CO LTD; AIST
摘要:A method for easily producing a heterogeneous catalyst having excellent catalytic activity at a low cost is provided. The heterogeneous catalyst is used for the purpose of synthesizing a cyclic carbonate by reacting an epoxide and carbon dioxide. A catalyst obtained by this production method and a method for synthesizing a cyclic carbonate with use of this catalyst are also provided.
专利号:CN-103467335-A
优先权日:2013-09-22
标 题:A kind of method based on carbon-based rhodium catalyst hydrogenation synthesis doxycycline hydrochloride intermediate α-6-deoxyoxytetracycline
专利号:CN-103467335-B
优先权日:2013-09-22
标 题 :A kind of method based on carbon-based rhodium catalyst hydrogenation synthesis doxycycline hydrochloride intermediate α-6-deoxyoxytetracycline
