专利号:US-7417142-B2 优先权日:2002-03-28 标 题:Chiral porphyrins, chiral metalloporphyrins, and methods for synthesis of the same 发明人:ZHANG X PETER; CHEN YING; GAO GUANG-YAO 权利人:UNIV TENNESSEE RES FOUNDATION 摘要:Novel methods of synthesizing heteroatom-containing chiral porphyrins and chiral metalloporphyrins and the novel chiral porphyrins and chiral metalloporphyrins themselves are disclosed. Metal complexes of the chiral porphyrins are prepared in high yields and shown to be active catalysts for highly enantioselective and diastereoselective cyclopropanation, aziridination, and epoxidation of alkenes under a practical one-pot protocol.