CAS: 1444-65-1; 2-Phenylcyclohexanone

相似化合物

2362-61-0 34281-92-0 1444-64-0

上下游产品

CAS号2362-61-0 反-2-苯基-1-环己醇 | CAS号108-94-1 环己酮 | CAS号108-90-7 氯苯 | CAS号108-86-1 溴苯 | CAS号64020-33-3 1-phenylhex-5-e... | CAS号100-59-4 苯基氯化镁 | CAS号771-98-2 1-苯基-1-环己烯 | CAS号822-87-7 2-氯环己酮 | CAS号98-80-6 苯硼酸 | CAS号1444-64-0 2-苯基环己醇 | CAS号105593-82-6 1-(2-methylsela... | CAS号4144-62-1 5-苯甲酰基戊酸 | CAS号65-85-0 苯甲酸 | CAS号4248-25-3 ethyl 6-oxo-6-p... | CAS号22591-17-9 (NZ)-N-(2-pheny... | CAS号2201-17-4 N,N-二甲基-1-苯基环己烷-1-胺 | CAS号771-98-2 1-苯基-1-环己烯 | CAS号98919-68-7 (1R,2S)-反-2-苯基-1-环己醇 | CAS号34281-92-0 (1S,2R)-反-2-苯基-1-环己醇 | CAS号827-52-1 环己基苯

1-(4-喹啉基)甲胺置于甲醇,Sodium Tetrahydroborate,四(三苯基膦)钯,Cerium(III) Chloride Heptahydrate,15% Palladium On Carbon,氢气,Potassium Carbonate,溶剂黄146,1,1'-(Phenyl-λ3-Iodane)Bis(Pyridinium) Trifluoromethanesulfonate体系中,用 甲醇,1,2-二氯乙烷,甲苯 用作溶剂,化学反应 25.0H,反应生成2-苯基环己酮
参考文献:N-连接的λ3-碘化物对赤道醇的化学选择性氧化
标题:N-连接的λ3-碘化物对赤道醇的化学选择性氧化
摘要:复杂多元醇中醇的位点选择性和化学选择性官能化仍然是一个艰巨的合成挑战.尽管在氧中心的选择性衍生化方面已取得重大进展,但化学选择性氧化为相应的羰基的进展却很少.在循环系统中,虽然对轴型醇的选择性氧化是众所周知的,但尚未报道互补的赤道选择性过程.本文中,我们报道了氮连接的(双)阳离子λ3-碘(n-Hvis)在醇氧化中的应用以及它们对赤道醇与轴向醇的氧化选择性的空前水平.条件温和,简单的吡啶连接试剂(py-Hvi)可以很容易地从商业phi(oac)2合成,可以分离或原位生成.
Doi:10.1021/acs.Orglett.9B02018

专利信息

专利号:US-4895996-A
优先权日:1988-10-17
标 题 :Synthesis of alkenes from enamines via hydroboration
发明人：GORALSKI CHRISTIAN T; SINGARAM BAKTHAN; BROWN HERBERT C
权利人:PURDUE RESEARCH FOUNDATION; DOW CHEMICAL CO
摘要:Alkenes are prepared by the hydroboration of enamines followed by an elimination reaction to form the alkene. This process has wide applicability and is useful for the stereospecific synthesis of [Z] isomers. It is preferred to use 9-borabicyclo[3.3.1 nonane as the hydroborating agent and to use methanol to catalyze the elimination reaction.

专利号:US-7884243-B2
优先权日:2003-12-22
标 题:Process for the synthesis of eneamide derivatives
发明人：BURGOS ALAIN; BERTRAND BLANDINE; ROUSSIASSE SONIA; PLUVIE JEAN-FRANCOIS; BLANCHET SYLVIE; MARTIN JULIETTE; PERRIN FLORENCE; BOURDEAU FRANCOISE
权利人:ZACH SYSTEM
摘要:A process for the production of ene-amide derivatives represented by the formula (I) n nwherein R1 and R2 and R3 are independently a hydrogen atom, an alkyl, a cycloalkyl, a cycloalkylalkyl, an alkylaryl, an aryl, a heterocycle, a cyano, an alkoxy, an aryloxy, a carboxyl, a carbamoyl, —CONR5R6 (in which R5 and R6 are independently an alkyl, arylalkyl or aryl group said ring being substituted or not with a functional group or with R5) or —COOR5 group (in which R5 is an alkyl, alkylaryl or aryl group), said alkyl, cycloalkyl, cycloalkylalkyl, alkylaryl and aryl groups being substituted or not with a functional group or with R5; or R1 and R2 taken together, may form a ring (which terms includes mono-, di- and higher polycyclic ring systems); R4 is a hydrogen atom, an alkyl, an aryl, an alkylaryl, said groups are substituted or not with a halogen atom as Cl, Br, or F; X is an oxygen atom or a leaving group and m is an integer 1 or 2; when m is 1 then X is a leaving group; when m is 2 then X is a oxygen atom, which comprise: a hydrogenation/isomerization reaction in presence of a heterogeneous catalyst, of an oxime derivatives of formula (II)n n nwherein R1, R2 and R3 are as defined above with an acyl derivative of formula (III) (R4CO) m X wherein R4, m and X are as defined above.

专利号:US-3814767-A
优先权日:1972-04-07
标 题 :Process for preparing bicyclo alkyl derivatives
发明人：WARD F
权利人:MILES LAB
摘要:A PROCESS FOR THE SYNTHESIS OF BICYCLO ALKYL DERIVATIVES OF THE STRUCTUAL FORMULA: 2,6-(-CH2-X-CH2-),2-R4,3-R1,4-R2,5-R5-CYCLOHEXANONE IN WICH R1 IS H OR PHENYL, R2 IS H OR ALKYL, R4 IS H PHENYL OR SUBSTITUTED PHENYL IN WHICH THE SUBSTITUENTS ARE HALOGEN, ALKOXY, OR ALKYL, R5 IS 4-(R3-PHENYL)PIPERAZINO OR 4-(R3-PHENYL)PIPERIDINO, R3 IS H, HALOGEN, ALKOXY OR CF3, AND X IS A POLYCARBON LOWER ALKYLENE RADICAL OF BETWEEN 0 AND 2 CARBON ATOMS INCLUSIVE, COMPRISING THE FOLLOWING REACTION SEQUENCE: O=CH-CH(-R2)-CH(-R1)-C(-R4)<(-CO-CH2-CH2-X-CH2-) + H-R5 --> (- H2O) R5-CH=C(-R2)-CH(-R1)-C(-R4)<(-CO-CH2-CH2-X- CH2-) --> (DELTA, DMF OR (I-PR-)OH, (ET-)3-N) 2,6-(-CH2-X- CH2-),2-R4,3-R1,4-R2,5-R5-CYCLOHEXANONE THE COMPOUNDS PREPARED ACCORDING TO THE PROCESS OF THIS INVENTION HAVE BENEFICIAL PHARMACOLOGICAL PROPERTIES.

专利号:CN-115161297-A
优先权日:2022-05-09
标 题 :Three-enzyme nanoreactor and its application and synthesis of chiral tertiary α-phenylcycloalcohol

专利号:US-7132092-B2
优先权日:2002-02-08
标 题:Metallized mesoporous silicate and method of oxidation with the same
发明人：HAGIYA KOJI
权利人:SUMITOMO CHEMICAL CO
摘要:A metallized mesoporous silicate which is obtained by (i) reacting (a) either a metal peroxide obtained by the reaction of an aqueous hydrogen peroxide solution with at least one metal or metal compound selected from the group consisting of the following 1) to 4) 1) tungsten 2) molybdenum 3) vanadium 4) compounds comprising 4 a ) any of tungsten, molybdenum, and vanadium and 4 b ) at least one element selected from Groups 13 to 16 (excluding oxygen) or a solution of the metal peroxide with (b) a silicon compound in the presence of an alkylamine or a quaternary ammonium salt and separating the resultant silicate; and a process for producing the metallized mesoporous silicate. Also provided is a method of organic synthesis with the silicate.

专利号:US-2007129573-A1
优先权日:2003-12-22
标 题:Process for the synthesis of eneamide derivatives