CAS: 6008-36-2; N-Nonanophenone

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📜壬酸置于n,N'-羰基二咪唑体系中,用 四氢呋喃,二氯甲烷,二丁醚 作为反应溶剂,化学反应 1.0H,反应生成 辛基苯基酮
参考文献:用水电还原实现苄基烯烃的定点加氢/氘化
标题:用水电还原实现苄基烯烃的定点加氢/氘化
摘要:苄基烯烃的电还原已应用于位点选择性氢化此类双键,同时存在在常规氢化条件下反应的其他功能.通过使用水作为质子源,该协议还允许通过简单地切换到 D 2 O 进行氘化.该方法的适用性通过使用商用电解装置和广泛的底物范围得到证明.
DOI:10.1002/chem.202300849

专利信息

专利号:US-7517828-B2
优先权日:2003-04-25
标 题 :Chiral broensted acid catalyst for asymmetric synthesis and method of asymmetric synthesis with the catalyst
发明人：AKIYAMA TAKAHIKO
权利人:TOAGOSEI CO LTD
摘要:A compound usable as an asymmetric synthesis catalyst which can be easily synthesized without using any metal such as a lanthanoid group element; a method of asymmetric synthesis with the compound; and a chiral compound obtained by the asymmetric synthesis method. A Broensted acid is used as a catalyst in asymmetric synthesis, the chiral Broensted acid being represented by formula (1) below or formula (3) below. The asymmetric synthesis method employs the catalyst. Asymmetric synthesis with the catalyst gives a chiral compound.

专利号:US-5211889-A
优先权日:1991-08-01
标 题:Soluble highly reactive form of calcium and reagents thereof
发明人：RIEKE REUBEN D
权利人:UNIV NEBRASKA
摘要:A soluble highly reactive form of calcium, prepared from Ca(II) salts and a reducing agent in ethereal, polyethereal, or hydrocarbon solvents, is presented. This form of calcium can be used in the preparation of organocalcium reagents. The organocalcium reagents resulting from the reaction of the soluble highly reactive calcium with organic compounds containing either halide, cyanide, a 1,3-diene, or a polyunsaturated functionality, are stable, useful reagents for organic synthesis. The organocalcium halide reagents undergo Grignard-type reactions. They also undergo reactions with Cu(I) salts to form organocalcium cuprate reagents. The organocalcium cuprate reagents undergo a variety of cross-coupling reactions. The soluble highly reactive calcium reacts with 1,3-dienes to yield the corresponding 2-butene-1,4-diylcalcium complexes. These bis-organocalcium reagents can undergo dialkylation reactions with α,ω-alkylene dihalides and dichlorosilanes to form the corresponding 3-, 5-, and 6-membered ring derivatives. The soluble highly reactive calcium also reacts with organic dihalides to form mono- or diorganocalcium compounds which can be converted into a wide variety of polymers.

专利号:US-5384078-A
优先权日:1991-08-01
标 题:Soluble highly reactive form of calcium and reagents thereof
发明人：RIEKE REUBEN D
权利人:UNIV NEBRASKA
摘要:A soluble highly reactive form of calcium, prepared from Ca(II) salts and a reducing agent in ethereal, polyethereal, or hydrocarbon solvents, is presented. This form of calcium can be used in the preparation of organocalcium reagents. The organocalcium reagents resulting from the reaction of the soluble highly reactive calcium with organic compounds containing either halide, cyanide, a 1,3-diene, or a polyunsaturated functionality, are stable, useful reagents for organic synthesis. The organocalcium halide reagents undergo Grignard-type reactions. They also undergo reactions with Cu(I) salts to form organocalcium cuprate reagents. The organocalcium cuprate reagents undergo a variety of cross-coupling reactions. The soluble highly reactive calcium reacts with 1,3-dienes to yield the corresponding 2-butene-1,4-diylcalcium complexes. These bis-organocalcium reagents can undergo dialkylation reactions with α,ω-alkylene dihalides and dichlorosilanes to form the corresponding 3-, 5-, and 6-membered ring derivatives. The soluble highly reactive calcium also reacts with organic dihalides to form mono- or diorganocalcium compounds which can be converted into a wide variety of polymers.

专利号:US-2006276329-A1
优先权日:2003-04-25
标题:Asymmetric synthesis catalyst based on chiral brsnsted acid and method of asymmetric synthesis with the catalyst

专利号:EP-1623971-A1
优先权日:2003-04-25
标 题:Asymmetric-synthesis catalyst based on chiral broensted acid and method of asymmetric synthesis with the catalyst

专利号:WO-2012131084-A1
优先权日:2011-03-31
标题 :Triaryl- and triheteroaryl- benzene monomers and polymers
发明人：MCCULLOCH IAIN; HEENEY MARTIN; NIELSEN CHRISTIAN; ZHANG WEIMIN; FRASER JAMIE; SCHROEDER BOB
权利人:IMP INNOVATIONS LTD; MCCULLOCH IAIN; HEENEY MARTIN; NIELSEN CHRISTIAN; ZHANG WEIMIN; FRASER JAMIE; SCHROEDER BOB
摘要:The invention relates to novel mono-, oligo- and polymeric compounds comprising substituted triaryl- and triheteroaryl benzene groups and their copolymers. The invention further relates to the methods of their synthesis, to organic semiconducting materials and blends, formulations and layers comprising them, and to electronic devices, like organic field effect transistors (OFETs) and organic photovoltaics (OPVs), comprising them.