2-氟苯甲醚置于氢溴酸,溴,溶剂黄146体系中,用 氯仿,N,N-二甲基甲酰胺 用作溶剂,化学反应 16.0H,反应生成3-氟-4-羟基苯甲酸 参考文献:Influence Of Fluoro Substituents On The Mesophase Behaviour Of Banana-Shaped Molecules 标题:Influence Of Fluoro Substituents On The Mesophase Behaviour Of Banana-Shaped Molecules 摘要:基于间苯二甲酸酯作为中心核以及偶氮次甲基键合,本文介绍了三种新的弯形五环液晶系列.它们的外环上卤素取代基的数量和位置不同.这种侧向取代强烈影响所形成的介晶相类型.为了确定沿不同分子电荷分布的改变,进行了计算. Doi:10.1039/b201467J
专利号:US-5098602-A 优先权日:1988-05-11 标题 :Novel halogen-containing ester compounds, and their intermediates, and method of producing the same as well as liquid crystal compositions containing the same and light switching elements 发明人:HIRAI TOSHIHIRO; YOSHIZAWA ATSUSHI; NISHIYAMA ISA; FUKUMASA MITSUO; SHIRATORI NOBUYUKI; YOKOYAMA AKIHISA 权利人:NIPPON MINING CO 摘要:This invention provides a novel halogen-containing ester compound represented by the following general formula (I): ##STR1## (wherein R is an alkyl group, A is selected from a single bond, --O--, --COO-- and --CO--, both of X and Y are halogen atoms or either one of X and Y is a halogen atom and the other is a hydrogen atom, each of m and n is 0 or 1, m+n=0 or 1, each of k and l is an integer of 1 or more, provide k 专利号:US-7005552-B2 优先权日:2003-11-03 标题:Single reactor synthesis of KOH-capped polyols based on DMC-synthesized intermediates 发明人:KAUSHIVA BRYAN D 权利人:BAYER MATERIALSCIENCE LLC 摘要:The present invention relates to processes for preparing ethylene oxide (EO)-capped polyols in which removal of catalyst residues or salts formed by the neutralization of the basic catalyst is not required prior to discharging the polyol from the reactor because neutralization occurs during or after the starter charge of a subsequent batch. The inventive processes allow for the preparation of DMC-catalyzed intermediates and their base-catalyzed EO caps within the same reactor. Polyols produced by the processes of the invention have a high content of primary hydroxyl groups and may be useful for producing polyurethane foams, elastomers, sealants, coatings, adhesives and the like.
专利号:JP-2005163022-A 优先权日:2003-11-03 标题 :Single reactor synthesis of KOH-capped polyols based on DMC synthesis intermediates
专利号:JP-5062951-B2 优先权日:2003-11-03 标 题:Single reactor synthesis of KOH-capped polyols based on DMC synthesis intermediates
专利号:CA-2486337-A1 优先权日:2003-11-03 标题:Single reactor synthesis of koh-capped polyols based on dmc-synthesized intermediates
专利号:EP-1528073-A1 优先权日:2003-11-03 标 题 :Single reactor synthesis of polyols capped using basic catalysts and being based on intermediates synthesized using DMC-catalysts
[参考文献]: R H Felton, Et Al. Solvent Proton Magnetic Resonance Dispersion In Protocatechuate 3,4-Dioxygenase And Complexes With 3-Halo-4-Hydroxybenzoate Inhibitors. Biochemistry. 1984 Aug 14;23(17):3955-9.