2-羟基-5-甲基嘧啶置于potassium Permanganate,水,三溴化磷,铜体系中,化学反应生成2,2'-联吡啶-5,5'-二羧酸 参考文献:The Synthesis Of Certain Substituted 2,2'-Bipyridyls1 标题:The Synthesis Of Certain Substituted 2,2'-Bipyridyls1 摘要: Doi:10.1021/ja01216A045
专利号:US-2014046064-A1 优先权日:2010-12-03 标题:Process for the Synthesis of Precursor Complexes of Titanium Dioxide Sensitization Dyes Based on Ruthenium Polypyridine Complexes 发明人:BOARETTO RITA; BUSATTO EVE; CARLI STEFANO; FRACASSO SANDRO; CARAMORI STEFANO; BIGNOZZI CARLO ALBERTO 权利人:DYEPOWER 摘要:The present invention concerns a process for the synthesis of precursor complexes and titanium dioxide sensitizing dyes based on ruthenium polypyridine complexes comprising the microwave irradiation under high pressure and in aqueous environment system of precursor complexes and sensitizers based on carboxylic functionalized ruthenium polypyridine complexes
专利号:US-2015361267-A1 优先权日:2010-12-03 标 题:Process for the Synthesis of Precursor Complexes of Titanium Dioxide Sensitization Dyes Based on Ruthenium Polypyridine Complexes 发明人:BOARETTO RITA; BUSATTO EVA; CARLI STEFANO; FRACASSO SANDRO; CARAMORI STEFANO; BIGNOZZI CARLO ALBERTO 权利人:DYEPOWER 摘要:The present invention concerns a process for the synthesis of both precursor complexes and dye sensitizers for titanium dioxide based on ruthenium polypyridine complexes comprising microwave irradiation, under high pressure and in aqueous environment system
专利号:US-2022089618-A1 优先权日:2019-01-29 标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks 发明人:MAJANO GERARDO J; FALKOWSKI JOSEPH M 权利人:EXXONMOBIL RES & ENG CO 摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.
专利号:US-10737239-B2 优先权日:2015-11-27 标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks 发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich 权利人:BASF SE 摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.
专利号:US-2021053903-A1 优先权日:2019-08-23 标 题:Applying hansen solubility parameters to metal-organic framework synthesis conditions 发明人:ABNEY CARTER W; IVASHKO ANNA C 权利人:EXXONMOBIL RES & ENG CO 摘要:A method suitable for use in investigating synthesis conditions for metal-organic frameworks may include: identifying synthesis conditions that includes a first solvent system by which a metal-organic framework is successfully synthesized; and synthesizing the metal-organic framework under substantially the same synthesis conditions but with a second solvent system (or a comparable solvent system) having a difference (R a ) between Hansen solubility parameters of 5 MPa 0.5 or less as compared to the first solvent system.
专利号:US-2018333696-A1 优先权日:2015-11-27 标题:Ultrafast high space-time-yield synthesis of metal-organic frameworks
[参考文献]: N J Hales, Et Al. Novel Inhibitors Of Prolyl 4-Hydroxylase. 5. The Intriguing Structure-Activity Relationships Seen With 2,2'-Bipyridine And Its 5,5'-Dicarboxylic Acid Derivatives. J Med Chem. 1993 Nov 26;36(24):3853-8.
合成参考文献
参考文献:10.1021/ic049755n 摘要:Gago S, Pillinger M, Valente AA, Santos TM, Rocha J, Gonçalves IS. Immobilization of oxomolybdenum species in a layered double hydroxide pillared by 2,2'-bipyridine-5,5'-dicarboxylate anions. Inorg Chem. 2004 Aug 23;43(17):5422–31. doi: 10.1021/ic049755n.