CAS: 1467-16-9; 1H-Imidazole Hydrochloride

该化合物是一种以其化和氯化阴离子为特征的离子液体,一般是白色的,白色的固体或晶状物质;该化合物以高热稳定性和低挥发性而著称,适合有机合成和催化的各种应用;氯化在极地溶剂中表现出良好的溶解性,可以作为刘易斯酸,促进有机化学的反应;其结构允许形成氢联结,从而促成其独特的特性,包括离子导性;此外,在电池和燃料电池以及金属的提取和分离过程中,常常使用盐来开发电解剂;氨环的存在具有有趣的电化学特性,使其成为材料科学和绿色化学等领域研究的课题;

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CAS号288-32-4 咪唑 | CAS号75-44-5 光气 | CAS号503-38-8 氯甲酸三氯甲酯 | CAS号79-44-7 二甲氨基甲酰氯 | CAS号288-32-4 咪唑 | CAS号12125-02-9 氯化铵

合成工艺路线路线简述

    咪唑置于盐酸体系中,用 水 用作溶剂,化学反应 4.0H,反应生成咪唑盐酸盐
    参考文献:基于咪唑鎓的新型室温离子液体和低熔点混合物:用于化学和生物应用的廉价离子溶剂
    标题:基于咪唑鎓的新型室温离子液体和低熔点混合物:用于化学和生物应用的廉价离子溶剂
    摘要:基于绿色成分,廉价来源,高纯度和易于制备的新型质子离子液体 (Pil) 和低熔点混合物 (Lmm) 已被合成.Pil 包括 [im][for],[im][ace],[im][pro],[im][but] 和 [im][pen].Lmm 包括 [imcl][eg],[imcl][gly],[imcl][peg],[imcl][eta] 和 [imcl][碳水化合物] + Dmso.这些溶剂包含咪唑鎓/咪唑鎓氯化物作为阳离子/盐.NMR光谱用于分析溶剂的结构.通过热分析测量熔点和热稳定性.我们希望用氯化咪唑鎓 (Imcl) 合成新的 Des;由于缺乏对 Imcl + 氢键供体 (Hbd) 混合物的熔点的观察,这些混合物在这项工作中被称为低熔点混合物 (Lmm).Pils/lmms 与分子溶剂的混合物对可用于分离目标的同质和异质系统显示出非常好的影响.碳水化合物和一些氨基酸的溶解度在纯离子液体和分子液体的混合中进行了测试.将
    Doi:10.1016/j.Molliq.2021.117877

    专利信息


    专利号:US-8410301-B2
    优先权日:2007-11-28
    标题:Methods for the synthesis of organic sulfides by using sulfides and organic sulfur-indium complexes
    发明人:LEE PHIL-HO
    权利人:LEE PHIL-HO; KNU INDUSTRY COOPERATION FOUND
    摘要:The present invention relates to a novel synthesis method for the formation of carbon-sulfur bonds by the reaction of an organic sulfur-indium complex with nucleophile in the presence of a palladium catalyst. The present invention provides a synthesis method to prepare several kinds of organic sulfides which are difficult to be prepared by the conventional synthesis methods. A short reaction time and quantitative yield are the advantages of this method. In addition, several kinds of organic sulfide can be prepared by the selection of nucleophile and organic sulfur-indium complex to be used.

    专利号:US-7906490-B2
    优先权日:1993-04-15
    标 题 :Circular DNA vectors for synthesis of RNA and DNA
    发明人:KOOL ERIC T
    权利人:UNIV ROCHESTER
    摘要:The present invention provides methods for synthesis and therapeutic use of DNA and RNA oligonucleotides and analogs. RNA oligonucleotides are synthesized using a small, circular DNA template which lacks an RNA polymerase promoter sequence. The RNA synthesis is performed by combining a circular single-stranded oligonucleotide template with an effective RNA polymerase and at least two types of ribonucleotide triphosphate to form an RNA oligonucleotide multimer comprising multiple copies of the desired RNA oligonucleotide sequence. Preferably, the RNA oligonucleotide multimer is cleaved to produce RNA oligonucleotides having well-defined ends. Preferred RNA oligonucleotide multimers contain ribozymes capable of both cis (autolytic) and trans cleavage.

    专利号:US-6368802-B1
    优先权日:1993-04-15
    标 题 :Circular DNA vectors for synthesis of RNA and DNA
    发明人:KOOL ERIC T
    权利人:UNIV ROCHESTER
    摘要:The present invention provides methods for synthesis and therapeutic use of DNA and RNA oligonucleotides and analogs. RNA oligonucleotides are synthesized using a small, circular DNA template which lacks an RNA polymerase promoter sequence. The RNA synthesis is performed by combining a circular single-stranded oligonucleotide template with an effective RNA polymerase and at least two types of ribonucleotide triphosphate to form an RNA oligonucleotide multimer comprising multiple copies of the desired RNA oligonucleotide sequence. Preferably, the RNA oligonucleotide multimer is cleaved to produce RNA oligonucleotides having well-defined ends. Preferred RNA oligonucleotide multimers contain ribozymes capable of both cis (autolytic) and trans cleavage.

    专利号:EP-1641729-B1
    优先权日:2003-07-09
    标题:Use of functionalized onium salts as a soluble support for organic synthesis
    发明人:VAULTIER MICHEL; GMOUH SAID; HASSINE FATIMA
    权利人:CENTRE NAT RECH SCIENT; UNIV RENNES
    摘要:The invention relates to the use of a onium salt functionalized by at least one organic function, as a soluble support, in the presence of at least one organic solvent, for organic synthesis of a molecule, in a homogenous phase, by at least one transformation of said organic function. The onium salt enables the synthesized molecule to be released. The onium salt is present in liquid or solid form at room temperature and corresponds to formula A1+, X1-, wherein A1+ represents a cation and X1- represents an anion.

    专利号:US-11848117-B2
    优先权日:2017-12-06
    标题:Thin and uniform silver nanowires, method of synthesis and transparent conductive films formed from the nanowires
    发明人:HU YONGXING; LI YING-SYI; YANG XIQIANG; ANG JING SHUN; VIRKAR AJAY
    权利人:C3 NANO INC
    摘要:Highly uniform and thin silver nanowires are described having average diameters below 20 nm and a small standard deviation of the diameters. The silver nanowires have a high aspect ratio. The silver nanowires can be characterized by a small number of nanowires having a diameter greater than 18 nm as well as with a blue shifted narrow absorption spectrum in a dilute solution. Methods are described to allow for the synthesis of the narrow uniform silver nanowires. Transparent conductive films formed from the thin, uniform silver nanowires can have very low levels of haze and low values of ΔL*, the diffusive luminosity, such that the transparent conductive films can provide little alteration of the appearance of a black background.

    专利号:US-7109348-B1
    优先权日:2002-08-30
    标题 :Synthesis of 1,3 distributed imidazolium salts
    发明人:NOLAN STEVEN P
    权利人:UNIV NEW ORLEANS RES AND TECHN
    摘要:Imidazolium salts are the immediate precursors to N-heterocyclic carbenes (NHC) yet a simple, general synthetic route to a wide variety of imidazolium salts is not yet available. Such a straightforward route is described for two specific members of this family of ligand precursor: 1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride (IMes.HCl) and 1,3-Bis(2,6-diispropylphenyl)imidazolium chloride (IPr.HCl). The procedure appears general and similar protocols can be used to isolate various imidazolium salts.
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    参考标题:Continuous Flow Solvent Free Organic Synthesis Involving Solids (Reactants/products) Using A Screw Reactor
    作者:Brijesh M. Sharma,Ranjit S. Atapalkar,Amol A. Kulkarni
    摘要:Nucleophilic Substitutions, Protection, Acylations And Coupling Reactions Using A Mechanochemical Approach At A Controlled Temperature Using A Single Synthesis Platform. Almost Minimal Solvents Or Solvent-Free Conditions Are Used, Making It A Very Efficient And Clean Synthesis Of Various Products. A Jacketed Screw Reactor When Operated At Different Temperatures (0 °C To 160 °C) And Over A Range Of

    合成参考文献


    参考文献:10.1007/s11745-999-0402-8
    摘要:Aoyama Y, Amano N, Yoshida A. Cholesterol synthesis and degradation in normal rats fed a cholesterol-free diet with excess cystine. Lipids. 1999 Jun;34(6):583–9. doi: 10.1007/s11745-999-0402-8.
    参考文献:10.1007/bf00965879
    摘要:Roberts E, Liron Z, Wong E. Potentiation of Na+-dependent uptake of gamma-aminobutyric acid in mouse brain particles by buffer-mediated proton removal. Neurochem Res. 1985 Aug;10(8):1025–46. doi: 10.1007/bf00965879.
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