CAS: 124878-55-3; 2-Iodo-1-Phenyl-Pentane-1-One
MSDS等安全信息
上下游产品
苯戊酮 Phenyl Butyl Ketone 1009-14-9合成工艺路线路线简述
- 合成目标产物 2-Iodo-1-Phenylpentan-1-One 主要起始原料 Valerophenone
- (文献来源)合成步骤主要原料 Valerophenone
📜苯戊酮置于碘体系中,用 乙二醇二甲醚 用作溶剂,化学反应 3.0H,以87%的收率获得2-碘-1-苯基-1-戊酮
参考文献:Metal Catalyst-Free Direct α-Iodination Of Ketones With Molecular Iodine
标题:Metal Catalyst-Free Direct α-Iodination Of Ketones With Molecular Iodine
摘要:Ketones Are Directly Converted To The Corresponding Alpha-Iodoketones In Good Yields With Molecular Iodine Under Metal Catalyst-Free Conditions. A Significant Difference In The Reactivities Was Observed For Aliphatic And Aromatic Ketones; Whereas Aliphatic Ketones Reacted Smoothly At Room Temperature Giving A Mixture Of 1-Iodo,3-Iodo And 1,3-Diiodoketones With Predominant Formation Of The 3-Iodo Product,The A-Iodination Of Aromatic Ketones Proceeded Conveniently Under Heating To Give Good Yields Of Alpha-Iodo Products. (C) 2006 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Tetlet.2006.07.057
海关参考信息
- 2902600000-乙苯
2912110000-甲醛
2912120000-乙醛
2912210000-苯甲醛 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Chemistry Of α-Nitroepoxides : Synthesis Of Useful Intermediates Via Nucleophilic Ring Opening Of α-Nitroepoxides作者:Yashwant D. Vankar,Kavita Shah,Anita Bawa,Surendra P. Singh |发布日期:1991.10
摘要:Various α-Nitroepoxides Are Converted Into Corresponding 1,2-Diketones Via Two Different Ways Of Ring Opening Viz. With Pd(O) And With Dmso/bf3.Et2O(Or Clsime3). In Addition To This, A Variety Of Nucleophiles Are Reacted With α-Nitrocyclopentene Oxide 6 And α-Nitro-Cyclohexene Oxide 7 To Form The Corresponding α-Substituted Ketones Which Are Useful Intermediates In Organic Synthesis. Two Of The Products
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