2386-57-4 = 870-72-4 反应条件:1.1 Reagents: Sulfuric Acid,Oxygen Catalysts: Cupric Chloride,Disodium Hexachloroplatinate Solvents: Water 标题:Catalytic Shilov Chemistry: Platinum Chloride-Catalyzed Oxidation Of Terminal Methyl Groups By Dioxygen 作者:Lin,Minren; Et Al 参考文献:Journal Of The American Chemical Society 日期:2001 卷标:123(5) 页码:1000-1001]
14254-57-0 = 870-72-4 反应条件:1.1 Catalysts: Cyclopropyllithium 标题:On The Preparation Of 5,6-Dihydro-1,4-Dithiins Via 1,3-Dithiolane Intermediates 作者:Nevalainen,Vesa; Et Al 参考文献:Finnish Chemical Letters 日期:1987 卷标:14(2) 页码:63-9
专利号:US-6924385-B2 优先权日:2002-11-18 标 题:Method for synthesis of aliphatic isocyanates from aromatic isocyanates 发明人:LETTMANN CHRISTIAN; KOHLSTRUK STEPHAN; STOCHNIOL GUIDO; SPYROU EMMANOUIL 权利人:DEGUSSA 摘要:The invention relates to a method for synthesis of aliphatic isocyanates from aromatic isocyanates in substantially 3 stages. In particular, the invention relates to a method for synthesis of bis{4-isocyanatocyclohexyl}methane (H 12 MDI) from bis{4-isocyanatophenyl}methane (MDI). More especially, the invention relates to a method for synthesis of H 12 MDI with a trans-trans isomer content of <30%, preferably of <20%, particularly preferably of 5 to 15%.
专利号:US-4293503-A 优先权日:1980-01-10 标题 :Synthesis of polyol bis(allyl carbonate) utilizing reagent recovery and recycle 发明人:YOUNG ELGIN E 权利人:PPG INDUSTRIES INC 摘要:Disclosed is an improved method of forming polyol (allyl carbonate) monomers. In the disclosed method, the organic by-products as diallyl carbonate and unreacted reagents as allyl alcohol are separated from the brine and wash water derived aqueous phase and returned to the allyl carbonate synthesis reaction. The aqueous phase is further separated to recover allyl alcohol therefrom, which is returned to the allyl carbonate synthesis reactor as an azeotrope.
专利号:US-5726332-A 优先权日:1995-09-21 标 题 :Synthesis of novel organometallics and their use in olefin polymerization 发明人:EISCH JOHN J; UZICK WOLFRAM; MACKENZIE KATRIN; GURTZGEN STEFAN; RIEGER RAINER 权利人:WITCO GMBH; UNIV NEW YORK STATE RES FOUND 摘要:Novel bimetallic organometallic compounds, their synthesis and application in polymerization catalyst system based on combination of such novel bimetallic organometallic compounds with transition metal complexes is provided.
专利号:WO-2024201367-A1 优先权日:2023-03-30 标 题:Process for sulfoalkylation of k-humates 发明人:KLEINHANS GEORGE; STANDER BAREND FREDERIK; HUYSER JOHANNES JACOBUS 权利人:OMNIA GROUP PTY LIMITED 摘要:The invention relates to a process for the preparation of a potassium humate ('K- humate') that is stable at pH of from at least 0.5, optionally including in the presence of divalent and trivalent cations, without aggregation occurring, comprising an initial step of synthesis of a formaldehyde-sodium/potassium bisulphite adduct, prepared via the addition of formaldehyde to a solution of sodium/potassium sulphite, followed by subsequent addition of the formaldehyde-sodium bisulphite adduct to an aqueous solution of K-humate and reacting the mixture at elevated temperatures to obtain the stable K-humate. The invention further relates to methods for stimulating plant growth with the use of the stable K-humate produced by the process of the invention.
专利号:US-10407402-B1 优先权日:2019-02-13 标题:Method for synthesis of chalcogenophenes 发明人:HAN CHIEN-CHUNG; KARAPALA VAMSI KRISHNA 权利人:UNIV NAT TSING HUA 摘要:A method of forming a chalcogenophene compound of formula (I) includes reacting a compound of formula (II) with a chalcogenide salt in presence of a proton source. n nY is O, S, Se, Te or Po. R 1 is hydrogen, deuterium, an aliphatic, heteroaromatic, or aromatic group, or a precursor of a leaving group Z whose conjugate acid (HZ) has pK a less than 30. R 2 is hydrogen, deuterium, or an aliphatic, heteroaromatic, or aromatic group. R 1 and R 2 may be the same or different, and may joint together to form a saturated or unsaturated, heteroalicyclic or alicyclic ring. R 3 is, for example, alkyl, aryl, heteroaryl, organosilyl, organotin, or organogermyl. R 3 ′ is the same as R 3 or is hydrogen. X is a precursor of a leaving group X whose conjugate acid (HX) has a pK a of less than 30.
专利号:US-4340762-A 优先权日:1980-12-15 标 题 :Gas phase synthesis of bis(trifluoromethyl) disulfide 发明人:ANELLO LOUIS G; SWEENEY RICHARD F 权利人:ALLIED CORP 摘要:A method of preparing bis(trifluoromethyl) disulfide, which comprises contacting, in the gaseous state, 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane with activated carbon catalyst at elevated temperature is disclosed.
[参考文献]: C R Warner, Et Al. Determination Of Free And Reversibly Bound Sulphite In Foods By Reverse-Phase, Ion-Pairing High-Performance Liquid Chromatography. Food Addit Contam. 1990 Sep-Oct;7(5):575-81. [参考文献]: R Aris, Et Al. Acid Fog-Induced Bronchoconstriction. The Role Of Hydroxymethanesulfonic Acid. Am Rev Respir Dis. 1990 Mar;141(3):546-51. [参考文献]: Roya R R Sardari, Et Al. Improved Production Of 3-Hydroxypropionaldehyde By Complex Formation With Bisulfite During Biotransformation Of Glycerol. Biotechnol Bioeng. 2013 Apr;110(4):1243-8. [参考文献]: Stephen Wai Cheung Chung, Et Al. Determination Of Free And Reversibly-Bound Sulfite In Selected Foods By High-Performance Liquid Chromatography With Fluorometric Detection. J Aoac Int. 2008 Jan-Feb;91(1):98-102. [参考文献]: Yuegang Zuo, Et Al. Light-Induced Formation Of Hydroxyl Radicals In Fog Waters Determined By An Authentic Fog Constituent, Hydroxymethanesulfonate. Chemosphere. 2003 Apr;51(3):175-9.
合成参考文献
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