CAS: 73936-91-1; 2-(2H-Benzotriazol-2-yl)-6-(1-Methyl-1-Phenylethyl)-4-(1,1,3,3-Tetramethylbutyl)Phenol

该化合物是一种有机化合物,主要用作各种材料包括塑料和涂层中的紫外线稳定剂;该化合物具有复杂的结构,包括一种以其有效的紫外线吸附特性而闻名的苯三色混合物,因此对保护材料免受光降解很有价值;四甲基丁基化合物等散装分体的存在增强了其在不同环境中的溶性与稳定性;此外,该化合物的热稳定性和耐沥滤功能对于长期保持其保护性至关重要,其应用遍及各个行业,特别是在汽车,建筑和消费品等需要紫外线保护的配方中.

结构式图片

欧盟法规

C&L通报

上下游产品

Cyasorb UV 5411 isopropenylbenzene 1,2-diamino-benzene 2-cumyl-4-(1,1,3,3-tetramethylbutyl)-phenol 2-[2-Hydroxy-3-(4-chlorosulfonyl-α-cumyl)-5-tert-°Ctylphenyl]-2H-benzotriazole

合成工艺路线路线简述

  • 合成目标产物 Uv Absorber-928 主要起始原料 Uv-329 And 2-Phenyl-1-Propene
  • (文献来源)合成步骤主要原料 Uv-329 和 2-Phenyl-1-Propene
邻枯基叔辛基苯酚置于吡啶,Oxone,Ammonium Hydroxide,2-碘苯磺酸钠,硼酸三乙酯,盐酸羟胺,四丁基硫酸氢铵,Potassium Carbonate,Copper(II) Sulfate,Sodium Sulfate体系中,用 四氢呋喃,乙醇,水,乙酸乙酯,异丙醇 作为反应溶剂,化学反应 27.0H,反应生成 紫外线吸收剂-928
参考文献: Novel Procedure For The Formation Of 2H-Benzotriazole Bodies And Congeners[fr] Nouvelle Procédure Pour La Formation De Corps 2H-Benzotriazole Et De Congénères
标题: Novel Procedure For The Formation Of 2H-Benzotriazole Bodies And Congeners[fr] Nouvelle Procédure Pour La Formation De Corps 2H-Benzotriazole Et De Congénères
摘要:本发明涉及一种制备2H-苯并三唑化合物及同系物的方法,新颖的2H-苯并三唑化合物及同系物,以及它们在涂料和大块塑料中作为紫外线吸收剂的用途.

海关参考信息

专利信息


专利号:US-2009318592-A1
优先权日:2005-10-11
标 题 :Process for the Synthesis of Amine Ethers
发明人:FREY MARKUS; BROENNIMANN VALERIE
权利人:CIBA GEIGY CORP
摘要:The present invention relates to novel processes for the preparation of a sterically hindered amine ether by reacting a corresponding sterically hindered amine oxide with a ketone or an aldehyde with at least one reactive H in the presence of a peroxydisulphate. Products obtained by this process may be hydrogenated. The compounds made by these processes are particularly effective in the stabilization of polymer compositions against harmful effects of light, oxygen and/or heat and as flame-retardants for polymers.

专利号:US-2007191516-A1
优先权日:2004-03-15
标题 :Process for the synthesis of amine ethers
发明人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
权利人:FREY MARKUS; RAST VALERIE; BRAIG ADALBERT; KRAMER ANDREAS
摘要:A process for the preparation of a sterically hindered amine ether which comprises reacting a corresponding sterically hindered aminoxide with a C 5 -C 18 alk-1-ene in the presence of an organic hydroperoxide and optionally hydrogenating the resulting product as well as the product mixtures obtained therewith and their use as stabilizers and flame retardants.

专利号:US-7402675-B2
优先权日:2000-05-26
标题 :Process for the synthesis of amine ethers from secondary amino oxides
发明人:HAFNER ANDREAS; KIRNER HANS JUERG; SCHWARZENBACH FRANZ; VAN DER SCHAAF PAUL ADRIAAN; NESVADBA PETER
权利人:CIBA SC HOLDING AG
摘要:An amine ether of formula A n nwherein a is 1 or 2; and when a is 1, E is E′; when a is 2, E is L;n E′ is C 1 -C 36 alkyl; C 3 -C 18 alkenyl; C 2 -C 18 alkinyl; C 5 -C 18 cycloalkyl; C 5 -C 18 cycloalkenyl; a radical of a saturated or unsaturated aliphatic bicyclic or tricyclic hydrocarbon of 7 to 12 carbon atoms; C 2 -C 7 alkyl or C 3 -C 7 alkenyl substituted by halogen; C 7 -C 15 aralkyl or C 7 -C 15 aralkyl substituted by C 1 -C 4 alkyl or phenyl; or E′ is a radical of formula (VII) as explained in claim 1; T′ is tertiary C 4 -C 18 alkyl or phenyl, each of which are unsubstituted or substituted by halogen, OH, COOR 21 or C(O)—R 22 ; or T′ is C 5 -C 12 cycloalkyl; C 5 -C 12 cycloalkyl which is interrupted by at least one O or —NR 18 —; a polycyclic alkyl radical having 7-18 carbon atoms, or the same radical which is interrupted by at least one O or —NR 18 —; or T′ is —C(G 1 )(G 2 )-T″; or C 1 -C 18 alkyl or C 5 -C 12 cycloalkyl substituted by n n n n n n n n n n n n T″ is hydrogen, halogen, NO 2 , cyano, or is a monovalent organic radical comprising 1-50 carbon atoms; n or T″ and T′ together form a divalent organic linking group completing, together with the hindered amine nitrogen atom and the quaternary carbon atom substituted by G 1 and G 2 , an optionally substituted five- or six-membered ring structure; and all other residues are as defined in claim 1, n are obtained in good yield from the corresponding N-oxyl hindered amine precursor by reaction with a hydrocarbon E 1 -H or H-L-H in the presence of an organic hydroperoxide and a catalytic amount of copper or a copper compound. n n n n n The products of present process find utility as polymerization regulators and/or light stabilizers for organic material.

专利号:US-6417363-B1
优先权日:1997-12-04
标题 :Heterocyclyl ligand containing ruthenium and osmium catalysts
发明人:VAN DER SCHAAF PAUL ADRIAAN; MUEHLEBACH ANDREAS; HAFNER ANDREAS; KOLLY ROMAN
权利人:CIBA SC HOLDING AG
摘要:Penta- and hexa-coordinated, bridged ruthenium and osmium catalysts of the formulawherein Me is ruthenium or osmium; L1 and L2 are neutral ligands having electron donor properties;X is an anionic ligand; Y is oxygen or sulphur; A is a direct bond, C1-C4alkylene or C2-C4alkylidene;Z is a direct bond, oxygen, sulphur or the groupswherein R1 and R2 are hydrogen or hydrocarbon radicals; their preparation and their us in the synthesis of polymers, in the ring-closure metathesis of diolefins, in the cross metathesis of olefins and in the isomerisation of olefins are disclosed.

专利号:US-6077805-A
优先权日:1997-03-06
标题:Hexacoordinated ruthenium or osmium carbene catalysts
发明人:VAN DER SCHAAF PAUL ADRIAAN; HAFNER ANDREAS; MUEHLEBACH ANDREAS
权利人:CIBA SC HOLDING AG
摘要:Hexacoordinated ruthenium and osmium catalysts of the formulae in which M and M' independently of one another are ruthenium or osmium; X, X', Y and Y' independently of one another are anionic ligands, or X and Y and X' and Y' in each case together are bis-anionic ligands L1 and L1' independently of one another are tertiary phosphine; L2 and L3 independently of one another are a monodentate ligand, or L2 and L3 together are bidentate, neutral electron donor ligands; L4 is tetradentate, neutral electron donor ligand; L5 is a bidentate, neutral electron donor ligand; and T and T' indepedently of one another are H or organic substituents, are useful for the synthesis of custom-tailored polymers and for the ring-closing metathesis of olefins.

专利号:US-2005043552-A1
优先权日:2000-05-26
标 题:Process for the synthesis of amine ethers from secondary amino oxides
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