CAS: 655246-35-8; (2R,3R,4S,5S,6R)-2-(4-Nitrophenoxy)-6-((Trityloxy)Methyl)Tetrahydro-2H-Pyran-3,4,5-Triol

英文名称(2R,3R,4S,5S,6R)-2-(4-Nitrophenoxy)-6-((Trityloxy)Methyl)Tetrahydro-2H-Pyran-3,4,5-Triol
中文名称(2R,3R,4S,5S,6R)-2-(4-硝基苯氧基)-6-((三苯甲氧基)甲基)四氢-2H-吡喃-3,4,5-三醇
IUPAC名称(2R,3R,4S,5S,6R)-2-(4-nitrophenoxy)-6-((trityloxy)methyl)tetrahydro-2H-pyran-3,4,5-triol
其它别名4-硝基苯基-6-O-三苯甲基-Alpha-D-吡喃葡萄糖苷; P-Nitrophenyl 6-O-Trityl-α-D-Glucopyranoside
CAS编号655246-35-8
MFCD编号:MFCD07369612
分子式:C31H29NO8分子量:543.57
产品CID: 2533240
产品分类有机原料→分子砌块→手性化合物→手性砌块

相似结构搜索
InChIKey: HUYKQPASBOHHIN-RLXMVLCYSA-N
InChI=1S/C31H29NO8/c33-27-26(40-30(29(35)28(27)34)39-25-18-16-24(17-19-25)32(36)37)20-38-31(21-10-4-1-5-11-21,22-12-6-2-7-13-22)23-14-8-3-9-15-23/h1-19,26-30,33-35H,20H2/
计算化学: 氢键受体数8.0氢键供体数3可旋转键数9

相似化合物

35599-02-1 3767-28-0 2492-87-7

MSDS等安全信息

上下游产品

trityl chloride 4-nitrophenyl-α-D-glucopyranoside 4-nitrophenyl 2,3,4-tri-O-benzoyl-6-O-[2',3',4',6'-tetra-O-benzoyl-5'-deoxy-5'-thio-D-glucopyranosyl]-α-D-glucopyranoside

合成工艺路线路线简述

合成目标产物 4-Nitrophenyl6-O-Trityl-A-D-Glucopyranoside 主要起始原料 Triphenylmethyl Chloride And 4-Nitrophenyl-Alpha-D-Glucopyranoside
(文献来源)合成步骤主要原料 Triphenylmethyl Chloride 和 4-Nitrophenyl-Alpha-D-Glucopyranoside

📜三苯基氯甲烷,对硝基苯-α-D-葡萄糖吡喃苷置于吡啶体系中,化学反应生成对硝基苯基 6-O-三苯甲基-Alpha-D-吡喃葡萄糖苷
参考文献:Synthetic Studies On Oligosaccharides Composed Of 5-Thioglucopyranose Units
标题:Synthetic Studies On Oligosaccharides Composed Of 5-Thioglucopyranose Units
摘要:Glycosylation Reactions Of 5-Thioglucopyranosyl Trichloroacetimidates Bearing Ethereal Protective Groups At The 2-O-Position 14-15,And 37 Proceed Smoothly To Give Alpha-Glycosides Stereoselectively By Using A Catalytic Amount Of Silyl Triflate. This Methodology Allowed Us To Achieve Syntheses Of Sulfur-Substituted Isomaltotetraoside 2 And Maltotetraoside 3. These Studies Also Revealed That Benzoyl-Protected 5-Thioglucopyranosyl Trichloroacetimidate 12 Underwent P-Selective Glycosylation With C6-Oh Glucopyranosyl Acceptors Upon Activation By Bf3Oet2. This Was Applied For Preparation Of Sulfur-Substituted Gentiobiosides 1 And 46. (C) 2005 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Bmc.2005.05.028