CAS: 33089-74-6; N'-(2,4-Dimethylphenyl)-N-Methylformamidine
该化合物是一种属于甲胺胺类的化学化合物,其特点是替代芳香和甲基基胺功能组,该化合物对合成有机化学具有兴趣,因为它作为包括农用化学品和药品在内的更复杂的分子的准备的中间体具有潜力,其结构由2,4-二甲基苯基组成,可具有为选择性转变而定制的稳定性和再活动性.N-甲基甲基甲基苯基胺协会的存在,可提高其在核生殖添加或凝聚反应方面的效用.研究人员认为,该化合物具有明确的纯度和受控合成应用的一贯性能.
- 英文名称N'-(2,4-Dimethylphenyl)-N-Methylformamidine
- 中文名称单甲脒
- IUPAC名称(E)-N-(2,4-dimethylphenyl)-N'-methylformimidamide
- 其它别名N-(2,4-Dimethylphenyl)-N'-methylmetha-nimidamide; N-(2,4-Dimethylphenyl)-N'-methylformamidine
- CAS编号33089-74-6
- MFCD编号:MFCD00225755
- EINECS号:861-087-6
- FDA UNII编号:CTZ715OQFA
- 分子式:C10H14N2分子量:162.23
- 产品CID: 1324408
- 产品分类化学农药原药 → 杀虫剂 → 杀螨剂
- 相似结构搜索
- 产品信息参考
;; - InChIKey: JIIOLEGNERQDIP-UHFFFAOYSA-N
- 1S/C10H14N2/c1-8-4-5-10(9(2)6-8)12-7-11-3/h4-7H,1-3H3,(H,11,12)
- 计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数2.0
物理性质
MSDS等安全信息
- GHS符号GHS07
- 危险类别急性毒性 类别4(吸入)
急性毒性 类别4(经皮)
急性毒性 类别4(经口)
特定目标器官毒性 - 单次接触 类别3
皮肤腐蚀/刺激 类别2
水生慢性毒性 类别3
严重眼刺激 类别2A - 警示词Warning
- 危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H412 |对水生生物有害并具有长期持续影响.
H319 |造成严重眼刺激. - 防范说明P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P-P261-P271-P304+P340-P312-P273-P501-P264-P270-P301+P312-P330-P501-P280-P302+P352-P312-P322-P363-P501
- UN编号UN 2811 6.1 / PGIII
- WGK Germany3
欧盟法规
C&L通报上下游产品
CAS号59263-66-0 1,1'-Thiobis[(m... | CAS号55311-62-1 N1-(p-Chlorophe...合成工艺路线路线简述
海关参考信息
- 2902300000-甲苯
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-10906880-B2
优先权日:2016-01-26
标题:Kind of isothiazole oxime ether-containing strobilurin derivatives and its preparation methods and application
发明人：FAN ZHIJIN; CHEN LAI; GUO XIAOFENG; ZHU YUJIE; QIAN XIAOLIN; MA LIUYONG; ZHANG NAILOU; WANG HAIXIA; ZHANG ZHIMING; XU JINGHUA; SONG YINQI
权利人:UNIV NANKAI
摘要:The present invention is that provided a synthesis method of a series of isothiazole oxime ether containing strobilurin derivatives IV. The present invention relates to 3,4-dichloroisothiazolyl oxime ether strobilurin derivatives, and their chemical structural formula is as shown by IV. n n n n n n n n n n The invention discloses the structural formula of the above compound, the synthesis method and the use as an insecticide, a fungicide, an anti-plant virus agent, and an agriculturally acceptable auxiliary or synergist and a commercial insecticide. The use of a fungicide, an anti-plant virus agent and an acaricide in combination for controlling agricultural, forestry, horticultural plant pests, diseases, virus diseases and preparation methods.
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主要参考文献
1: Moyano P, Ruiz M, García JM, Frejo MT, Anadon Baselga MJ, Lobo M, García J, Del Pino J. Oxidative stress and cell death induction by amitraz and its metabolite BTS-27271 mediated through cytochrome P450 and NRF2 pathway alteration in primary hippocampal cell. Food Chem Toxicol. 2019 Jul;129:87-96. doi: 10.1016/j.fct.2019.04.042. Epub 2019 Apr 25.
65:40-45. doi: 10.1016/j.etap.2018.11.005. Epub 2018 Nov 23.
63:47-53. doi: 10.1016/j.ibmb.2015.04.008. Epub 2015 May 6. 93(2):380-8. 28(7):553-62. doi: 10.1093/jat/28.7.553. 65(1):22-7. doi: 10.1007/s0012800089. 48(11):1461-9. doi: 10.1016/s0026-0495(99)90160-9. 18(3):210-5. doi: 10.1111/j.1365-2885.1995.tb00580.x. 271(3):1240-5. 128(1):45-9. doi: 10.1006/taap.1994.1178. 99(1-2):169-72. doi: 10.1016/0742-8413(91)90095-b. 83(6):2181-6. doi: 10.1093/jee/83.6.2181. 27(1):71-80. doi: 10.1016/0300-483x(83)90076-8. 16(5 Pt B):547-55. doi: 10.1080/03601238109372278. 28(2):215-28.
合成参考文献
参考文献:10.1016/s0022-3565(25)23983-0
摘要:Chen TH, Hsu WH. Inhibition of insulin release by a formamidine pesticide amitraz and its metabolites in a rat beta-cell line: an action mediated by alpha-2 adrenoceptors, a GTP-binding protein and a decrease in cyclic AMP. The Journal of Pharmacology and Experimental Therapeutics. 1994 Dec;271(3):1240–5. doi: 10.1016/s0022-3565(25)23983-0.
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