专利号:US-2022220061-A1 优先权日:2019-05-09 标 题:Process for the synthesis of the ionic liquid tetraoctylammonium di(2-ethylhexyl)-oxamate (il-5), product obtained and its use in selective metal extraction 发明人:ARRIEGAS ESTEVÃO CORREIA LEAL JOÃO PAULO; DA CUNHA OLIVEIRA FIGUEIRA CARRETAS JOSÉ MANUEL; MARIA CRUZ ADELAIDE; DE JESUS MARIA LEONOR MARIA; RAMOS BATISTA MONTEIRO BERNARDO 权利人:INST SUPERIOR TECNICO 摘要:a) The present invention falls within the area of the synthesis of ionic liquids, namely it concerns a process of synthesis of the ionic liquid tetraoctylammonium di(2-ethylhexyl)-oxamate (IL-5) with a high degree of purity and its use in the extraction and selective separation of metals, namely lanthanides. Thus, it is the object of the present invention, a process for the synthesis of a pure ionic liquid using in its constitution only the elements carbon, hydrogen, oxygen and nitrogen (CHON), assuming itself as a “greenâ€? alternative in the recovery of metals, thus reducing the environmental impact in the way they are recovered, as well as the guarantee of a more efficient extraction of these metals.
专利号:WO-2020226521-A1 优先权日:2019-05-09 标题:Process for the synthesis of the ionic liquid tetraoctylammonium dioctyl-diglycolamate (il-4), product obtained and its use in metal remediation 发明人:ARRIEGAS ESTEVÃO CORREIA LEAL JOÃO PAULO; DA CUNHA OLIVEIRA FIGUEIRA CARRETAS JOSÉ MANUEL; MARIA CRUZ ADELAIDE; DE JESUS MARIA LEONOR MARIA; RAMOS BATISTA MONTEIRO BERNARDO 权利人:INST SUPERIOR TECNICO 摘要:The present invention falls within the area of the synthesis of ionic liquids, namely it concerns a process of synthesis of the ionic liquid tetraoctylammonium dioctyl-diglycolamate (IL-4) with a high degree of purity and its use in an environmental remediation process of lanthanides and actinides. In addition, it is also an object of the present invention to obtain the ionic liquid tetraoctylammonium dioctyl-diglycolamate (IL-4) with a high degree of purity that allows the separation and sequestration of metals with a high efficiency.
专利号:WO-2023152730-A1 优先权日:2022-02-14 标题 :Amine-borane adducts in the synthesis of polyester and its copolymers using cyclic esters and compositions thereof 发明人:FENG XIAOSHUANG; LIU JINGJING; GNANOU YVES 权利人:UNIV KING ABDULLAH SCI & TECH 摘要:Embodiments of the present disclosure provide for the process of synthesis of polyester and its copolymers through (co)polymerization of cyclic esters and with other oxygenated monomers using amine-borane adduct. Embodiments of the present disclosure further describe the controlled anionic ring-opening polymerization of the cyclic compounds. Embodiments of the present disclosure also describe the polymerization of cyclic compounds using the synergistic effect of amines and thioureas. Embodiments of the present disclosure also describe compositions of polymers formed by the said process.
专利号:US-2024009660-A1 优先权日:2022-07-05 标题 :Methods for synthesis of hierarchically ordered crystalline microporous materials with long-range mesoporous order 发明人:PARSAPUR RAJESH KUMAR; HODGKINS ROBERT PETER; KOSEOGLU OMER REFA; HUANG KUO-WEI; SEDJERARI ANISSA BENDJERIOU 权利人:SAUDI ARABIAN OIL CO; UNIV KING ABDULLAH SCI & TECH 摘要:Methods for synthesis of hierarchically ordered zeolites and zeolite-type materials are provided. Synthesized hierarchically ordered zeolites and zeolite-type materials formed according to the methods herein possess a high-degree of well-defined long-range mesoporous ordering. The methods include base-mediated reassembly, by dissolution of the parent material to the level of oligomeric structural building units of the parent material, and minimizing or avoiding amorphization/structural collapse. The dissolution and self-assembly is comprehensively controlled to produce hierarchically ordered zeolites and zeolite-type materials according to the methods herein.
专利号:US-2024010662-A1 优先权日:2022-07-05 标题 :Methods for synthesis of hierarchically ordered crystalline microporous materials with long-range mesoporous order 发明人:PARSAPUR RAJESH KUMAR; HODGKINS ROBERT P; KOSEOGLU OMER REFA; HUANG KUO-WEI; SEDJERARI ANISSA BENDJERIOU 权利人:SAUDI ARABIAN OIL CO; UNIV KING ABDULLAH SCI & TECH 摘要:Methods for synthesis of hierarchically ordered zeolites and zeolite-type materials are provided. Synthesized hierarchically ordered zeolites and zeolite-type materials formed according to the methods herein possess a high-degree of well-defined long-range mesoporous ordering. The methods include base-mediated reassembly, by dissolution of the parent material to the level of oligomeric structural building units of the parent material, and minimizing or avoiding amorphization/structural collapse. The dissolution and self-assembly is comprehensively controlled to produce hierarchically ordered zeolites and zeolite-type materials according to the methods herein.
专利号:US-2009253746-A1 优先权日:2005-11-14 标题 :Synthesis and Preparations of Intermediates and New Polymorphs Thereof Useful For The Preparation Of Donepezil Hydrochlcoride 发明人:SOLDEVILLA MADRID NURIA 权利人:SOLDEVILLA MADRID NURIA 摘要:The invention relates to an improved process for preparing 2-(1-benzylpiperidin-4-ylmethyliden)-5,6-dimethoxyin-dan- 1 -one (a key intermediate in the synthesis of donepezil hydrochloride), crystalline polymorph forms of this key intermediate and their use thereof for producing donepezil hydrochloride. In particular, the invention provides an improved method for producing the intermediate 2-(1-benzylpiperidin-4-ylmethyliden)-5,6-dimethoxyindan-1-one. The process includes reacting 5,6-dimethoxyin-dan- 1 -one with 1-benzylpiperidine-4-carbaldehyde using potassium hydroxide in an aqueous solvent. The aqueous solvent can be a mixture of an organic solvent and water Where the organic solvent is not miscible with water, the reaction may be performed in the presence of a phase transfer catalyst.
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