专利号:US-6924385-B2 优先权日:2002-11-18 标 题:Method for synthesis of aliphatic isocyanates from aromatic isocyanates 发明人:LETTMANN CHRISTIAN; KOHLSTRUK STEPHAN; STOCHNIOL GUIDO; SPYROU EMMANOUIL 权利人:DEGUSSA 摘要:The invention relates to a method for synthesis of aliphatic isocyanates from aromatic isocyanates in substantially 3 stages. In particular, the invention relates to a method for synthesis of bis{4-isocyanatocyclohexyl}methane (H 12 MDI) from bis{4-isocyanatophenyl}methane (MDI). More especially, the invention relates to a method for synthesis of H 12 MDI with a trans-trans isomer content of <30%, preferably of <20%, particularly preferably of 5 to 15%.
专利号:US-9126196-B2 优先权日:2009-05-26 标题 :Composition including dialkyl tin oxide and use thereof as a transesterification catalyst for the synthesis of (meth) acrylic esters 发明人:PAUL JEAN-MICHEL; TONNELIER BORIS; AUGUSTIN FRANCIS 权利人:PAUL JEAN-MICHEL; TONNELIER BORIS; AUGUSTIN FRANCIS; ARKEMA FRANCE 摘要:The present invention relates to a composition including a dialkyl tin oxide, such as DBTO, which can be used as a transesterification catalyst for the synthesis of (meth)acrylic esters. The invention also relates to a method for the synthesis of (meth)acrylic esters by transesterification in the presence of said composition.
专利号:US-7141702-B2 优先权日:2004-03-26 标 题 :Process for the synthesis of α-substituted acroleins 发明人:DESHPANDE RAJ M; DIWAKAR MAKARAND M; CHAUDHARI RAGHUNATH V 权利人:COUNCIL SCIENT IND RES 摘要:The present invention provides an improved process for the synthesis of α-substituted acroleins from olefins by a tandem hydroformylation and Mannich reaction sequence in the presence of syngas and formaldehyde, wherein the two catalysts are segregated into two different phases thereby preventing deactivation of the catalysts by each other, and yielding a highly selective and active catalyst.
专利号:US-5248815-A 优先权日:1991-12-27 标 题 :Stereo-selective synthesis of 2-aryl-propionic acids of high optical purity by using chiral oxazolines 发明人:PARADIES HENRICH H 权利人:PARADIES HENRICH H 摘要:The present invention relates to a stereospecific chemical synthesis of optically pure enantiomers of 2-aryl-alkanoic acids, especially those of the biologically active (S)-aryl-propionic acids, in good chemical yields, useful for preparing large quantities thereof, and having a high optical purity.
专利号:WO-2005063668-A1 优先权日:2003-12-31 标题 :Process for synthesis of alpha-substituted acroleins 发明人:DESHPANDE RAJ MADHUKAR; DIWAKAR MAKARAND MADHUKAR; CHAUDHARI RAGHUNATH VITTHAL 权利人:COUNCIL SCIENT IND RES 摘要:The present invention provides an improved process for the synthesis of α-substituted acroleins from olefins by a tandem hydroformylation and Mannich reaction sequence in the presence of syngas and formaldehyde, wherein the two catalysts are segregated into two different phases thereby preventing deactivation of the catalysts by each other, and yielding a highly selective and active catalyst.
专利号:US-5097089-A 优先权日:1987-08-29 标 题 :Synthesis of glycerol from formaldehyde 发明人:GRACEY BENJAMIN P; HUDSON BARRY; WILLIAMS PETER S 权利人:BP CHEM INT LTD 摘要:This invention relates to a process for synthesis of glycerol from formaldehyde, wherein formaldehyde under substantially anhydrous condition is self-condensed in a catalytic step is dihydroxyacetone which is separated from the self-condensation catalyst and hydrogenated catalytically to glycerol. n The feature of the invention is to have less than 0.4% w/w of water in the self-condensation reaction mixture thereby improving the process to produce glycerol in commercially viable rates and yields.
参考文献:10.1007/s10886-011-9995-3 摘要:Andersson MN, Binyameen M, Sadek MM, Schlyter F. Attraction modulated by spacing of pheromone components and anti-attractants in a bark beetle and a moth. J Chem Ecol. 2011 Aug;37(8):899–911. doi: 10.1007/s10886-011-9995-3.