CAS: 15554-47-9; Tris(Acetylacetonato)Yttrium

该化合物是一个协调化合物,其特点是其圆形离子,有2,2,4个圆形的离子.该化合物一般是黄色至橙色晶状固体,可溶于乙醇和丙酮等有机溶剂,因其稳定性而闻名,并经常用作合成含有胚胎的材料,包括陶瓷和薄薄膜的前体.该复合体的子离子有6个协调数,形成扭曲的八面形几何,因为乙酰氟酸盐的诱导性质.Ytttrium-2,4-相聚物也用于多种用途,包括催化,发光材料和作为磷的涂料.其特性使其在材料科学和纳米技术领域具有价值,有助于高级功能材料的开发.在处理该化合物时,应注意安全防范措施,因为许多金属-有机化合物.

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    专利号:US-2024075466-A1
    优先权日:2021-04-09
    标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites
    发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE
    权利人:UMICORE AG & CO KG
    摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.

    专利号:US-5502126-A
    优先权日:1993-06-17
    标 题 :Process for the synthesis of isoprene butadiene rubber
    发明人:BELL ANTHONY J; MATRANA BARRY A; HALASA ADEL F
    权利人:GOODYEAR TIRE & RUBBER
    摘要:The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component; (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component; and (3) adding a compound which contains at least one labile halogen atom to the Group III-B metal containing catalyst component.

    专利号:US-7220398-B2
    优先权日:2002-02-19
    标题:Mixed-metal oxide particles by liquid feed flame spray pyrolysis of oxide precursors in oxygenated solvents
    发明人:SUTORIK ANTHONY C; LAINE RICHARD M; MARCHAL JULIEN; JOHNS TYRONE; HINKLIN THOMAS
    权利人:TAL MATERIALS & THE REGENTS OF
    摘要:Liquid feed flame spray pyrolysis of solutions of a metal oxide precursor which is an alkoxide or C 1-6 carboxylate and at least one second metal oxide precursor and/or second metal compound dissolved in oxygenated solvent by combustion with oxygen lead to the formation of sub-micron mixed-metal oxide powders not accessible by other processes or by the pyrolysis of metal chlorides or nitrates. The powders have numerous uses in advanced materials applications including particulate solid state lasers, advanced ceramic materials, and as catalysts in organic synthesis and automobile exhaust systems.

    专利号:US-2003125487-A1
    优先权日:2001-12-31
    标题 :Group III-B metal catalyst system
    发明人:HSU WEN-LIANG; HALASA ADEL FARHAN; JASIUNAS CHAD AARON
    权利人:HSU WEN-LIANG; HALASA ADEL FARHAN; JASIUNAS CHAD AARON
    摘要:The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system that is comprised of (I) a compound which contains at least one labile halogen atom and (II) a Group III-B metal containing catalyst component which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component, and (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component.

    专利号:US-7959885-B2
    优先权日:2008-02-15
    标 题:Nanoparticle synthesis by solvothermal process
    发明人:LI SHENG; FROEHLICH JESSE DAN; NAKAMURA TOSHITAKA; MOCHIZUKI AMANE
    权利人:NITTO DENKO CORP
    摘要:A solvothermal process for making inorganic nanoparticles is described. Inorganic nanoparticles can be produced by forming a suspension or solution comprising at least one group II-IV and lanthanide metal inorganic salt in a first medium, disposing the suspension or solution in a sealed chamber having an interior pressure, elevating the interior pressure of the sealed chamber to an initial interior pressure prior to the heating, heating the suspension or solution to a peak temperature higher than the normal boiling point of the first medium, optionally adding a second medium to the suspension or solution after the heating.

    专利号:US-7595275-B2
    优先权日:2006-08-15
    标 题:Catalyst compositions and their synthesis
    发明人:XU TENG
    权利人:EXXONMOBIL CHEM PATENTS INC
    摘要:The present invention relates to molecular sieve compositions and a process to synthesize such compositions. More particularly, this invention relates to a catalyst composition with metal oxide deposited on the exterior surface of the molecular sieve particles. The metal oxide can be deposited by contacting the molecular sieve particles with a solution of a metal-containing salt and a solvent, the metal-containing salt solution having an anion size larger than the pore size of the molecular sieve particles. The molecular sieve particles can then be dried and then treated under conditions sufficient to form a metal oxide, whereby at least a portion of the metal-containing salt can be converted to metal oxide.

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