CAS: 1271-51-8; Vinylferrocene

该化合物是有机金属化合物,其特点是存在一种铁单体,由两环环开甲醚环之间夹杂的中央铁原子组成,其基质组附于环开丁二烯环中环环中的一个环上,该产品具有独特的特性,因为它的铁质结构和乙烯功能组是其各种领域(包括材料科学和有机合成)中感兴趣的一个主题.在室内温度下,乙烯一般是一种稳定,橙色至红色的固态,在二氯甲烷和甲苯等有机溶剂中可溶解.该化合物的再活性受到可参与各种化学反应的乙烯组的存在的影响,包括聚合和交叉相联反应.此外,乙烯可作为合成更复杂的有机化合物和材料的前体,展示其在化学应用中的多功能性.该混合物独特的电子特性也使它成为研究电化学和催化学的候选对象.

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CAS号12093-10-6 二茂铁甲醛 | CAS号1779-49-3 甲基三苯基溴化膦 | CAS号1277-49-2 1-二茂铁基乙醇 | CAS号64-18-6 甲酸 | CAS号1271-47-2 二茂铁乙炔 | CAS号19493-09-5 methylidene tri... | CAS号1271-55-2 乙酰基二茂铁 | CAS号102-54-5 二茂铁 | CAS号107-13-1 丙烯腈 | CAS号1271-47-2 二茂铁乙炔

合成工艺路线路线简述

    乙酰基二茂铁置于hc(oc2H5)3体系中,用 乙醇 用作溶剂,化学反应生成乙烯基二茂铁
    参考文献:Acid-Catalyzed Reaction Of Acetylferrocene With Triethyl Orthoformate
    标题:Acid-Catalyzed Reaction Of Acetylferrocene With Triethyl Orthoformate
    摘要:
    Doi:10.1021/jo00961A014

    海关参考信息

    专利信息


    专利号:WO-2013067646-A1
    优先权日:2011-11-12
    标题:Process for the synthesis of beta-aminocarbonyls
    发明人:BEAUCHEMIN ANDRE MARTIN; CLAVETTE CHRISTIAN; GAN WEI; MARKIEWICZ THOMAS; TODERIAN AMY BEVERLY
    权利人:UNIV OTTAWA
    摘要:The present application provides processes and intermediates useful in the production of β- aminocarbonyl- or β-aminothiocarbonyl-containing compounds. Provided herein is a process for synthesizing β-aminocarbonyl- or β-aminothiocarbonyl-containing compounds from an alkene and a hydrazone. Also provided herein is a process for synthesizing β-aminocarbonyl- or β-aminothiocarbonyl-containing compounds from an alkene and a hydrazine. The present application further provides intermediate aminoisocyanate and iminoisocyanate compounds, and methods for synthesizing the starting hydrazone and hydrazine compounds.

    专利号:US-11840715-B2
    优先权日:2020-06-30
    标题 :Microelectrode array with a switchable hydrophilic surface
    发明人:NGUYEN BICHLIEN; SMITH JAKE
    权利人:MICROSOFT TECHNOLOGY LICENSING LLC
    摘要:A switchable hydrophilic surface is created by attaching electrochemically switchable hydrophilicity polymers to the surface of a microelectrode array. Ferrocene polymers are one example of electrochemically switchable hydrophilicity polymers. Activation of electrodes in the microelectrode array changes the oxidation state of metal ions which switches the polymers between hydrophobic and hydrophilic conformations. Selective activation of electrodes can create patterns of wettability on the microelectrode array that may be varied in real time. The switchable hydrophilic surface may be used to control solid-phase synthesis of polymers. Growing polymers may be selectively extended at locations on the microelectrode array that are hydrophilic. The pattern of hydrophobic and hydrophilic regions can be changed during sequential rounds of synthesis to create a variety of different polymers at different locations on the surface of the microelectrode array.

    专利号:US-8575381-B2
    优先权日:2010-09-17
    标题:Trihydridosilyl-terminated polysilanes and methods of preparation
    发明人:ARKLES BARRY C; PAN YOULIN; LARSON GERALD L
    权利人:ARKLES BARRY C; PAN YOULIN; LARSON GERALD L; GELEST TECHNOLOGIES INC
    摘要:Novel trihydridosilyl-terminated polysilanes and methods for their synthesis, which are applicable to other polysilanes, are provided. The synthetic methods provide for facile preparation of products with minimal handling of pyrophoric intermediates and byproducts. The novel compounds contain at least three silicon-silicon bonds and at least one terminal silicon atom having three hydrogen substituents.

    专利号:WO-9325300-A1
    优先权日:1992-06-05
    标 题:Ultrathin composite membranes
    发明人:MARTIN CHARLES R; LIU CHAO
    权利人:RES CORP TECHNOLOGIES INC; MARTIN CHARLES R; LIU CHAO
    摘要:The present invention relates to a method of forming defect-free ultrathin film composite membranes by the photochemical synthesis of an ultrathin polymer film on the surface of a microporous support membrane. In one particular embodiment, the method entails placing a support membrane on a filter paper which is saturated with a solution of the desired monomer(s). The solution then wicks to the top of the membrane, covering the surface with a thin solution film, where it is subjected to irradiation by ultraviolet (UV) light to initiate the polymerization of the ultrathin polymer film. The rate of polymerization can be enhanced by adding a photoinitiator to the gas phase above the membrane or into solution with the monomer or monomers to induce radical polymerization. The method results in a defect-free ultrathin composite membrane. In addition, to minimize photon penetration depth and confine the polymerization predominantly to the membrane surface, the incident at which the UV light strikes the membrane surface is kept at an acute angle. The ultrathin film composite membranes can be used in a vast number of chemical separation processes, bioreactors and sensors, energy conversion and drug delivery systems.

    专利号:US-10392267-B2
    优先权日:2017-04-18
    标 题 :Azo dye intercalated Fe(II)/Fe(III) layered double hydroxide for water purification
    发明人:ELSAYED Waleed Elsayed Mahmoud; AL-GHAMDI AHMED ABDULLAH SALEM; AL-TURKI YUSUF ABDULAZIZ
    权利人:UNIV KING ABDULAZIZ
    摘要:A nanostructured material having a coral reef morphology of nanoflake walls is described. The nanostructured material comprises a Fe(II)/Fe(III) layered double hydroxide intercalated with an azo dye, and a synthesis method is discussed. The nanostructured material may be used to remove a contaminant from a solution by adsorption. The nanostructured material may be cleaned and reused with high adsorption efficiency.

    专利号:CN-110483561-B
    优先权日:2019-08-24
    标 题:Synthesis method of alkenyl borate compound
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    合成参考文献


    摘要:Li, W.; Liu, X. H.; Feng, X. M., Science of Synthesis Knowledge Updates, (2021) 1, 34.
    摘要:Tang, X., Science of Synthesis Knowledge Updates, (2022) 3, 484.
    摘要:Banerjee, S.; Ilies, L., Science of Synthesis: Base-Metal Catalysis, (2023) 2, 351.
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