专利号:US-2008206890-A1 优先权日:2006-07-31 标题:Bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(i) complexes, methods of synthesis, and uses therof 发明人:BURSTYN JUDITH N; GREEN OMAR; GANDHI BHAVESH A 权利人:WISCONSIN ALUMNI RES FOUND 摘要:The present invention provides homoleptic and heteroleptic copper(I) complexes having sterically demanding ligands, such as the bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(I) complex and related complexes, methods of synthesis of these complexes and uses thereof. These copper(I) complexes are useful for various applications including photovoltaic cells, light-emitting electrochemical cells, and analyte sensor systems.
专利号:US-8168745-B2 优先权日:2007-08-02 标 题:Process for the preparation of poly- and oligothiophenes on an industrial scale 发明人:HENNINGER BJOERN; RAUSCHER FRANK; MLECZKO LESLAW 权利人:HENNINGER BJOERN; RAUSCHER FRANK; MLECZKO LESLAW; BAYER TECHNOLOGY SERVICES GMBH 摘要:Process for industrial scale synthesis of poly- and oligothiophenes, which works in concentrated solution. In this process, a solution which comprises an organometallic thiophene reagent is added to a second solution which comprises a catalyst.
专利号:CA-2692673-A1 优先权日:2007-07-09 标题 :Process for the synthesis of oligo/polythiophenes by a 'one-pot' synthesis route
专利号:US-8716485-B2 优先权日:2010-03-29 标 题:Pyrazole synthesis by coupling of carboxylic acid derivatives and enamines 发明人:NEUMANN JULIA; SURI MAMTA; GLORIUS FRANK 权利人:NEUMANN JULIA; SURI MAMTA; GLORIUS FRANK; WESTFÄLISHE WILHELMS UNIVERSITÄT MÜNSTER 摘要:The invention describes a novel process for synthesizing pyrazoles by means of oxidative conversion of enamines with suitable N-containing carboxylic acid derivatives.
专利号:US-8912342-B2 优先权日:2012-02-06 标题:Pyrazole synthesis by coupling of carboxylic acid derivatives and enamines 发明人:GLORIUS FRANK; SURI MAMTA 权利人:UNIV MUENSTER WILHELMS; Westfälische Wilhelms Universität Münster 摘要:A method of synthesizing Pyrazoles by means of the oxidative conversion of Enamines with suitable N-containing carboxylic acid derivatives in the presence of copper ions and 2-picolinic acid derivatives is provided.
专利号:WO-2013038134-A1 优先权日:2011-09-16 标题 :Synthesis and anticancer activity of ruthenium (11) cis-cis-1,3,5- triaminocyclohexane complexes 发明人:GAMBLE AIMEE JOANNA; LYNAM JASON MARTIN; WALTON PAUL HOWARD 权利人:UNIV YORK; GAMBLE AIMEE JOANNA; LYNAM JASON MARTIN; WALTON PAUL HOWARD 摘要:There is described a complex of formula I: in which, R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are each, hydrogen, alkyl CI to 20 alkenyl CI to 20, aryl, alkyl(ci t0 20)aryl, alkenyl(Ci t0 20>aryl, heteroaryl, etc.; R 7 , R 8 and R 9 are each, hydrogen or alkyl CI to 20; L 1 , L 2 and L 3 , are each a ligand; in free or in salt form.
参考文献:10.1039/b717910c 摘要:Janzen DE, Vanderveer DG, Mehne LF, da Silva Filho DA, Brédas JL, Grant GJ. Cyclometallated Pt(II) and Pd(II) complexes with a trithiacrown ligand. Dalton Trans. 2008 Apr 14;(14):1872–82. doi: 10.1039/b717910c. 参考文献:10.1107/s1600536810046556 摘要:Fernandes JA, Almeida Paz FA, Mota MJP, Braga SS, Santos TM. (2,2′-Bipyridine-κ2N,N′)chlorido(1,4,7-trithiacyclononane-κ3S,S′,S′′)ruthenium(II) nitrate monohydrate. Acta Crystallogr E Struct Rep Online. 2010 Nov 13;66(12):m1575. doi: 10.1107/s1600536810046556. 参考文献:10.1039/b200315p 摘要:Karmazin L, Mazzanti M, Pécaut J. Unique crown thioether complexes of f elements: the crystal structure of U(III) and La(III) complexes of 1,4,7-trithiacyclononane. Chem Commun (Camb). 2002 Mar 21;(6):654–5. doi: 10.1039/b200315p. 参考文献:10.1021/ic0497533 摘要:Sala X, Romero I, Rodríguez M, Llobet A, González G, Martínez M, Benet-Buchholz J. Synthesis, structure, and substitution mechanism of new Ru(II) complexes containing 1,4,7-trithiacyclononane and 1,10-phenanthroline ligands. Inorg Chem. 2004 Aug 23;43(17):5403–9. doi: 10.1021/ic0497533.