CAS: 6573-11-1; 1,4,7-Trithionane

该化合物是一个循环化合物,其独特的结构结构包括三个硫磺原子,这些原子被纳入一个九人环状环状圈中,该化合物属于硫环-环烷类,由于能够形成稳定的化学和材料科学,因此在协调化学和材料科学中具有潜在的应用作用,具有各种金属离子,硫磷原子存在于环状体中,这助长了其独特的化学特性,例如,反应力和参加再毒反应的能力增加.此外,1,4,7-Trityhiacyclanonane的熔点相对较低,可溶于极有机溶剂中,可促进其在各种化学反应中的使用,其结构特性还允许一致性灵活性,可影响其与其他分子的相互作用.

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CAS号106-93-4 1,2-二溴乙烷

合成工艺路线路线简述

    📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于bis(Tetramethylammonium) 3-Thiapentane-1,5-Dithiolate体系中,用 二甲基亚砜 作为反应溶剂,化学反应 48.0H,以60%的收率获得产物1,4,7-三硫环壬烷
    参考文献:übergangsmetallkomplexemit Schwefelliganden:X.取代基-氧化还原-还原化合物vonmolybdän(0)-羰基-Komplexen Mitmehrzähnigen硫醚硫醇-配体1,2-甲基硫代苯并硫醇,1,4,7-三硫杂庚烷,23,8,1,4,7,10-四硫杂蒽1,2,2-苯并二硫醇
    标题:übergangsmetallkomplexemit Schwefelliganden:X.取代基-氧化还原-还原化合物vonmolybdän(0)-羰基-Komplexen Mitmehrzähnigen硫醚硫醇-配体1,2-甲基硫代苯并硫醇,1,4,7-三硫杂庚烷,23,8,1,4,7,10-四硫杂蒽1,2,2-苯并二硫醇
    摘要:在钼(0)羰基配合物的多齿有机硫的配体,(nme的反应的研究4)2 [沫(co)3(sc 2 ħ 4 Sc 2 H ^ 4 S)的方法,由[沫(co)获得的3(ch 3 Cn)3]和(nme 4)2(sc 2 H 4 Sc 2 H 4 S);随后用1,2-二溴乙烷烷基化得到[mo(co)3 Ttcn](ttcn = 1,4,7-三噻吩烷).从[mo(co)3Ttcn]由(nme 4)2(sc)2 ħ 4 Sc 2 H ^ 4 S)下的起始复合物的再生(nme 4)2 [沫(co)3(sc 2 ħ 4 Sc 2 H ^ 4 S)].ttcn和[mocl 3(thf)3]产生[mocl 3(ttcn)].[mo(co)4(降冰片二烯)]和(nme 4)2(dttd),(dttd 2 = 2,3,8,9-二苯并-1,4,7,10-四硫杂癸烷(−2)),给出(nme 4)2 [μ-Dttd{mo(co)4
    DOI:10.1016/0022-328X(85)88027-X

    海关参考信息

    专利信息


    专利号:US-2008206890-A1
    优先权日:2006-07-31
    标题:Bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(i) complexes, methods of synthesis, and uses therof
    发明人:BURSTYN JUDITH N; GREEN OMAR; GANDHI BHAVESH A
    权利人:WISCONSIN ALUMNI RES FOUND
    摘要:The present invention provides homoleptic and heteroleptic copper(I) complexes having sterically demanding ligands, such as the bis(2,9-di-tert-butyl-1,10-phenanthroline)copper(I) complex and related complexes, methods of synthesis of these complexes and uses thereof. These copper(I) complexes are useful for various applications including photovoltaic cells, light-emitting electrochemical cells, and analyte sensor systems.

    专利号:US-8168745-B2
    优先权日:2007-08-02
    标 题:Process for the preparation of poly- and oligothiophenes on an industrial scale
    发明人:HENNINGER BJOERN; RAUSCHER FRANK; MLECZKO LESLAW
    权利人:HENNINGER BJOERN; RAUSCHER FRANK; MLECZKO LESLAW; BAYER TECHNOLOGY SERVICES GMBH
    摘要:Process for industrial scale synthesis of poly- and oligothiophenes, which works in concentrated solution. In this process, a solution which comprises an organometallic thiophene reagent is added to a second solution which comprises a catalyst.

    专利号:CA-2692673-A1
    优先权日:2007-07-09
    标题 :Process for the synthesis of oligo/polythiophenes by a 'one-pot' synthesis route

    专利号:US-8716485-B2
    优先权日:2010-03-29
    标 题:Pyrazole synthesis by coupling of carboxylic acid derivatives and enamines
    发明人:NEUMANN JULIA; SURI MAMTA; GLORIUS FRANK
    权利人:NEUMANN JULIA; SURI MAMTA; GLORIUS FRANK; WESTFÄLISHE WILHELMS UNIVERSITÄT MÜNSTER
    摘要:The invention describes a novel process for synthesizing pyrazoles by means of oxidative conversion of enamines with suitable N-containing carboxylic acid derivatives.

    专利号:US-8912342-B2
    优先权日:2012-02-06
    标题:Pyrazole synthesis by coupling of carboxylic acid derivatives and enamines
    发明人:GLORIUS FRANK; SURI MAMTA
    权利人:UNIV MUENSTER WILHELMS; Westfälische Wilhelms Universität Münster
    摘要:A method of synthesizing Pyrazoles by means of the oxidative conversion of Enamines with suitable N-containing carboxylic acid derivatives in the presence of copper ions and 2-picolinic acid derivatives is provided.

    专利号:WO-2013038134-A1
    优先权日:2011-09-16
    标题 :Synthesis and anticancer activity of ruthenium (11) cis-cis-1,3,5- triaminocyclohexane complexes
    发明人:GAMBLE AIMEE JOANNA; LYNAM JASON MARTIN; WALTON PAUL HOWARD
    权利人:UNIV YORK; GAMBLE AIMEE JOANNA; LYNAM JASON MARTIN; WALTON PAUL HOWARD
    摘要:There is described a complex of formula I: in which, R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are each, hydrogen, alkyl CI to 20 alkenyl CI to 20, aryl, alkyl(ci t0 20)aryl, alkenyl(Ci t0 20>aryl, heteroaryl, etc.; R 7 , R 8 and R 9 are each, hydrogen or alkyl CI to 20; L 1 , L 2 and L 3 , are each a ligand; in free or in salt form.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1039/b717910c
    摘要:Janzen DE, Vanderveer DG, Mehne LF, da Silva Filho DA, Brédas JL, Grant GJ. Cyclometallated Pt(II) and Pd(II) complexes with a trithiacrown ligand. Dalton Trans. 2008 Apr 14;(14):1872–82. doi: 10.1039/b717910c.
    参考文献:10.1107/s1600536810046556
    摘要:Fernandes JA, Almeida Paz FA, Mota MJP, Braga SS, Santos TM. (2,2′-Bipyridine-κ2N,N′)chlorido(1,4,7-trithiacyclononane-κ3S,S′,S′′)ruthenium(II) nitrate monohydrate. Acta Crystallogr E Struct Rep Online. 2010 Nov 13;66(12):m1575. doi: 10.1107/s1600536810046556.
    参考文献:10.1039/b200315p
    摘要:Karmazin L, Mazzanti M, Pécaut J. Unique crown thioether complexes of f elements: the crystal structure of U(III) and La(III) complexes of 1,4,7-trithiacyclononane. Chem Commun (Camb). 2002 Mar 21;(6):654–5. doi: 10.1039/b200315p.
    参考文献:10.1021/ic0497533
    摘要:Sala X, Romero I, Rodríguez M, Llobet A, González G, Martínez M, Benet-Buchholz J. Synthesis, structure, and substitution mechanism of new Ru(II) complexes containing 1,4,7-trithiacyclononane and 1,10-phenanthroline ligands. Inorg Chem. 2004 Aug 23;43(17):5403–9. doi: 10.1021/ic0497533.
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