CAS: 39807-15-3; Oxadiargyl

该化合物是一种选择性除草剂,主要用于农业,以控制不同作物中某些大叶杂草和草草;它属于硫酸甲酸酯化学类,其功能是抑制脂肪酸合成,这对植物生长至关重要;Oxadiagy通常根据目标杂草和作物类型,在出现前或出现后应用;该物质的特点是其对哺乳动物的毒性相对较低,使其在农业环境中使用更为安全;必须指出,尽管对特定杂草物种有效,但其功效可能受到土壤类型,湿度和温度等环境因素的影响;此外,适当的应用技术对于最大限度地减少杂草人口抗药性发展的风险至关重要;与任何农用化学品一样,遵守安全准则和条例对于确保环境保护和人类健康至关重要.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签ECHA物质欧盟农药活性物质食品接触材料-禁用CMR物质OtherC&L通报REACH预注册废弃物危险特性清单"欧盟管控危险化学品"工作场所安全标识要求ECHA物质化妆品禁用物质清单

上下游产品

3-(2,4-dichloro-5-hydroxyphenyl)-5-(1,1-dimethylethyl)-1,3,4-oxadiazol-2(3H)-one propargyl p-toluenesulfonate

合成工艺路线路线简述

    📜5-叔丁基-3-(2,4-二氯-5-羟基苯基)-1,3,4-恶二唑-2-酮,对甲苯磺酸丙炔酯置于potassium Carbonate体系中,用 甲苯 作为反应溶剂,化学反应 4.0H,以96%的收率获得产物丙炔恶草酮
    参考文献:一种丙炔噁草酮的合成方法
    标题:一种丙炔噁草酮的合成方法
    摘要:本发明公开了一种丙炔噁草酮的合成方法,在非质子有机溶剂中,噁草酮酚在碳酸盐存在下与对甲苯磺酸炔丙基酯反应,经过滤,蒸馏除去溶剂,重结晶得到丙炔噁草酮,产物是一种除草剂.本发明合成方法在常压下进行,不需加入催化剂,不采用易燃,易爆的氯丙炔或溴丙炔原料,产品收率高,纯度高,工艺操作安全,适合工业化采用.

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:US-9644469-B2
    优先权日:2012-07-24
    标题 :Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and VLCFA and lipid synthesis inhibiting herbicides
    发明人:YERKES CARLA N; MANN RICHARD K; SHIRAISHI IKUO; YANAGIYAMA SHINGO; SATCHIVI NORBERT M
    权利人:DOW AGROSCIENCES LLC
    摘要:A synergistic herbicidal composition containing (a) a compound of formula (I): n nor an agriculturally acceptable salt or ester thereof and (b) VLCFA and fatty acid/lipid synthesis inhibiting herbicides, including but not limited to, acetochlor, alachlor, anilofos, benfuresate, cafenstrole, dimethenamid-P, fentrazamide, indanofan, flufenacet, mefenacet, s-metolachlor, molinate, pethoxamid, pretilachlor, prosulfocarb, pyroxasulfone, thenylchlor and thiobencarb, or a salt or ester thereof, provide synergistic weed control of undesirable vegetation in direct-seeded, water-seeded and transplanted rice, cereals, wheat, barley, oats, rye, sorghum, corn or maize, sugarcane, sunflower, oilseed rape, canola, sugar beet, soybean, cotton, pineapple, pastures, grasslands, rangelands, fallowland, turf, tree and vine orchards, aquatics, plantation crops, vegetables, industrial vegetation management (IVM) or rights-of-way (ROW).

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Rees KC, Dou Z, Whitehead DC. Oxadiazon Derivatives Elicit Potent Intracellular Growth Inhibition against Toxoplasma gondii by Disrupting Heme Biosynthesis. ACS Infect Dis. 2022 May 13;8(5):911-917. doi: 10.1021/acsinfecdis.2c00020. Epub 2022 Apr 1.
    2: Budak TB, Ayyıldız MF, Chormey DS, Bakırdere S. Combination of vortex assisted binary solvent microextraction and QuEChERS for the determination of prothiofos, oxadiargyl, and gamma-cyhalothrin in water and pineapple samples by gas chromatography mass spectrometry. Environ Monit Assess. 2020 Apr 8;192(5):273. doi: 10.1007/s10661-020-8209-2. 15(8):1680. doi: 10.3390/ijerph15081680.
    4: Ahmed A, Shamsi A, Bano B. Oxadiargyl induced conformational transition of cystatin isolated from yellow mustard seeds: Biophysical and biochemical approach. Int J Biol Macromol. 2017 May;98:802-809. doi: 10.1016/j.ijbiomac.2017.02.055. Epub 2017 Feb 16.

    合成参考文献


    参考文献:10.1007/978-3-030-23396-9_3
    摘要:Sousa S, Maia ML, Correira-Sá L, Fernandes VC, Delerue-Matos C, Calhau C, Domingues VF. Chemistry and Toxicology Behind Insecticides and Herbicides. 2019 Aug 01. In: Controlled Release of Pesticides for Sustainable Agriculture.
    参考文献:10.1007/698_2021_800
    摘要:Carpio MJ, Rodríguez-Cruz MS, Sánchez-Martín MJ, Marín-Benito JM. Pesticide Fate in Soils Under Different Agricultural Management Practices. 2021. In: The Handbook of Environmental Chemistry.
    参考文献:10.1007/978-3-030-25598-5_2
    摘要:Devendar P, Yang G. Sulfur-Containing Agrochemicals. 2017 Oct 09. In: Topics in Current Chemistry Collections.
    参考文献:10.1007/978-981-16-4955-4_19
    摘要:Javaid MM, Mahmood A, Nadeem MA, Sarwar N, Safdar ME, Ahmad M, Hasanuzzaman M, Ahmad S. Weed Management Strategies in Direct Seeded Rice. 2022. In: Modern Techniques of Rice Crop Production.
    参考文献:10.1007/978-981-16-1197-1_5
    摘要:Mamatha NC, Panyam KR. Agronomic Practices in Fenugreek. 2021. In: Fenugreek.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知