CAS: 3524-62-7; 2-Methoxy-1,2-Diphenylethanone

该化合物是紫外线可保证涂层,墨水和粘合物中广泛使用的光动剂.其主要优势在于其在紫外光下高效的自由激进生产,使丙烯酸和甲基丙烯酸酯树脂能够快速聚合. 该化合物在250-350纳米范围内被大量吸收,适合需要快速治愈的中度紫外线强度的应用. 它与各种树脂系统的兼容性和低挥发性提高了配制稳定性. 此外,本甲醚展示了最低黄化后固化作用,有助于提高成品的光亮度. 妥善处理是因为它具有轻度的特性.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2-methoxy-2-phenylacetonitrile benzoin dimethyl ketal (R)-2-methoxy-2-phenylacetamide methanolbenzil erythro-1,2-Diphenyl-2-methoxyethanol threo-2-methoxy-1,2-diphenylethanol 2-acetoxy-2-phenylacetophenone

合成工艺路线路线简述

    1,2-Diphenyl-2-Methoxyethanol置于盐酸,4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧,氧气,硝酸体系中,用 水,乙腈 用作溶剂,以87%的收率获得安息香甲基醚
    参考文献:木质素中化学选择性无金属有氧醇氧化
    标题:木质素中化学选择性无金属有氧醇氧化
    摘要:已经确定了一种有效的有机催化方法,用于对木质素模型化合物中的仲苄醇进行化学选择性有氧氧化.天然木质素中选择性氧化的扩展也已被证明.最佳催化剂体系由 4-乙酰氨基-Tempo(5 Mol%;Tempo = 2,2,6,6-四甲基哌啶-N-氧基)与 Hno3 和 Hcl(各 10 Mol%)组成.初步研究强调了将该方法与随后的氧化步骤相结合以实现 Cc 键断裂的前景.
    Doi:10.1021/ja401793N

    海关参考信息

    专利信息


    专利号:US-4609707-A
    优先权日:1983-11-10
    标题 :Synthesis of polymers containing integral antibodies
    发明人:NOWINSKI ROBERT C; HOFFMAN ALLAN S
    权利人:GENETIC SYSTEMS CORP
    摘要:A method is disclosed for the de novo synthesis of antibody-containing polymers and the preparation of a class of polymerizable compounds used in the synthesis of such antibody-containing polymers. Antibody-containing polymers formed from monomer/antibody conjugates and nonderivatized polymerizable compounds can be varied in formation of the polymer to provide control of (a) molecular spacing, steric accessibility and the number of antibody molecules that are integrally incorporated into the polymer backbone, and (b) the chemical and physical structure of the polymer itself, thus enabling specific tailoring of antibody-containing polymers for particular end-use application. Also disclosed is a method for the selective removal of a compound from a solution or suspension thereof using monomer/receptor conjugates where the compound has the capacity to bind to the receptor in the conjugate. The bound compound is removed by polymerization - induced separation of the monomer/receptor--compound complex from solution.

    专利号:US-9969823-B1
    优先权日:2011-09-01
    标题 :Synthesis and polymerization of vinyl triazolium ionic liquids
    发明人:LUEBKE DAVID; NULWALA HUNAID; MATYJASZEWSKI KRZYSZTOF; ADZIMA BRIAN
    权利人:US ENERGY; THE US DEPARTMENT OF ENERGY
    摘要:Herein, we describe polymerized ionic liquids, demonstrate the synthesis of polymerized ionic liquids, and demonstrate the polymerization of triazolium monomers. One embodiment shows the polymeriazation of the triazolium monomers with bis(trifluoromethanesulfonyl)imide anions. In another embodiment we show the feasibility of copolymerizing with commodity monomers such as styrene using free radical polymerization techniques.

    专利号:EP-4428168-A1
    优先权日:2023-03-08
    标 题 :Polyurethane/oligomeric urethane synthesis method by radiation
    发明人:AKBULUT HÜSEYIN; ÇEL KBA SENA; ENADA SEHER; U AKLI MÜGE; DEM RBAY DUYGU
    权利人:CHT TURKEY KIMYA SANAYI VE TICARET A S
    摘要:In particular, the invention relates to the synthesis of radiation-curable polyurethane/oligomeric urethane dispersions of anionic and cationic characters, containing neutralization techniques characterized by the selection of counter ions as monomers and/or agents which can be polymers acting as promoters under radiation, to a radiation polyurethane/oligomeric urethane synthesis method that enables the creation of radiation curable binder systems without using cosolvents, surfactants, emulsifiers, defoamers, stabilizers and additives, wherein all components of the radiation-curable binder systems can be polymerized.

    专利号:US-4752638-A
    优先权日:1983-11-10
    标 题:Synthesis and use of polymers containing integral binding-pair members
    发明人:NOWINSKI ROBERT C; HOFFMAN ALLAN S; HOUGHTON RAYMOND L; PRIEST JOHN H; MONJI NOBUO
    权利人:GENETIC SYSTEMS CORP
    摘要:Conjugate monomers, polymers, and methods for the de novo synthesis of the polymers are provided. Conjugate organic monomers contain binding-pair members which upon polymerization become integrally associated with the resultant polymer. Specifically, antigens, antibodies, receptors, and ligands may be bound to organic monomers either directly by chemical reaction or indirectly by chemical spacer arms, and these conjugates may be polymerized or copolymerized with nonderivatized monomers to form polymers containing variable amounts of the binding-pair members. Such conjugate monomers and polymers find a wide variety of uses in binding to their binding-pair-member cognate which include selective removal of complementary binding-pair members from solution as well as in immunoassay procedures and in immunization regimes.

    专利号:US-9867899-B2
    优先权日:2010-05-24
    标题 :Reinforced adhesive complex coacervates and methods of making and using thereof
    发明人:STEWART RUSSELL J
    权利人:UNIV UTAH RES FOUND
    摘要:Described herein is the synthesis of reinforced adhesive complex coacervates and their use thereof. The reinforced adhesive complex coacervates are composed of (a) at least one polycation, (b) at least one polyanion, and (c) a reinforcing component. The adhesive complex coacervates described herein can be subsequently cured to produce strong, cohesive adhesives. The reinforced adhesive complex coacervates have several desirable features when compared to conventional adhesives. The reinforced adhesive complex coacervates are effective in wet or underwater applications. The reinforced adhesive complex coacervates described herein, being phase separated from water, can be applied underwater without dissolving or dispersing into the water. The reinforced adhesive complex coacervates have numerous biological applications as bioadhesives and bioactive delivery devices. In particular, the reinforced adhesive complex coacervates described herein are particularly useful in underwater applications and situations where water is present such as, for example, wet tissues in physiological conditions.

    专利号:US-2012238661-A1
    优先权日:2011-01-14
    标 题 :Processes for the Synthesis of Compounds from Cyclic Carbonates
    发明人:IYER RAMESH; MCKENNA PETER; SMALLRIDGE MARK; MATTHEWS MELISSA; NATESH ANBAZHAGAN
    权利人:IYER RAMESH; MCKENNA PETER; SMALLRIDGE MARK; MATTHEWS MELISSA; NATESH ANBAZHAGAN; COGNIS IP MAN GMBH
    摘要:The invention provides compounds containing the ring-opening products of ethylenically unsaturated cyclic carbonates for use in preparing hydrogel polymers, as well as methods for their preparation. A preferred method of the invention includes the reaction of nucleophilic compounds containing Si, F, N or O atoms, or combinations thereof, or latent moieties in the form of unsaturated or hydroxylated functional groups, with ethylenically unsaturated glycerol carbonate derivatives. The compounds and hydrogel polymers are useful for the preparation of contact lenses.
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    主要参考文献

    [参考文献]: Benjamin D Brooks, Et Al. A Resorbable Antibiotic-Eluting Polymer Composite Bone Void Filler For Perioperative Infection Prevention In A Rabbit Radial Defect Model. Plos One. 2015 Mar 27;10(3):E0118696.
    [参考文献]: Kira A Ivanova, Et Al. Induction Of Host Defences By Rhizobium During Ineffective Nodulation Of Pea (Pisum Sativum L.) Carrying Symbiotically Defective Mutations Sym40 (Psefd), Sym33 (Psipd3/pscyclops) And Sym42. Protoplasma. 2015 Nov;252(6):1505-17.
    [参考文献]: Leila Hejazi, Et Al. Gas Chromatography With Parallel Hard And Soft Ionization Mass Spectrometry. Rapid Commun Mass Spectrom. 2015 Jan 15;29(1):91-9.
    [参考文献]: Mengzhe Guo, Et Al. A New Strategy To Determine The Protein Mutation Site Using Matrix-Assisted Laser Desorption Ionization In-Source Decay: Derivatization By Ionic Liquid. Anal Chim Acta. 2015 Mar 20:865:31-8.
    [参考文献]: Samim Sardar, Et Al. Enhanced Charge Separation And Fret At Heterojunctions Between Semiconductor Nanoparticles And Conducting Polymer Nanofibers For Efficient Solar Light Harvesting. Sci Rep. 2015 Nov 27:5:17313.

    合成参考文献


    参考文献:10.1002/elps.200900508
    摘要:Luces CA, Warner IM. Achiral and chiral separations using MEKC, polyelectrolyte multilayer coatings, and mixed mode separation techniques with molecular micelles. Electrophoresis. 2010 Mar;31(6):1036–43.
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