专利号:US-2024009660-A1 优先权日:2022-07-05 标题 :Methods for synthesis of hierarchically ordered crystalline microporous materials with long-range mesoporous order 发明人:PARSAPUR RAJESH KUMAR; HODGKINS ROBERT PETER; KOSEOGLU OMER REFA; HUANG KUO-WEI; SEDJERARI ANISSA BENDJERIOU 权利人:SAUDI ARABIAN OIL CO; UNIV KING ABDULLAH SCI & TECH 摘要:Methods for synthesis of hierarchically ordered zeolites and zeolite-type materials are provided. Synthesized hierarchically ordered zeolites and zeolite-type materials formed according to the methods herein possess a high-degree of well-defined long-range mesoporous ordering. The methods include base-mediated reassembly, by dissolution of the parent material to the level of oligomeric structural building units of the parent material, and minimizing or avoiding amorphization/structural collapse. The dissolution and self-assembly is comprehensively controlled to produce hierarchically ordered zeolites and zeolite-type materials according to the methods herein.
专利号:US-2024010662-A1 优先权日:2022-07-05 标题 :Methods for synthesis of hierarchically ordered crystalline microporous materials with long-range mesoporous order 发明人:PARSAPUR RAJESH KUMAR; HODGKINS ROBERT P; KOSEOGLU OMER REFA; HUANG KUO-WEI; SEDJERARI ANISSA BENDJERIOU 权利人:SAUDI ARABIAN OIL CO; UNIV KING ABDULLAH SCI & TECH 摘要:Methods for synthesis of hierarchically ordered zeolites and zeolite-type materials are provided. Synthesized hierarchically ordered zeolites and zeolite-type materials formed according to the methods herein possess a high-degree of well-defined long-range mesoporous ordering. The methods include base-mediated reassembly, by dissolution of the parent material to the level of oligomeric structural building units of the parent material, and minimizing or avoiding amorphization/structural collapse. The dissolution and self-assembly is comprehensively controlled to produce hierarchically ordered zeolites and zeolite-type materials according to the methods herein.
专利号:US-11554348-B2 优先权日:2016-11-10 标 题 :Method of preparing hierarchical porous channel molecular sieve membrane and application thereof 发明人:GU XUEHONG; YAO XUN; PENG LI 权利人:NANJING UNIVERSITY OF TECHNOLOGY 摘要:The invention relates to a method for preparing a hierarchical porous zeolite membrane and an application thereof, comprising the following steps: a mesoporous structure-directing agent is added to limit the growth of zeolite crystals, and self-assembled in the crystallization process to generate a mesoporous structure. Based on a seed crystal induced secondary nucleation mechanism, this method can realize one-step hydrothermal synthesis of hierarchical porous zeolite membrane with the advantages of mild and controllable synthesis conditions, simple process, good repeatability, reduced energy consumption and cost savings. The hierarchical porous zeolite membrane prepared by the method has good cut-off performance, and the cut-off molecular weight is adjustable between 200 to 500,000 Da.
专利号:US-8815351-B2 优先权日:2005-09-15 标 题:Method for attachment of silicon-containing compounds to a surface and for synthesis of hypervalent silicon-compounds 发明人:OWENS JEFFREY R 权利人:OWENS JEFFREY R; US AIR FORCE 摘要:A method for attaching silicon-containing compounds to a surface and for synthesis of hypervalent silicon-compounds is described. Attaching silicon-containing compounds to a surface comprises providing a silicon-containing compound having two or more leaving groups, and a first functional compound comprising at least one nucleophilic group, contacting the silicon-containing compound and the functional compound with a surface of a substrate having nucleophilic sites and exposing the silicon-containing compound, the functional compound and the surface of the substrate to microwave radiation.
专利号:US-8951498-B2 优先权日:2010-07-30 标题 :Synthesis of hierarchical nanocrystalline zeolites with controlled particle size and mesoporosity 发明人:LARSEN SARAH; PETUSHKOV ANTON 权利人:LARSEN SARAH; PETUSHKOV ANTON; UNIV IOWA RES FOUND 摘要:A one step synthesis of nanocrystalline zeolites ZSM-5 and Naβ from a single template system in high yield has been discovered. The size of individual nanocrystals, as well as mesopore surface area and pore volume can be controlled by adjusting the pH of the reaction mixture, as well as the hydrothermal treatment temperature and duration. The mesopore volume and size distribution show a dependence on particle size such that smaller particles lead to higher mesopore volumes and narrower pore size distributions.
专利号:WO-2025024735-A1 优先权日:2023-07-27 标 题:Preparation of nanosheet zeolites and applications for methane dehydroaromatization 发明人:GOUNDER RAJAMANI; SANTIAGO-COLÓN Ã?NGEL 权利人:PURDUE RESEARCH FOUNDATION 摘要:Methods for making a Mo-nanosheet-CHA catalyst and Mo-meso-CHA catalyst. The method includes preparing an aqueous solution comprising one or more structure directing agents, mixing the aqueous solution with at least one silicon precursor and at least one aluminum precursor to provide a synthesis gel; recovering crystalline solids from the synthesis gel, wherein the crystalline solids consist of CHA zeolite crystallites; depositing a source of molybdenum onto the CHA zeolite crystallites to provide Mo-CHA zeolite crystallites having an average particle size of less than 200 nm in Mo-nanosheet-CHA and an average particle size > 500 nm in Mo-meso-CHA and containing a plurality of CHA zeolite pores; and carburizing the Mo-CHA zeolite crystallites at a temperature of 500°C to 900°C and a pressure of 80-100 kPa in the presence of methane (CHa) to form Mo carbide domains within the CHA zeolite pores. The Mo-nanosheet-CHA and Mo-meso-CHA catalysts are particularly useful for converting methane to aromatics.
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合成参考文献
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