CAS: 2388-68-3; 1,2-Bis(Methylthio)Benzene

该化合物是一种二硫醇化合物,配有与苯环相连的两个硫醇功能组,这种芳香二硫醇通常用作铬化剂和有机合成的构件,特别是在制作金属-有机框架和协调聚合物时;其硬苯基和双硫醇组对过渡金属具有很强的约束力,使其在催化和物质科学应用中具有价值;该化合物还作为异性合成的异性环化合物和离心体的前体;可用作专门研究和工业用途的高纯度,确保敏感化学工艺的一贯性能.

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100-68-5 54615-64-4 65516-74-7

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CAS号108-98-5 硫酚 | CAS号17534-15-5 1,2-苯二硫醇 | CAS号624-92-0 二甲基二硫醚 | CAS号71-43-2 苯 | CAS号77-78-1 硫酸二甲酯 | CAS号95-50-1 邻二氯苯 | CAS号74-88-4 碘甲烷 | CAS号87-61-6 1,2,3-三氯苯 | CAS号6461-76-3 1,2-苯二磺酰二氯 | CAS号2987-53-3 2-(甲硫基)苯胺 | CAS号29906-21-6 3-phenyl-1,5-di... | CAS号31443-14-8 spiro[1,5-dihyd... | CAS号154583-78-5 3-propan-2-yl-1... | CAS号138709-32-7 1-bromo-2-[2-br... | CAS号87453-67-6 1,2-bis(propyls...

合成工艺路线路线简述

    📜1,2-苯二磺酰二氯置于盐酸,锌体系中,化学反应生成1,2-苯二甲硫醇
    参考文献:Pollak,Monatshefte Fur Chemie,1913,Vol. 34,P. 1681
    标题:Pollak,Monatshefte Fur Chemie,1913,Vol. 34,P. 1681

    海关参考信息

    专利信息


    专利号:US-6790946-B2
    优先权日:1997-05-14
    标题 :Synthesis of oligonucleotides
    发明人：KWIATKOWSKI MAREK; LANDEGREN ULF; NILSSON MATS
    权利人:QUIATECH AB
    摘要:A method of preparing an immobilized oligonucleotide having a free 3′-end comprises the steps of: i) preparing an oligonucleotide attached in a first position to a solid support via its 3′-end and having a free 5′-end; ii) binding said oligonucleotide in a second position remote from the 3′-end to the solid support; and iii) selectively releasing the 3′-end of the oligonucleotide from the solid support to obta the oligonucleotide attached to the support in said second position in a reversed orientation with a free 3′-end.

    专利号:WO-2012059510-A1
    优先权日:2010-11-02
    标题:Back pressure control during solid-phase synthesis on polymeric supports
    发明人：CRAMER HAGEN; FINN KEVIN JAMES; ADUDA VINCENT OCHIENG; RUPP THOMAS M
    权利人:GIRINDUS AMERICA INC; CRAMER HAGEN; FINN KEVIN JAMES; ADUDA VINCENT OCHIENG; RUPP THOMAS M
    摘要:Described herein are methods for reducing the pressure in a solid-support column caused by swelling of the solid support in various solvents used in the detritylation and/or thiolation processes during oligonucleotide synthesis. Also described herein are methods for synthesizing oligonucleotides comprising contacting the solid-phase support with a washing fluid prior to and/or after thiolation and/or detritylation, wherein the washing fluid reduces pressure build up during oligonucleotide synthesis.

    专利号:US-2002051994-A1
    优先权日:1997-05-14
    标题 :Synthesis of oligonucleotides

    专利号:EP-0983288-B1
    优先权日:1997-05-14
    标 题 :Synthesis of oligonucleotides

    专利号:WO-9851698-A1
    优先权日:1997-05-14
    标题:Synthesis of oligonucleotides

    专利号:EP-0983288-A1
    优先权日:1997-05-14
    标题:Synthesis of oligonucleotides

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    主要参考文献

    [参考文献]: Anirban Das, Et Al. Ultrasound-Assisted Synthesis Of Pbs Quantum Dots Stabilized By 1,2-Benzenedimethanethiol And Attachment To Single-Walled Carbon Nanotubes. Ultrason Sonochem. 2014 Mar;21(2):892-900.

    合成参考文献


    摘要:Sato, R., Science of Synthesis, (2004) 16, 70.
    摘要:Collier, S. J., Science of Synthesis, (2007) 20, 688.
    摘要:Collier, S. J.; Kataisto, E., Science of Synthesis, (2007) 20, 63.
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