CAS: 13674-84-5; Tris(1-Chloro-2-Propyl) Phosphate

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13674-87-8 229625-50-7 72236-72-7

上下游产品

CAS号75-56-9 环氧丙烷

Methyloxirane置于三氯氧磷体系中,化学反应 3.0H,以95%的收率获得三(1-氯-2-丙基)磷酸酯
参考文献:一种磷酸三(2-氯丙基)酯的制备方法
标题:一种磷酸三(2-氯丙基)酯的制备方法
摘要:本发明公开了一种磷酸三(2‑氯丙基)酯的制备方法.现有的方法得到的产品颜色深,纯度不高,后处理操作麻烦.本发明以三氯氧磷与环氧丙烷为原料,以磁性金属有机框架mof复合材料为多相催化剂,无其它有机溶剂助剂加入情况下,在20~70oc下搅拌反应1~6小时,发生选择性酯化反应即可得到目标产物.本发明制备方法具有操作简便,反应条件温和,收率非常好,催化剂可多次反复使用,减少了三废排放,实现了清洁生产,是绿色环保的制备方法.

专利信息

专利号:EP-4345058-A1
优先权日:2022-08-16
标 题:Method for recycling organophosphates
发明人：WEIGAND JAN; SCHWEDTMANN KAI; SCHNEIDER TOBIAS; SCHULZ STEPHEN
权利人:UNIV DRESDEN TECH
摘要:The present invention relates to a process for the synthesis of nitrogen-containing phosphorus(V) precursors of the formula (I), wherein a phosphoric acid ester is reacted with an oxygen acceptor based on a sulfonic acid anhydride in the presence of a Lewis base L_N which is capable of coordination via a nitrogen atom, wherein the Lewis base L_N is a nitrogen-containing heteroaromatic compound which contains a six-membered heteroaromatic ring.The present invention also relates to a process for the synthesis of oxyphosphorus compounds, wherein the process is carried out for the synthesis of nitrogen-containing phosphorus(V) precursors of the formula (I) and the nitrogen-containing phosphorus(V) precursor of the formula (I) is reacted with a nucleophile.

专利号:PL-233221-B1
优先权日:2017-09-18
标 题 :The method of obtaining polyol raw material for the synthesis of rigid polyurethane-polyisocyanurate foams and the method of synthesis of rigid polyurethane-polyisocyanurate foams

专利号:US-5194469-A
优先权日:1991-02-28
标题:Latex for coatings having improved flexibility
发明人：SRAIL RICHARD E; BURROWAY GARY L
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved flexibility and good water resistance. Coatings of this type are particularly useful in roof coating applications because they offer excellent flexibility, excellent ultra-violet light resistance, and good water resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: n (1) free radical aqueous emulsion polymerizing, at a pH of less than about 3.5, a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 30 to about 70 weight percent vinyl aromatic monomers, (b) from about 25 to about 65 weight percent of at least one alkyl acrylate monomer, (c) from about 1 to about 5 weight percent of acrylic acid, and (d) about 0.4 to about 3 weight percent methacrylic acid, in the presence of about 0.2 to 0.4 phm at least one sulfonate surfactant and in the presence of about 4 to 8 phm of at least one nonionic surface active agent having a hydrophile-lipophile balance number which is within the range of about 12 to about 20 to produce a latex; and n (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex.

专利号:US-5122566-A
优先权日:1989-10-06
标 题 :Latex for coatings having reduced blushing characteristics
发明人：BURROWAY GARY L; GESENHUES ALBERT M; BRADEN JENNIFER T
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved water resistance for both moisture vapor transmission and water spotting. Coatings which are formulated with the latex of this invention are particularly useful for coating metal substrates because they provide excellent rust and corrosion resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: (1) free radical aqueous emulsion polymerizing at a pH of less than about 3.5 a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 45 to about 85 weight percent vinyl aromatic monomers, (b) from about 15 to about 50 weight percent of at least one alkyl acrylate monomer, and (c) from about 1 to about 6 weight percent of at least one unsaturated carbonyl compound; in the presence of about 0.5 to 4.0 phm at least one phosphate ester surfactant and in the presence of about 0.5 to 4.0 phm of at least one water insoluble nonionic surface active agent to produce a latex; and (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to a bout 10.5 to produce the neutralized latex.

专利号:CN-115181126-A
优先权日:2022-07-14
标 题 :A kind of method for continuous flow synthesis of tris(1-chloro-2-propyl) phosphate

专利号:US-4968741-A
优先权日:1989-10-06
标题:Latex for coatings having reduced blushing characteristics
发明人：BURROWAY GARY L; GESENHUES ALBERT M; BRADEN JENNIFER T
权利人:GOODYEAR TIRE & RUBBER
摘要:This invention relates to the synthesis of a latex which can be formulated into coatings having improved water resistance for both moisture vapor transmission and water spotting. Coatings which are formulated with the latex of this invention are particularly useful for coating metal substrates because they provide excellent rust and corrosion resistance. The subject invention more specifically discloses a process for producing a neutralized latex that is useful in the manufacture of water reducible coatings which comprises: n (1) free radical aqueous emulsion polymerizing at a pH of less than about 3.5 a monomer mixture which comprises, based on 100 weight percent monomers: (a) from about 45 to about 85 weight percent vinyl aromatic monomers, (b) from about 15 to about 50 weight percent of at least one alkyl acrylate monomer, and (c) from about 1 to about 6 weight percent of at least one unsaturated carbonyl compound; in the presence of about 0.5 to 4.0 phm at least one phosphate ester surfactant and in the presence of about 0.5 to 4.0 phm of at least one water insoluble nonionic surface active agent to produce a latex; and n (2) neutralizing the latex with ammonia to a pH which is within the range of about 7 to about 10.5 to produce the neutralized latex.