CAS: 424-64-6; 1H,1H-Heptafluorobutylacrylate

该化合物是一种氟丙烯单体,其特点是七氟丁基组,具有高化学抗药性,低地表能和极佳的热稳定性等独特特性.这种化合物在需要疏水和疏油表面的应用中特别具有价值,包括先进的涂层,粘合剂和特殊聚合物.其氟化侧链在恶劣的环境中增强耐用性和性能,使之适合工业和高技术应用.单体的再活动允许与其他丙烯酸酯形成光化共聚体,使材料具有适应性.处理要求对丙烯酸酯单体采取标准防范措施,包括防止光和湿度,以保持稳定性.

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54052-90-3 307-98-2 376-84-1

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ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号79-10-7 丙烯酸 | CAS号407-25-0 三氟乙酸酐(TFAH) | CAS号375-01-9 全氟丁醇 | CAS号814-68-6 丙烯酰氯

合成工艺路线路线简述

    📜丙烯酸,三氟乙酸酐 反应生成 2,2,3,3,4,4,4-七氟丁基丙烯酸酯
    参考文献:含氟聚合物.二,1,1-二氢全氟烷基丙烯酸酯:单体的制备1
    标题:含氟聚合物.二,1,1-二氢全氟烷基丙烯酸酯:单体的制备1
    摘要:已经合成了七种 N-1,1-二氢全氟烷醇的丙烯酸酯.酯是: 1,1-二氢全氟乙基-;1,1-二氢全氟丙基-;1,1-二氢全氟丁基-;1,1-二氢全氟戊基-;1,1-二氢全氟己基-;1,1-二氢全氟辛基-;和 1,1-二氢全氟癸基丙烯酸酯.由于这些醇类难以使用常规方法酯化,因此在这项工作中使用了丙烯酰氯或丙烯酸加全氟乙酸酐.
    DOI:10.1002/pol.1955.120158018

    海关参考信息

    专利信息


    专利号:US-8299139-B1
    优先权日:2009-09-08
    标 题:Process and reactor for synthesis of ultra-high molecular weight acrylic polymers
    发明人:TARANEKAR PRASAD; SCHUMAN AUSTIN L; BANERJIE ASIS
    权利人:TARANEKAR PRASAD; SCHUMAN AUSTIN L; BANERJIE ASIS; OVATION POLYMER TECHNOLOGY AND ENGINEERED MATERIALS INC
    摘要:This invention relates to a process for producing high molecular weight (HMW) and ultra-high molecular weight (UHMW) acrylic polymers having unique polymer tacticity and exhibiting enhanced thermal and mechanical properties. This process comprises polymerizing ethylenically unsaturated monomer in the presence of a free radical initiator that results in a “living-like polymer†utilizing a multi-step approach. In conducting the process of this invention the “living-like polymer†is further dissolved in a liquid carrier, wherein the said liquid carrier is a reactive diluent that can be reacted subsequently by an addition polymerization process to create a block- or multi-block, copolymer or homopolymer. This process can be progressively repeated with the same or various different reactive diluents to generate desired architecture and molecular weight polymer(s) which can be used in further processing procedures to be manufactured directly into finished articles.

    专利号:US-9534062-B2
    优先权日:2014-07-02
    标 题:Synthesis of an acrylate polymer in flow reactor
    发明人:HE MINGQIAN; HORN CLEMENS RUDOLF; HU JIEYU; JEAN PATRICK; NIU WEIJUN; SCHISSEL DAVID NEAL; WINNINGHAM MICHAEL JAMES
    权利人:CORNING INC
    摘要:An improved process for synthesizing acrylic polymers, which is highly controllable to achieve high molecular weight, high conversion rate, and low polydispersity involves continuously introducing initiator(s), acrylic monomer(s), and optionally other monomers capable of polymerizing with the acrylic monomer(s), into a microchannel of a microreactor having an integral micromixer and an integral heat exchanger.

    专利号:US-10150111-B2
    优先权日:2016-09-06
    标题 :Method for catalytic synthesis of cinnamic acid with catalyst recycle

    专利号:US-2016002367-A1
    优先权日:2014-07-02
    标题 :Synthesis of an acrylate polymer in flow reactor

    专利号:US-2018326410-A1
    优先权日:2016-09-06
    标题 :Method for catalytic synthesis of cinnamic acid with catalyst recycle

    专利号:JP-2017524797-A
    优先权日:2014-07-02
    标 题 :Synthesis of acrylic polymers in a flow reactor.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Artak Tovmasyan, Et Al. Novel Amphiphilic Cationic Porphyrin And Its Ag(Ii) Complex As Potential Anticancer Agents. J Inorg Biochem. 2014 Nov:140:94-103.
    [参考文献]: Erin Gemperline, Et Al. Measurement Of Nmda Receptor Antagonist, Cpp, In Mouse Plasma And Brain Tissue Following Systematic Administration Using Ion-Pair Lcms/ms. Anal Methods. 2014 Aug 21;6(16):6389-6396.
    [参考文献]: Ilaria Colzi, Et Al. Antibiotic Delivery By Liposomes From Prokaryotic Microorganisms: Similia Cum Similis Works Better. Eur J Pharm Biopharm. 2015 Aug:94:411-8.
    [参考文献]: Kale S Bongers, Et Al. Spermine Oxidase Maintains Basal Skeletal Muscle Gene Expression And Fiber Size And Is Strongly Repressed By Conditions That Cause Skeletal Muscle Atrophy. Am J Physiol Endocrinol Metab. 2015 Jan 15;308(2):E144-58.
    [参考文献]: Karine Meisser Redeuil, Et Al. Simultaneous Quantification Of 21 Water Soluble Vitamin Circulating Forms In Human Plasma By Liquid Chromatography-Mass Spectrometry. J Chromatogr A. 2015 Nov 27:1422:89-98.

    合成参考文献


    摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775
    摘要:Compound: 2-Propenoic acid, 2,2,3,3,4,4,4-heptafluorobutyl ester, homopolymer
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