CAS: 39718-32-6; 1,4-Difluoro-2-Isocyanatobenzene

该化合物是一种有机化合物,其特征是附于苯环的氟和异丙胺功能组,其特征是:含有氟和异丙胺的有机化合物,其特征是位于苯环1和4位置上的两个氟原子,可影响其反应和物理特性,如极度和沸点等;2位置的异氰酸盐组(-N=C=O),其潜力是各种化学反应中的一种反应中间体,特别是聚氨乙烷和其他聚合物的合成中.氟原子的存在通常会增强化合物的稳定性,并可能影响有机溶剂中的溶解性.此外,由于氟原子的含电磁性,1,4-二氟-2-异辛烷基苯可能具有独特的电子特性,从而引起材料科学和药用化学的兴趣.在处理这一化合物时,应当采取安全防范措施,因为据知,这种同位素是有毒的.

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MSDS等安全信息

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上下游产品

phosgene 2,5-difluoroaniline bis(trichloromethyl) carbonate 1,1-Dibenzyl-3-(2,5-difluoro-phenyl)-urea 2,5-difluorophenyl urea 5-(2'-methylpropyl)-3-(2,5-difluorophenyl)-1-methylimidazolidine-2,4-dione

合成工艺路线路线简述

    📜2,5-二氟苯胺置于硫酸体系中,用 甲苯 用作溶剂,化学反应 2.0H,反应生成异氰酸2,5-二氟苯酯
    参考文献:Organosilicon Synthesis Of Isocyanates: I. Synthesis Of Isocyanates Of The Furan,Thiophene,And Mono-And Polyfluorophenyl Series
    标题:Organosilicon Synthesis Of Isocyanates: I. Synthesis Of Isocyanates Of The Furan,Thiophene,And Mono-And Polyfluorophenyl Series
    摘要:A Convenient Synthesis Of Known And Unknown Isocyanates Of The Furan,Thiophene,And Mono-And Polyfluorophenyl Series,Involving Silylation Of Starting Amines With Hexamethyldisilazane Or Chlorotrimethylsilane,Followed By Phosgenation Of The Resulting N-Silyl-Substituted Amines. An Unusual High-Temperature Rearrangement Of 3-(Methoxycarbonyl)-4,5-Dimethylthiophene-2-Yl Isocyanate Into Its 5-Ethyl Isomer. Ortho-Fluorine Substituent In Anilines Decreases The Yield Of Isocyanates,Whereas 2,3,5,6-Tetrafluorophenyl Isocyanate Exists For Only A Short Time As A 5% Toluene Solution.
    Doi:10.1134/s1070363206010208

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    专利信息


    专利号:CN-111471171-B
    优先权日:2019-01-24
    标 题:A kind of aryl sulfonic acid intermediate and its preparation method, and its application for the synthesis of low temperature sensitive admixture for concrete

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    主要参考文献

    参考标题:Application Of A Catalytic Asymmetric Povarov Reaction Using Chiral Ureas To The Synthesis Of A Tetrahydroquinoline Library
    作者:Baudouin Gerard,Morgan Welzel O'Shea,Etienne Donckele,Sarathy Kesavan,Lakshmi B. Akella,Hao Xu,Eric N. Jacobsen,Lisa A. Marcaurelle |发布日期:2012.11.12
    摘要:A 2328-Membered Library Of 2,3,4-Trisubstituted Tetrahydroquinolines Was Produced Using A Combination Of Solution- And Solid-Phase Synthesis Techniques. A Tetrahydroquinoline (Thq) Scaffold Was Prepared Via An Asymmetric Povarov Reaction Using Cooperative Catalysis To Generate Three Contiguous Stereogenic Centers. A Matrix Of 4 Stereoisomers Of The Thq Scaffold Was Prepared To Enable The Development

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    参考DOI号:10.1134/S1070363206010208
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